US4201739A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Manufacture of metal halide particles
Assignee: APL Inc A CORP OF OHIO
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Filing: 1976-03-17
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Granted: 1980-05-06
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Expires: 1996-03-17
Abstract
Abstract An improvement is disclosed in a process for the manufacture of metal halide particles containing at least one lanthanide metal halide in which the metal halide is melted and passed through a discharge conduit into an inert, quenching atmosphere. The improvement comprises adding a minor amount of hydrogen halide (the halide radical of the lanthanide metal halide and of the hydrogen halide being of the same halogen species) to the molten lanthanide metal halide to promote wetting of the molten lanthanide metal salt on the discharge conduit. The resulting particles show excellent uniformity of particle size and size distribution.
Inventors
- 👤 Scott Anderson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 21:14
CPC Classifications
B; B01; B01J; B01J2/00; B01J2/02; B01J2/04; C; C01; C01F; C01F17/00; C01F17/20; C01F17/253; C01G; C01G1/00; C01G1/06
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
127 words
In a process in which a purified lanthanide metal halide salt is melted and passed through a discharge conduit into an inert, quenching atmosphere of sufficient length and temperature to at least partially solidify particles containing purified lanthanide metal halide, the improvement which comprises promoting wetting of the lanthanide metal halide salt on the conduit without the addition of water to the quenching atmosphere, said promoting of wetting being effected by adding to said molten lanthanide metal halide a controlled amount of hydrogen halide effective to promote wetting of the lanthanide metal halide salt on the conduit during the discharge into the inert quenching atmosphere, the halide radical of the lanthanide metal salt and the halide radical of the hydrogen halide being of the same halogen species.
Claim 2
Dependent Claim
127 words
In a process in which a purified lanthanide metal halide salt is melted and passed through a discharge conduit into an inert, quenching atmosphere of sufficient length and temperature to at least partially solidify particles containing purified lanthanide metal halide, the improvement which comprises promoting wetting of the lanthanide metal halide salt on the conduit without the addition of water to the quenching atmosphere, said promoting of wetting being effected by adding to said molten lanthanide metal halide a controlled amount of hydrogen halide effective to promote wetting of the lanthanide metal halide salt on the conduit during the discharge into the inert quenching atmosphere, the halide radical of the lanthanide metal salt and the halide radical of the hydrogen halide being of the same halogen species.
Claim 3
Dependent Claim
37 words
In the process of claim 1, wherein the hydrogen halide is added to the quenching atmosphere in an amount of from about 3 to about 15 p.p.m based on the total mass of the lanthanide metal halide.
Claim 4
Dependent Claim
27 words
In the process of claim 2, wherein the hydrogen halide is added to the quenching atmosphere in an amount of from about 5 to about 10 p.p.m.
Claim 5
Dependent Claim
11 words
In the process of claim 1, wherein the halide is iodide.
Claim 6
Dependent Claim
12 words
In the process of claim 4, wherein the lanthanide metal is scandium.
Claim 7
Independent Claim
143 words
A method of forming substantially uniformly sized particles comprising a lanthanide metal halide salt having a mass greater than about 3 milligrams per particle comprising forming a melt comprising a purified lanthanide metal halide salt discharging the molten purified lanthanide metal halide salt through a conduit as particles of substantially uniform size into a quenching chamber having an inert atmosphere, the chamber having a temperature and length sufficient to substantially solidify said particles, said discharging being performed in the presence of a minor amount of wetting agent effective to promote the wetting of the molten lanthanide metal salt on the conduit, to facilitate formation of particles having a mass greater than about 3 milligrams per particle said minor amount of said wetting agent being essentially soluble in the molten lanthanide metal halide salt and substantially insoluble in said solidified lanthanide metal salt particles.
Claim 8
Independent Claim
143 words
A method of forming substantially uniformly sized particles comprising a lanthanide metal halide salt having a mass greater than about 3 milligrams per particle comprising forming a melt comprising a purified lanthanide metal halide salt discharging the molten purified lanthanide metal halide salt through a conduit as particles of substantially uniform size into a quenching chamber having an inert atmosphere, the chamber having a temperature and length sufficient to substantially solidify said particles, said discharging being performed in the presence of a minor amount of wetting agent effective to promote the wetting of the molten lanthanide metal salt on the conduit, to facilitate formation of particles having a mass greater than about 3 milligrams per particle said minor amount of said wetting agent being essentially soluble in the molten lanthanide metal halide salt and substantially insoluble in said solidified lanthanide metal salt particles.
