US4207305A
Expired / Lapsed
US
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Hexacoordinated ruthenium moderated production of hydrogen peroxide and sulfur from oxygen and hydrogen sulfide
Assignee: Honeywell International Inc
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Filing: 1979-04-27
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Granted: 1980-06-10
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Expires: 1999-04-27
Abstract
Abstract A process of reacting in the liquid phase a hexacoordinated ruthenium(II) complex with oxygen in the presence of a source of hydrogen ions under conditions forming hydrogen peroxide and the corresponding hexacoordinated ruthenium(III) complex and reacting the hexacoordinated ruthenium(III) complex with hydrogen sulfide to form elemental sulfur and regenerate the hexacoordinated ruthenium(II) complex, the hexacoordinated ruthenium(III) complex having a reduction potential of not more than +0.68. Five or six of the ligands of the ruthenium complexes are non-labile in both valence states.
Inventors
- 👤 Steven E. Diamond
- 👤 Frank Mares
- 👤 Benjamin S. Tovrog
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 14:27
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/05; C01B15/00; C01B15/01
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
110 words
A process for the production of hydrogen peroxide and elemental sulfur from oxygen and hydrogen sulfide which comprises reacting in the liquid phase a hexacoordinated ruthenium(II) complex with oxygen in the presence of a hydrogen ion donating species under conditions forming hydrogen peroxide and the corresponding hexacoordinated ruthenium(III) complex and reacting the hexacoordinate ruthenium(III) complex with hydrogen sulfide to form elemental sulfur and hydrogen ions and to regenerate the hexacoordinated ruthenium(II) complex, said hexacoordinated ruthenium(III) complex having a reduction potential to ruthenium(II) of no more than +0.68 volts and at least 5 of the 6 ligands being non-labile for both the hexacoordinated ruthenium(II) complex and the hexacoordinated ruthenium (III) complex.
Claim 2
Dependent Claim
110 words
A process for the production of hydrogen peroxide and elemental sulfur from oxygen and hydrogen sulfide which comprises reacting in the liquid phase a hexacoordinated ruthenium(II) complex with oxygen in the presence of a hydrogen ion donating species under conditions forming hydrogen peroxide and the corresponding hexacoordinated ruthenium(III) complex and reacting the hexacoordinate ruthenium(III) complex with hydrogen sulfide to form elemental sulfur and hydrogen ions and to regenerate the hexacoordinated ruthenium(II) complex, said hexacoordinated ruthenium(III) complex having a reduction potential to ruthenium(II) of no more than +0.68 volts and at least 5 of the 6 ligands being non-labile for both the hexacoordinated ruthenium(II) complex and the hexacoordinated ruthenium (III) complex.
Claim 3
Dependent Claim
23 words
The process of claim 1 wherein all 6 of the ligands are non-labile in the hexacoordinated ruthenium(II) complex and the hexacoordinated ruthenium(III) complex.
Claim 4
Dependent Claim
23 words
The process of claim 1 wherein at least 5 of the ligands of the hexacoordinated ruthenium complexes have nitrogen as the ligating atom.
Claim 5
Dependent Claim
22 words
The process of claim 1 wherein all 6 of the ligands of the hexacoordinated ruthenium complexes have nitrogen as the ligating atom.
Claim 6
Dependent Claim
26 words
The process of claim 1 wherein the reduction potential of said hexacoordinated ruthenium(III) complex to said hexacoordinated ruthenium(II) complex is not greater than about +0.2 volts.
Claim 7
Dependent Claim
26 words
The process of claim 1 wherein the reduction potential of said hexacoordinated ruthenium(III) complex to said hexacoordinated ruthenium(II) complex is not greater than about +0.1 volts.
Claim 8
Dependent Claim
16 words
The process of claim 1 wherein the reduction of oxygen is conducted in an aqueous phase.
Claim 9
Dependent Claim
17 words
The process of claim 1 wherein the oxidation of hydrogen sulfide is conducted in an aqueous phase.
Claim 10
Dependent Claim
57 words
A process of forming a hexacoordinated ruthenium (II) complex which comprises reacting a hexacoordinated ruthenium(III) complex with hydrogen sulfide in a liquid phase to produce the corresponding hexacoordinated ruthenium (II) complex, hydrogen ions and elemental sulfur, with at least five of the six ligands being non-labile for both the hexacoordinated ruthenium(II) complex and the hexacoordinated ruthenium(III) complex.
Claim 11
Dependent Claim
57 words
A process of forming a hexacoordinated ruthenium (II) complex which comprises reacting a hexacoordinated ruthenium(III) complex with hydrogen sulfide in a liquid phase to produce the corresponding hexacoordinated ruthenium (II) complex, hydrogen ions and elemental sulfur, with at least five of the six ligands being non-labile for both the hexacoordinated ruthenium(II) complex and the hexacoordinated ruthenium(III) complex.
Claim 12
Dependent Claim
18 words
The process of claim 9 wherein all 6 of the ligands of said hexacoordinated ruthenium(III) complex are non-labile.
Claim 13
Dependent Claim
17 words
The process of claim 9 wherein all 6 of said ligands have nitrogen as the ligating atom.
Claim 14
Dependent Claim
15 words
The process of claim 9 wherein said reduction potential is not greater than about +0.2.
Claim 15
Dependent Claim
20 words
The process of claim 9 wherein said hexacoordinated ruthenium(III) complex has a reduction potential to ruthenium(II) not greater than +0.68.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-06-10 | 1983-12-10 | 1984-06-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-06-10 | 1987-12-10 | 1988-06-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-06-10 | 1991-12-10 | 1992-06-10 | $7700.00 | Window Closed / Lapsed |