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US4170482A Expired / Lapsed US ⏱️ 0.0 years remaining

Jet printing ink composition containing an acetylenic compound and a lactone

Assignee: M&T Chemicals Inc
•
Filing: 1978-09-08
•
Granted: 1979-10-09
•
Expires: 1998-09-08
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Abstract

Abstract An ink composition for use in jet printing comprising an aqueous solution of a water-soluble dye and a humectant consisting of the combination of at least one water-soluble acetylenic compound and the internal anhydride of at least one carboxylic acid in a ratio of 90:1 of the former to 1:90 of the latter.

Inventors

  • 👤 Ishwar R. Mansukhani

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 23:01
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 275 words
In a process for information recording comprising producing a fine jet of colored aqueous liquid, directing the jet of colored liquid onto a recording medium, modulating the density of the applied jet by an electric field in accordance with the information to be recorded, the improvement comprising the presence as a humectant consisting of the combination of at least one water-soluble acetylenic compound selected from α-substituted acetylenic compounds exhibiting the structural formula: ##STR6## in which each of R 1 and R 2 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and R 1 and R 2 may together be a carbonyl oxygen; R 3 may be a substituent of the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkenyl and alkynyl groups, and substituted-alkyl groups having the formula: ##STR7## in which each of R 4 and R 5 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, and hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and when R 1 and R 2 together are carbonyl oxygen, R 3 may be an aryl group, including hydroxy and alkoxy and alkyl-substituted aryl; each of R.sub.α and R.sub.α' may be substituents selected from the group consisting of hydroxy, alkoxy, carboxy-substituted alkoxy, formoxy, alkanoxy, halogen and polyoxy groups and the internal anhydride of at least one carboxylic acid selected from the group consisting of the lactones of fatty acids, the lactones of alicyclic acids, the lactones of acetylenic acids, and the lactones of aromatic acids in a ratio of 90:1 of the former to 1:90 of the latter.
Claim 2
Dependent Claim 275 words
In a process for information recording comprising producing a fine jet of colored aqueous liquid, directing the jet of colored liquid onto a recording medium, modulating the density of the applied jet by an electric field in accordance with the information to be recorded, the improvement comprising the presence as a humectant consisting of the combination of at least one water-soluble acetylenic compound selected from α-substituted acetylenic compounds exhibiting the structural formula: ##STR6## in which each of R 1 and R 2 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and R 1 and R 2 may together be a carbonyl oxygen; R 3 may be a substituent of the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkenyl and alkynyl groups, and substituted-alkyl groups having the formula: ##STR7## in which each of R 4 and R 5 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, and hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and when R 1 and R 2 together are carbonyl oxygen, R 3 may be an aryl group, including hydroxy and alkoxy and alkyl-substituted aryl; each of R.sub.α and R.sub.α' may be substituents selected from the group consisting of hydroxy, alkoxy, carboxy-substituted alkoxy, formoxy, alkanoxy, halogen and polyoxy groups and the internal anhydride of at least one carboxylic acid selected from the group consisting of the lactones of fatty acids, the lactones of alicyclic acids, the lactones of acetylenic acids, and the lactones of aromatic acids in a ratio of 90:1 of the former to 1:90 of the latter.
Claim 3
Dependent Claim 12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 1,4-di-(β-hydroxyethoxy)-2-butyne.
Claim 4
Dependent Claim 12 words
The process of claim 1 wherein said water-soluble acethylenic compound is 1,4-di-(β-hydroxy-γ-chloropropoxy)-2-butyne.
Claim 5
Dependent Claim 12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 1,4-di-(β-,γ-epoxypropoxy)-2-butyne.
Claim 6
Dependent Claim 12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 1,4-di-(β-hydroxy-γ-butenoxy)-2-butyne.
Claim 7
Dependent Claim 12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 1,4-di-(2'-hydroxy-4'-oxa-6'-heptenoxy)-2-butyne.
Claim 8
Dependent Claim 12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 2-butyne-1,4-diol.
Claim 9
Dependent Claim 13 words
The process of claim 1 wherein said water-soluble acetylenic compound is propargyl alcohol.
Claim 10
