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US4238476A Expired / Lapsed US ⏱️ 0.0 years remaining

Dentifrices

Assignee: Colgate Palmolive Co
•
Filing: 1979-05-10
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Granted: 1980-12-09
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Expires: 1999-05-10
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Abstract

Abstract A clear gel dentifrice containing "narrow cut" alkali metal lauryl sulphate in which the C 12 content is at least 90% by weight of the total alkyl content and a fluorine providing compound. The dentifrice contains a further anionic surface active agent which is a substantially saturated higher aliphatic acyl amide of a lower aliphatic amino carboxylic acid salt, a substantially saturated higher fatty aliphatic alcohol alkylene oxide sulphate or a mixture of mono- and di- phosphate esters.

Inventors

  • 👤 Kenneth Harvey

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 02:04
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/44; A61K8/442; A61K8/19; A61K8/26; A61K8/46; A61K8/463; A61K8/55; A61K8/556; A61K8/72; A61K8/73; A61K8/731; A61Q; A61Q11/00

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 263 words
A clear dentifrice comprising a dentifrice vehicle containing from 5% to 50% of a polishing agent having an empirical SiO 2 content of at least 70%, a particle size in the range from 1 to 35 microns, an essentially amorphous X-ray structure and an index of refraction between 1.44 and 1.47, a liquid phase having an index of refraction matching that of the polishing agent to permit clarity of the dentifrice, the liquid phase including humectant, a solid phase including a gelling agent or a thickening agent or a mixture thereof, a compound which provides from 0.01% to 1% of fluorine, selected from alkali metal fluorides and alkali metal monofluorophosphates, and from 0.1% to 5% of a surface active system comprising narrow cut alkali metal lauryl sulphate in which the C 12 content is at least 90% and a further anionic surface active agent selected from (a) alkali metal salts of a substantially saturated higher aliphatic acid amide of a lower aliphatic amino carboxlic acid compound, (b) alkali metal salts of a substantially saturated higher fatty aliphatic alcohol alkylene oxide sulphate, (c) an anionic phosphate esters comprising a mixture of a monoester of the formula ##STR4## and a diester of the formula ##STR5## wherein R is an alkyl group of from 10 to 20 carbon atoms, n is an integer from 1 to 6 and M is hydrogen, an alkali metal or ammonium and (d) mixtures thereof, the amount of the alkali metal lauryl sulphate being greater than the amount of the further anionic surface active agent, the ratio being at least 3:1.
Claim 2
Dependent Claim 263 words
A clear dentifrice comprising a dentifrice vehicle containing from 5% to 50% of a polishing agent having an empirical SiO 2 content of at least 70%, a particle size in the range from 1 to 35 microns, an essentially amorphous X-ray structure and an index of refraction between 1.44 and 1.47, a liquid phase having an index of refraction matching that of the polishing agent to permit clarity of the dentifrice, the liquid phase including humectant, a solid phase including a gelling agent or a thickening agent or a mixture thereof, a compound which provides from 0.01% to 1% of fluorine, selected from alkali metal fluorides and alkali metal monofluorophosphates, and from 0.1% to 5% of a surface active system comprising narrow cut alkali metal lauryl sulphate in which the C 12 content is at least 90% and a further anionic surface active agent selected from (a) alkali metal salts of a substantially saturated higher aliphatic acid amide of a lower aliphatic amino carboxlic acid compound, (b) alkali metal salts of a substantially saturated higher fatty aliphatic alcohol alkylene oxide sulphate, (c) an anionic phosphate esters comprising a mixture of a monoester of the formula ##STR4## and a diester of the formula ##STR5## wherein R is an alkyl group of from 10 to 20 carbon atoms, n is an integer from 1 to 6 and M is hydrogen, an alkali metal or ammonium and (d) mixtures thereof, the amount of the alkali metal lauryl sulphate being greater than the amount of the further anionic surface active agent, the ratio being at least 3:1.
Claim 3
Dependent Claim 28 words
A clear dentifrice as claimed in claim 1 wherein the ratio of narrow cut alkali metal lauryl sulphate to the further anionic surface active agent is about 20:1.
Claim 4
Dependent Claim 22 words
A clear dentifrice as claimed in claim 1 wherein the narrow cut alkali metal lauryl sulphate is narrow cut sodium lauryl sulphate.
Claim 5
Dependent Claim 20 words
A clear dentifrice as claimed in claim 1 wherein the liquid phase comprises glycerine, sorbitol solution or a mixture thereof.
Claim 6
Dependent Claim 16 words
A clear dentifrice as claimed in claim 1 wherein the solid phase contains sodium carboxymethyl cellulose.
Claim 7
Dependent Claim 16 words
A clear dentifrice as claimed in claim 1 wherein the compound providing fluorine is sodium monofluorophosphate.
Claim 8
Dependent Claim 25 words
A clear dentifrice as claimed in claim 1 wherein the particle size of the polishing agent is in the range from 2 to 20 microns.
Claim 9
Dependent Claim 15 words
A clear dentifrice as claimed in claim 1 wherein the polishing agent is sodium aluminosilicate.
Claim 10
Dependent Claim 19 words
A clear dentifrice as claimed in claim 1 wherein the further anionic surface active agent is sodium N-lauroyl sarcosinate.
Claim 11
Dependent Claim 25 words
A clear dentifrice as claimed in claim 1 wherein the further anionic surface active agent is a C 12-14 alcohol (ethylene oxide) 2-3:1 sodium sulphate.
Claim 12
Dependent Claim 44 words
A clear dentifrice as claimed in claim 1 wherein the further anionic surface active agent is a said anionic phosphate ester mixture wherein in the formulae of the monoester and the diester R is an alkyl group containing from 16 to 18 carbon atoms.
Claim 13
Dependent Claim 29 words
A clear dentifrice as claimed in claim 11 wherein the further anionic surface active agent is a mixture of the sodium salts of the anionic phosphate monoester and diester.

References Cited (Backward Citations)

US2054742A Cited
US3538230A Cited
US3662059A Cited
US3927202A Cited
US4036950A Cited
US4123517A Cited
US4130636A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-09 1984-06-09 1984-12-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-09 1988-06-09 1988-12-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-09 1992-06-09 1992-12-09 $7700.00 Window Closed / Lapsed

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