Claim 9
Dependent Claim
36 words
The method of claim 6 wherein said wetting agent is a hydrogen halide, the halide radical of the lanthanide metal halide salt and the halide radical of the hydrogen halide being of the same halogen species.
Claim 10
Dependent Claim
11 words
The method of claim 7 wherein the halogen species is iodine.
Claim 11
Dependent Claim
11 words
The method of claim 8 wherein the lanthanide metal is scandium.
Claim 12
Dependent Claim
42 words
The method of claim 6 wherein said melt also includes a halide salt of a non-lanthanide metal, the halide radical of the non-lanthanide metal halide salt being of the same halogen species as the halide radical of the lanthanide metal halide salt.
Claim 13
Dependent Claim
11 words
The method of claim 10 wherein the non-lanthanide metal is sodium.
Claim 14
Dependent Claim
11 words
The method of claim 11 wherein the lanthanide metal is scandium.
Claim 15
Dependent Claim
36 words
The method of claim 7 wherein said hydrogen halide wetting agent is present in an amount of from about 3 to about 15 parts per million based on the weight of the lanthanide metal halide salt.
Claim 16
Dependent Claim
36 words
The method of claim 13 wherein said hydrogen halide wetting agent is present in an amount of from about 5 to about 10 parts per million based on the weight of the lanthanide metal halide salt.
Claim 17
Dependent Claim
34 words
The method of claim 6 wherein the wetting agent is mixed with an inert gas and the mixture is passed into contact with the melt prior to discharge of the melt through the conduit.
Claim 18
Independent Claim
151 words
A method of forming substantially uniform sized particles containing a lanthanide metal halide salt, said particles having a mass greater than about 3 milligrams comprising the steps of: (a) forming a melt containing a purified lanthanide metal halide salt; (b) discharging the molten metal halide salt through the conduit into a chamber having an inert quenching atmosphere to form pellets of substantially uniform size, the chamber having a temperature and a length sufficient to substantially solidify said pellets sufficient to resist deformation upon collection in the quenching chamber; and, (c) contacting the discharge conduit and the molten metal halide salt with an amount of a substance effective to wet the molten metal halide salt on the conduit to facilitate formation of droplets of the molten metal halide salt having a mass greater than about 3 milligrams per particle, without reacting with the molten metal halide salt to form insoluble impurities therein.
Claim 19
Independent Claim
151 words
A method of forming substantially uniform sized particles containing a lanthanide metal halide salt, said particles having a mass greater than about 3 milligrams comprising the steps of: (a) forming a melt containing a purified lanthanide metal halide salt; (b) discharging the molten metal halide salt through the conduit into a chamber having an inert quenching atmosphere to form pellets of substantially uniform size, the chamber having a temperature and a length sufficient to substantially solidify said pellets sufficient to resist deformation upon collection in the quenching chamber; and, (c) contacting the discharge conduit and the molten metal halide salt with an amount of a substance effective to wet the molten metal halide salt on the conduit to facilitate formation of droplets of the molten metal halide salt having a mass greater than about 3 milligrams per particle, without reacting with the molten metal halide salt to form insoluble impurities therein.
Claim 20
Dependent Claim
59 words
The method of claim 16 wherein said substance is a hydrogen halide, the halide radical of the lanthanide metal halide salt and the halide radical of the hydrogen halide being of the same halogen species, present in an amount of from about 3 to about 15 parts per million based on the amount of the lanthanide metal halide salt.
Claim 21
Dependent Claim
25 words
The method of claim 17 wherein the melt is formed of a mixture of a lanthanide metal halide salt and an alkali metal halide salt.
Claim 22
Dependent Claim
46 words
The method of claim 18 wherein the lanthanide metal halide salt is scandium iodide, the alkali metal halide salt is sodium iodide, the hydrogen halide is hydrogen iodide and the hydrogen iodide is present in an amount of from about 5 to 10 parts per million.
References Cited (Backward Citations)
US3676534A
Cited
US3944639A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-05-06 | 1983-11-05 | 1984-05-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-05-06 | 1987-11-05 | 1988-05-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-05-06 | 1991-11-05 | 1992-05-06 | $7700.00 | Window Closed / Lapsed |