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US4208477A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat resistant photoresist composition and process for preparing the same

Assignee: Asahi Kasei Corp
•
Filing: 1978-11-16
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Granted: 1980-06-17
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Expires: 1998-11-16
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Abstract

Abstract An organic polar solvent-soluble aromatic polyamide-imide having therein aromatic nuclei linked at their respective 1- and 3-positions and having therein amide linkages and terminal groups unsubstituted or partially substituted with acrylate or methacrylate groups is found to impart excellent heat resistance and insulating property to a photoresist composition produced therefrom.

Inventors

  • 👤 Kaoru Ohmura
  • 👤 Ichiro Shibasaki
  • 👤 Takeo Kimura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 00:08
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/14; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; G03F7/037; G03F7/038; G03F7/0387

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 385 words
A heat resistant photoresist composition comprising: (1) 100 parts by weight of a polymer selected from the group consisting of a polymer (α) of the general formula ##STR30## a polymer (β) of the general formula ##STR31## a polymer (γ) of the general formula ##STR32## mixtures thereof wherein R 1 to R 6 are the same or different and each represent a hydrogen atom, a (C 1 --C 4 ) alkyl group or a halogen atom, Ar represents ##STR33## wherein R 7 to R 15 are the same or different and each have the same meaning as defined with respect to R 1 to R 6 and X 1 to X 4 are the same or different and each represent --O--, --SO 2 --, --CH 2 --, --CO--, --COO--, --C(CH 3 ) 2 --, --S-- or --(CH 2 ) 2 --, Ar' represents ##STR34## wherein R 16 to R 20 are the same or different and each have the same meaning as defined with respect to R 1 to R 6 and X 5 has the same meaning as defined with respect to X 1 to X 4 , Ar" has the same meaning as defined with respect to Ar or Ar', B 1 to B 4 are the same or different and each represent --NCO or a substituent (A) formed by the reaction of --NCO with acrylic acid, methacrylic acid, a hydroxy acrylate or a hydroxy methacrylate, Q represents a hydrogen atom, or a hydrogen atom and a substituent (A'), provided that each of the rates of substituent introduction into the molecules of the polymers (α), (β) and (γ) as defined by the formulae ##EQU3## with respect to the polymer (α), the polymer (β) and the polymer (γ), respectively, is 0 to 50%, said substituent (A') being a member selected from residual groups of acrylic acid chloride, methacrylic acid chloride, glycidyl acrylate and glycidyl methacrylate, said residual groups being introduced alone or in combination, and m, n and p are integers corresponding to reduced viscosities of 0.1 to 2.0 with respect to the polymer (α) the polymer (β) and the polymer (γ), respectively; (2) 0.01 to 20 parts by weight of a photopolymerizationinitiator; and (3) 0.1 to 100 parts by weight of a compound having in its molecule at least one ethylenically unsaturated double bond.
Claim 2
Dependent Claim 385 words
A heat resistant photoresist composition comprising: (1) 100 parts by weight of a polymer selected from the group consisting of a polymer (α) of the general formula ##STR30## a polymer (β) of the general formula ##STR31## a polymer (γ) of the general formula ##STR32## mixtures thereof wherein R 1 to R 6 are the same or different and each represent a hydrogen atom, a (C 1 --C 4 ) alkyl group or a halogen atom, Ar represents ##STR33## wherein R 7 to R 15 are the same or different and each have the same meaning as defined with respect to R 1 to R 6 and X 1 to X 4 are the same or different and each represent --O--, --SO 2 --, --CH 2 --, --CO--, --COO--, --C(CH 3 ) 2 --, --S-- or --(CH 2 ) 2 --, Ar' represents ##STR34## wherein R 16 to R 20 are the same or different and each have the same meaning as defined with respect to R 1 to R 6 and X 5 has the same meaning as defined with respect to X 1 to X 4 , Ar" has the same meaning as defined with respect to Ar or Ar', B 1 to B 4 are the same or different and each represent --NCO or a substituent (A) formed by the reaction of --NCO with acrylic acid, methacrylic acid, a hydroxy acrylate or a hydroxy methacrylate, Q represents a hydrogen atom, or a hydrogen atom and a substituent (A'), provided that each of the rates of substituent introduction into the molecules of the polymers (α), (β) and (γ) as defined by the formulae ##EQU3## with respect to the polymer (α), the polymer (β) and the polymer (γ), respectively, is 0 to 50%, said substituent (A') being a member selected from residual groups of acrylic acid chloride, methacrylic acid chloride, glycidyl acrylate and glycidyl methacrylate, said residual groups being introduced alone or in combination, and m, n and p are integers corresponding to reduced viscosities of 0.1 to 2.0 with respect to the polymer (α) the polymer (β) and the polymer (γ), respectively; (2) 0.01 to 20 parts by weight of a photopolymerizationinitiator; and (3) 0.1 to 100 parts by weight of a compound having in its molecule at least one ethylenically unsaturated double bond.
