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US4239866A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable coating composition

Assignee: BASF SE
•
Filing: 1979-05-25
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Granted: 1980-12-16
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Expires: 1999-05-25
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Abstract

Abstract Curable coating compositions which contain, as the binder, one or more olefinically unsaturated compounds containing urethane groups, with or without one or more olefinically unsaturated compounds copolymerizable therewith, in which the olefinically unsaturated compound containing urethane groups is a reaction product of vinyl isocyanate and a compound which contains at least one hydroxyl group and at least one radical of an ester of an α,β-olefinically unsaturated carboxylic acid of 3 to 6 carbon atoms. The compositions may, for example, be used for the manufacture of coatings which can be cured with electron beams.

Inventors

  • 👤 Christian Reitel
  • 👤 Lutz Goethlich

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 10:48
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/02; C09D11/10; C09D11/101; C08; C08F; C08F120/00; C08F120/02; C08F120/10; C08F120/34; C08F120/36; C08F299/00; C08F299/02; C08F299/04; C08F299/0478; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/81; C08G18/8108; C08G18/8141; C08G18/815; C08G18/8158; C08G18/8175; Y; Y10; Y10S; Y10S525/00; Y10S525/92

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 136 words
A radiation-curable binder for coating compositions which binder comprises one or more olefinically unsaturated compounds of the general formula (I) ##STR4## where x and y may be identical or different and each is a number from 1 to 5, R is hydrogen or methyl, R' is a divalent linear or branched radical of 2 to 16 carbon atoms which may or may not contain oxa groups, or is a divalent cycloaliphatic radical of 5 to 12 carbon atoms, R" is a divalent linear or branched aliphatic, cycloaliphatic or aromatic radical of 6 to 15 carbon atoms and R'" is a radical which is derived from a polyhydric alcohol, a polyether-ol or a polyester-ol and which has a valency corresponding to the sum of x+y, with or without additional other radiation-curable olefinically unsaturated compounds having acrylyl radicals.
Claim 2
Dependent Claim 136 words
A radiation-curable binder for coating compositions which binder comprises one or more olefinically unsaturated compounds of the general formula (I) ##STR4## where x and y may be identical or different and each is a number from 1 to 5, R is hydrogen or methyl, R' is a divalent linear or branched radical of 2 to 16 carbon atoms which may or may not contain oxa groups, or is a divalent cycloaliphatic radical of 5 to 12 carbon atoms, R" is a divalent linear or branched aliphatic, cycloaliphatic or aromatic radical of 6 to 15 carbon atoms and R'" is a radical which is derived from a polyhydric alcohol, a polyether-ol or a polyester-ol and which has a valency corresponding to the sum of x+y, with or without additional other radiation-curable olefinically unsaturated compounds having acrylyl radicals.
Claim 3
Dependent Claim 12 words
The binder of claim 1, wherein R'" is derived from a polyester-ol.
Claim 4
Dependent Claim 12 words
The binder of claim 1, wherein R'" is derived from a polyether-ol.
Claim 5
Dependent Claim 13 words
The binder of claim 1, wherein R'" is derived from a polyhydric alcohol.
Claim 6
Dependent Claim 30 words
The binder of claim 2, 3 or 4, wherein said additional other radiation-curable olefinically unsaturated compounds have molecular weights of from 70 to 20,000 and boiling points above 50° C.
Claim 7
Dependent Claim 137 words
The binder of claim 2, 3 or 4, wherein said additional other radiation-curable olefinically unsaturated compounds are one or more materials selected from the group consisting of esters of unsaturated monocarboxylic or dicarboxylic acids with aliphatic, cycloaliphatic or aromatic-aliphatic monohydric to tetrahydric alcohols of 3 to 20 carbon atoms, amides of acrylic acid or methacrylic acid, which may or may not be substituted by alkyl, alkoxyalkyl or hydroxyalkyl at the nitrogen, unsaturated polyesters having a molecular weight of from 500 to 5,000 and containing from 0.5 to 10 double bonds per 1,000 molecular weight units, unsaturated epoxy resins, unsaturated polyurethanes obtained from hydroxyalkyl acrylates, diisocyanates and polyols or polyamines, reaction products or copolymers, containing maleic anhydride groups, with unsaturated alcohols, and reaction products of acrylic ester copolymers or polyesters containing carboxylic acid groups, with olefinically unsaturated epoxides.
Claim 8
Dependent Claim 44 words
The binder of claim 2, which is the reaction product of vinyl isocyanate with a compound selected from the group consisting of hydroxypropyl acrylate, hydroxybutyl acrylate, hydroxyethyl acrylate and the adduct of 2 moles of acrylic acid with 1 mole of butanediol diglycidyl ether.
Claim 9
Dependent Claim 23 words
The binder of claim 5, wherein the total composition contains up to 95% by weight of said additional other radiation-curable olefinically unsaturated compounds.
Claim 10
Dependent Claim 23 words
The binder of claim 5, wherein the total composition contains up to 70% by weight of said additional other radiation-curable olefinically unsaturated compounds.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-16 1984-06-16 1984-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-16 1988-06-16 1988-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-16 1992-06-16 1992-12-16 $7700.00 Window Closed / Lapsed

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