Abstract Disclosed herein are cross-linked lignin gels which have been found useful as pesticide carriers in controlled release pesticide systems. The carrier is a highly reswellable cross-linked lignin gel prepared by reacting alkali lignin with from 1 mole to 10 moles of cross-linking agent, such as formaldehyde, per 1,000 grams of lignin. An aqueous solution of lignin and the cross-linking agent is reacted at elevated temperatures until cross-linking occurs to the point where a discernible increase in viscosity takes place and the gel is formed. The gels are allowed to dehydrate, and the pesticide in an amount from 0.1:1.0 to 2:1 (pesticide to carrier) is included by reswelling the dehydrated gel in an aqueous solution of the pesticide.
A cross-linked lignin gel for use as a controlled release herbicide carrier comprising the reaction product of an aqueous solution of alkali lignin at a concentration of 10% to 40% weight by volume with from 1 to 10 moles of a cross-linking agent selected from the group consisting of formaldehyde, glyoxal, and glutaric dialdehyde reacted at a temperature between about 10° C. and 100° C. until a reversibly swellable gel is formed.
Claim 2
Dependent Claim
72 words
A cross-linked lignin gel for use as a controlled release herbicide carrier comprising the reaction product of an aqueous solution of alkali lignin at a concentration of 10% to 40% weight by volume with from 1 to 10 moles of a cross-linking agent selected from the group consisting of formaldehyde, glyoxal, and glutaric dialdehyde reacted at a temperature between about 10° C. and 100° C. until a reversibly swellable gel is formed.
Claim 3
Dependent Claim
12 words
The lignin gel of claim 1 wherein said cross-linking agent is formaldehyde.
Claim 4
Dependent Claim
28 words
The lignin gel of claim 1 wherein said cross-linking agent is glutaric dialdehyde and from 0.1 to 5 moles per 1,000 grams of lignin of epichlorohydrin is added.
Claim 5
Dependent Claim
36 words
The lignin gel of claim 1 wherein said lignin is at a concentration from 20% to 25% and said reaction is carried out at about 80° C. to 95° C. for from 5 to 9 hours.
Claim 6
Dependent Claim
71 words
In a controlled release herbicide composition comprising a lignin carrier and a herbicide physically interspersed throughout at a weight ratio of 0.1:1 to 2:1 herbicide-to-lignin carrier which herbicide is released over an extended period of time under environmental conditions indigenous to agriculture, the improvement comprising the cross-linked, reversibly swellable alkali lignin gel of claim 1, and said controlled release composition being used in an amount containing an effective amount of herbicide.