Dependent Claim 12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 2-methyl-3-butyn-2-ol.
Claim 11
Dependent Claim 12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 1,4-di-(β-sulfoethoxy)-2-butyne.
Claim 12
Dependent Claim 12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 3-(β-hydroxyethoxy)-propyne.
Claim 13
Dependent Claim 12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 3-(β-hydroxypropoxy)-propyne.
Claim 14
Dependent Claim 11 words
The process of claim 1 wherein said internal anhydride is butyrolactone.
Claim 15
Dependent Claim 242 words
An ink composition for use in jet printing comprising an aqueous solution of a water-soluble dye and a humectant consisting of the combination of at least one water-soluble acetylenic compound selected from α-substituted acetylenic compounds exhibiting the structural formula: ##STR8## in which each of R 1 and R 2 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and R 1 and R 2 may together be a carbonyl oxygen; R 3 may be a substituent of the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkenyl and alkynyl groups, and substituted-alkyl groups having the formula: ##STR9## in which each of R 4 and R 5 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, and hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and when R 1 and R 2 together are carbonyl oxygen, R 3 may be an aryl group, including hydroxy and alkoxy and alkyl-substituted aryl; each of R.sub.α and R.sub.α' may be substituents selected from the group consisting of hydroxy, alkoxy, carboxy-substituted alkoxy, formoxy, alkanoxy, halogen and polyoxy groups and the internal anhydride of at least one carboxylic acid selected from the group consisting of the lactones of fatty acids, the lactones of alicyclic acids, the lactones of acetylenic acids, and the lactones of aromatic acids in a ratio of 90:1 of the former to 1:90 of the latter.
Claim 16
Dependent Claim 242 words
An ink composition for use in jet printing comprising an aqueous solution of a water-soluble dye and a humectant consisting of the combination of at least one water-soluble acetylenic compound selected from α-substituted acetylenic compounds exhibiting the structural formula: ##STR8## in which each of R 1 and R 2 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and R 1 and R 2 may together be a carbonyl oxygen; R 3 may be a substituent of the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkenyl and alkynyl groups, and substituted-alkyl groups having the formula: ##STR9## in which each of R 4 and R 5 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, and hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and when R 1 and R 2 together are carbonyl oxygen, R 3 may be an aryl group, including hydroxy and alkoxy and alkyl-substituted aryl; each of R.sub.α and R.sub.α' may be substituents selected from the group consisting of hydroxy, alkoxy, carboxy-substituted alkoxy, formoxy, alkanoxy, halogen and polyoxy groups and the internal anhydride of at least one carboxylic acid selected from the group consisting of the lactones of fatty acids, the lactones of alicyclic acids, the lactones of acetylenic acids, and the lactones of aromatic acids in a ratio of 90:1 of the former to 1:90 of the latter.
Claim 17
Dependent Claim 12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(β-hydroxyethoxy)-2-butyne.
Claim 18
Dependent Claim 12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(β-hydroxy-γ-chloropropoxy)-2-butyne.
Claim 19
Dependent Claim 12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(β-,γ-epoxypropoxy)-2-butyne.
Claim 20
Dependent Claim 12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(β-hydroxy-γ-butenoxy)-2-butyne.
Claim 21
Dependent Claim 12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(2'-hydroxy-4'-oxa-6'-heptenoxy)-2-butyne.
Claim 22
Dependent Claim 12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 2-butyne-1,4-diol.
Claim 23
Dependent Claim 13 words
The composition of claim 14 wherein said water-soluble acetylenic compound is propargyl alcohol.
Claim 24
Dependent Claim 12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 2-methyl-3-butyn-2-ol.
Claim 25
Dependent Claim 12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(β-sulfoethoxy)-2-butyne.
Claim 26
Dependent Claim 12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 3-(β-hydroxyethoxy)-propyne.
Claim 27
Dependent Claim 12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 3-(β-hydroxypropoxy)-propyne.

References Cited (Backward Citations)

US3692548A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-10-08 1983-04-09 1983-10-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-10-08 1987-04-09 1987-10-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-10-08 1991-04-09 1991-10-09 $7700.00 Window Closed / Lapsed

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