US4152467A
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US
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Electroless copper plating process with dissolved oxygen maintained in bath
Assignee: International Business Machines Corp
•
Filing: 1978-03-10
•
Granted: 1979-05-01
•
Expires: 1998-03-10
Abstract
Abstract Copper is electrolessly deposited on a surface wherein the dissolved oxygen content is maintained between 2 and 4 ppm in the plating bath.
Inventors
- 👤 Warren A. Alpaugh
- 👤 Theodore D. Zucconi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 13:37
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/31; C23C18/38; C23C18/40; H; H05; H05K; H05K3/00; H05K3/10; H05K3/18; H05K3/181; H05K3/187
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
49 words
A process for electrolessly depositing copper on a surface which is catalytic for the deposition of copper which comprises contacting the surface to be plated with a copper plating bath and maintaining during the plating a level of dissolved O 2 in the bath between 2 and 4 ppm.
Claim 2
Dependent Claim
49 words
A process for electrolessly depositing copper on a surface which is catalytic for the deposition of copper which comprises contacting the surface to be plated with a copper plating bath and maintaining during the plating a level of dissolved O 2 in the bath between 2 and 4 ppm.
Claim 3
Dependent Claim
22 words
The process of claim 1 wherein the predetermined level of the dissolved oxygen in the bath is between 2.5 and 3.5 ppm.
Claim 4
Dependent Claim
17 words
The process of claim 1 wherein the temperature of the bath is between 70° and 80° C.
Claim 5
Dependent Claim
17 words
The process of claim 1 wherein the temperature of the bath is between 70° and 75° C.
Claim 6
Dependent Claim
18 words
The process of claim 1 wherein the temperature of the bath is maintained within 0.5° of 73° C.
Claim 7
Dependent Claim
20 words
The process of claim 1 wherein the pH of the bath is maintained within the range of 11.6 and 11.8.
Claim 8
Dependent Claim
13 words
The process of claim 1 wherein the electroless process is a continuous process.
Claim 9
Dependent Claim
17 words
The process of claim 1 wherein the specific gravity of the bath is between 1.060 and 1.080.
Claim 10
Dependent Claim
36 words
The process of claim 1 wherein the plating bath comprises a source of cupric ions, a reducing agent for said cupric ions, a surfactant, a complexing agent for cupric ions, and a source of cyanide ions.
Claim 11
Dependent Claim
39 words
The process of claim 9 wherein the bath is maintained continuously between 70° and 80° C. during the plating and the bath is adjusted to maintain continuously a cyanide ion concentration within the range of 0.0002 to 0.0004 molar.
Claim 12
Dependent Claim
89 words
The process of claim 1 wherein said plating bath comprises 3 to 15 grams per liter of cupric ion source, 0.7 to 7 grams per liter of a reducing agent, 0.02 to 0.3 grams per liter of a surface-active agent, 20 to 50 grams per liter of a complexing agent for the cupric ion, 10 to 25 mg per liter of cyanide ion, a pH of 11.6-11.8, and a specific gravity of 1.060 to 1.080, and wherein the bath is maintained at a temperature of 70° to 80° C.
Claim 13
Dependent Claim
11 words
The process of claim 11 wherein the reducing agent is formaldehyde.
Claim 14
Dependent Claim
14 words
The process of claim 11 wherein the complexing agent is ethylene diamine tetraacetic acid.
Claim 15
Dependent Claim
13 words
The process of claim 11 wherein the surfactant is an organic phosphate ester.
Claim 16
Dependent Claim
63 words
The process of claim 1 wherein the amount of dissolved oxygen is maintained by introducing into the bath a mixture of oxygen-containing gas and an inert gas wherein the amount of oxygen in the mixture is such that there will be less than that amount of oxygen dissolved in the bath than would be present if the bath were aerated with air alone.
Claim 17
Dependent Claim
24 words
The process of claim 15 wherein the flow rate of said mixture is between about 1 and 20 SCFM per 1000 gallons of bath.
Claim 18
Dependent Claim
23 words
The process of claim 15 wherein the flow rate of said mixture is between 3 and 8 SCFM per 1000 gallons of bath.
Claim 19
Dependent Claim
11 words
The process of claim 15 wherein the oxygen-containing gas is air.
Claim 20
Dependent Claim
24 words
The process of claim 15 wherein said inert gas is selected from the group consisting of hydrogen, nitrogen, argon, neon, krypton, and mixtures thereof.
Claim 21
Dependent Claim
11 words
The process of claim 15 wherein said inert gas is nitrogen.
Claim 22
Dependent Claim
17 words
The process of claim 1 wherein the oxygen level of the bath is measured during the plating.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-04-30 | 1982-10-30 | 1983-05-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-04-30 | 1986-10-30 | 1987-05-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-04-30 | 1990-10-30 | 1991-05-01 | $7700.00 | Window Closed / Lapsed |