Claim 3
Dependent Claim 31 words
A heat resistant photoresist composition according to claim 1, wherein said compound having in its molecule at least one ethylenically unsaturated double bond has 2 to 4 ethylenically unsaturated double bonds.
Claim 4
Dependent Claim 34 words
A heat resistant photoresist composition according to claim 1, wherein said photopolymerization initiator is a member selected from the group consisting of carbonyl compounds, peroxides, azo compounds, sulfur compounds, halogen compounds and mixtures thereof.
Claim 5
Dependent Claim 20 words
A heat resistant photoresist composition according to claim 3, wherein said photopolymerization initiator is a member selected from carbonyl compounds.
Claim 6
Dependent Claim 33 words
A heat resistant photoresist composition according to claim 1, wherein the amount of the compound having in its molecule at least one ethylenically unsaturated double bond is 0.5 to 50 parts by weight.
Claim 7
Dependent Claim 333 words
A process for the preparation of a heat resistant photoresist composition which comprises: reacting an organic polar solvent-soluble aromatic polyamide-imide having aromatic nuclei linked at their respective 1-and 3-positions and selected from the group consisting of a polyamide-imide (α') of the general formula ##STR35## a polyamide-imide (β') of the general formula ##STR36## a polyamide-imide (γ') of the general formula ##STR37## and mixtures thereof wherein R 1 to R 6 are the same or different and each represent a hydrogen atom, a (C 1 --C 4 ) alkyl group or a halogen atom, Ar represents ##STR38## wherein R 7 to R 15 are the same or different and each have the same meaning as defined with respect to R 1 to R 6 and X 1 to X 4 are the same or different and each represent --O--, --SO 2 --, --CH 2 --, --CO--, --COO--, --C(CH 3 ) 2 --, --S-- or --(CH 2 ) 2 --, Ar' represents ##STR39## wherein R 16 to R 20 are the same or different and each have the same meaning as defined with respect to R 1 to R 6 and X 5 has the same meaning as defined with respect to X 1 to X 4 , Ar" has the same meaning as defined with respect to Ar or Ar', and m', n' and p' are integers corresponding to reduced viscosities of 0.1 to 2.0 with respect to the polyamide-imide (α!), the polyamide-imide (β!) and the polyamide-imide (γ'), respectively, with a reactant selected from the group consisting of acrylic acid chloride, methacrylic acid chloride, glycidyl acrylate, glycidyl methacrylate, acrylic acid, methacrylic acid, a hydroxy acrylate, a hydroxy methacrylate and mixtures thereof, in the presence of an organic polar solvent, to produce a polymer; and mixing 100 parts by weight of the resulting polymer with 0.01 to 20 parts by weight of a photopolymerization initiator and 0.1 to 100 parts by weight of a compound having in its molecule at least one ethylenically unsaturated double bond.
Claim 8
Dependent Claim 333 words
A process for the preparation of a heat resistant photoresist composition which comprises: reacting an organic polar solvent-soluble aromatic polyamide-imide having aromatic nuclei linked at their respective 1-and 3-positions and selected from the group consisting of a polyamide-imide (α') of the general formula ##STR35## a polyamide-imide (β') of the general formula ##STR36## a polyamide-imide (γ') of the general formula ##STR37## and mixtures thereof wherein R 1 to R 6 are the same or different and each represent a hydrogen atom, a (C 1 --C 4 ) alkyl group or a halogen atom, Ar represents ##STR38## wherein R 7 to R 15 are the same or different and each have the same meaning as defined with respect to R 1 to R 6 and X 1 to X 4 are the same or different and each represent --O--, --SO 2 --, --CH 2 --, --CO--, --COO--, --C(CH 3 ) 2 --, --S-- or --(CH 2 ) 2 --, Ar' represents ##STR39## wherein R 16 to R 20 are the same or different and each have the same meaning as defined with respect to R 1 to R 6 and X 5 has the same meaning as defined with respect to X 1 to X 4 , Ar" has the same meaning as defined with respect to Ar or Ar', and m', n' and p' are integers corresponding to reduced viscosities of 0.1 to 2.0 with respect to the polyamide-imide (α!), the polyamide-imide (β!) and the polyamide-imide (γ'), respectively, with a reactant selected from the group consisting of acrylic acid chloride, methacrylic acid chloride, glycidyl acrylate, glycidyl methacrylate, acrylic acid, methacrylic acid, a hydroxy acrylate, a hydroxy methacrylate and mixtures thereof, in the presence of an organic polar solvent, to produce a polymer; and mixing 100 parts by weight of the resulting polymer with 0.01 to 20 parts by weight of a photopolymerization initiator and 0.1 to 100 parts by weight of a compound having in its molecule at least one ethylenically unsaturated double bond.

References Cited (Backward Citations)

US4048144A Cited
US3623870A Cited
US3918973A Cited
US3929713A Cited
US4106943A Cited
US4093461A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-06-17 1983-12-17 1984-06-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-06-17 1987-12-17 1988-06-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-06-17 1991-12-17 1992-06-17 $7700.00 Window Closed / Lapsed

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