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US4181654A Expired / Lapsed US ⏱️ 0.0 years remaining

2,3-Dihydroxybenzoic acid amides of tetraazaalkanes and tetaaza cycloalkanes

Assignee: United States Department of Energy
•
Filing: 1978-07-24
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Granted: 1980-01-01
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Expires: 1998-07-24
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Abstract

Abstract A compound of the formula: <IMAGE> <IMAGE> wherein X is hydrogen or a conventional electron-withdrawing group, particularly -SO3H or a salt thereof; n is 2, 3, or 4; m is 2, 3, or 4; and p is 2 or 3. The present compounds are useful as specific sequestering agents for actinide (IV) ions. Also described is a method for the 2,3-dihydroxybenzamidation of azaalkanes.

Inventors

  • 👤 Frederick L. Weitl
  • 👤 Kenneth N. Raymond

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 17:35
CPC Classifications
C; C07; C07D; C07D257/00; C07D257/02

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 39 words
A compound of the formula: ##STR5## wherein X is hydrogen, --SO 3 H or a salt thereof, or --NO 2 ; n is 2, 3, or 4; m is 2, 3, or 4; and p is 2 or 3.
Claim 2
Dependent Claim 39 words
A compound of the formula: ##STR5## wherein X is hydrogen, --SO 3 H or a salt thereof, or --NO 2 ; n is 2, 3, or 4; m is 2, 3, or 4; and p is 2 or 3.
Claim 3
Dependent Claim 20 words
A compound as in claim 1 wherein the formula is ##STR6## and n, m, and p are 2 or 3.
Claim 4
Dependent Claim 11 words
A compound as in claim 2 wherein the compound is 1,4,8,11-N,N',N",N'"-tetra(2,3-dihydroxybenzoyl)tetraazacyclotetradecane.
Claim 5
Dependent Claim 11 words
A compound as in claim 2 wherein the compound is 1,4,8,11-N,N',N",N'"-tetra(2,3-dihydroxy-5-nitrobenzoyl)tetraazacyclotetradecane.
Claim 6
Dependent Claim 11 words
A compound as in claim 2 wherein the compound is 1,5,9,13-N,N',N",N'"-tetra(2,3-dihydroxybenzoyl)tetraazacyclohexadecane.
Claim 7
Dependent Claim 18 words
A compound as in claim 2 wherein the compound is a 1,5,9,13-N,N',N",N'"-tetra(2,3-dihydroxybenzoyl)tetraazacyclohexadecane sulfonic acid or a salt thereof.
Claim 8
Dependent Claim 11 words
A compound as in claim 2 wherein the compound is 1,4,8,12-N,N',N",N'"-tetra(2,3-dihydroxybenzoyl)tetraazacyclopentadecane.
Claim 9
Dependent Claim 17 words
A compound as in claim 2 wherein the compound is 1,4,8,12-N,N',N",N'"-tetra(2,3-dihydrobenzoyl)tetraazacyclopentadecane sulfonic acid or a salt thereof.
Claim 10
Dependent Claim 11 words
A compound as in claim 1 wherein the formula is ##STR7##
Claim 11
Dependent Claim 11 words
A compound as in claim 9 wherein the compound is 1,4,8,11-N,N',N",N'"-tetra(2,3-dihydroxybenzoyl)tetraazaundecane.
Claim 12
Dependent Claim 17 words
A compound as in claim 9 wherein the compound is 1,4,8,11-N,N',N",N'"-tetra(2,3-dihydroxybenzoyl)tetraazaundecane sulfonic acid or a salt thereof.
Claim 13
Dependent Claim 11 words
A compound as in claim 9 wherein the compound is 1,6,11,16-N,N',N",N'"-tetra(2,3-dihydroxybenzoyl)tetraazahexadecane.

References Cited (Backward Citations)

USB403326I5 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-31 1983-07-02 1984-01-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-31 1987-07-02 1988-01-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-31 1991-07-02 1992-01-01 $7700.00 Window Closed / Lapsed

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