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US4250240A Expired / Lapsed US ⏱️ 0.0 years remaining

Photosensitive material for use in electrophotography

Assignee: Ricoh Co Ltd
•
Filing: 1979-06-19
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Granted: 1981-02-10
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Expires: 1999-06-19
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Abstract

Abstract The present invention relates to a photosensitive material for use in electrophotography comprising a photoconductive layer on which there is a transparent protective layer consisting essentially of a substance resulting from partial hydrolysis of a mixture of (a) a compound having the following general formula I, (b) a copolymer of a compound having the general formula II with a compound having the general formula III or maleic anhydride and (c) a compound having the general formula IV, (1) General formula I (R.sup.1).sub.l Si(OR.sup.2).sub.m [wherein R 1 is a C 1-4 alkyl radical, vinyl radical, γ-methacryloxypropyl radical, phenyl radical, γ-glycidoxypropyl radical, γ-chloropropyl radical, γ-mercaptopropyl radical, γ-β(aminoethyl)γ-aminopropyl radical or γ-aminopropyl radical; R 2 is a hydroxyethylalkyl ether radical or C 1-4 alkyl radical; l is 0-2; and m is 2-4.] (2) General formula II ##STR1## [wherein R 3 is hydrogen or a methyl radical; R 4 is hydrogen or a C 1-4 alkyl radical; n is 1-4; and q is 1-3.] (3) General formula III ##STR2## [wherein R 5 is hydrogen or a methyl radical; R 6 is --COOR 7 (R 7 is hydrogen or a C 1-12 alkyl radical, hydroxyalkyl radical, glycidyl radical or dimethylaminoalkyl radical), --CN, --OCOCH 3 , --CONH 2 , ##STR3## (4) General formula IV ##STR4## [wherein R 8 is a C 1-4 alkyl radical or phenyl radical; z is 2-25.]

Inventors

  • 👤 Masaru Shimada
  • 👤 Shoji Maruyama
  • 👤 Hiroshi Tamura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 12:47
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/14; G03G5/147; G03G5/14708; G03G5/14713; G03G5/14717; G03G5/14734; G03G5/14739; G03G5/14786; Y; Y10; Y10S; Y10S430/00; Y10S430/162

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 244 words
A photosensitive material for use in electrophotography which comprises an electroconductive substrate, a photoconductive layer coated on said electroconductive substrate and a transparent protective layer coated on said photoconductive layer, said transparent protective layer consisting essentially of a material obtained by partial hydrolysis of a mixture of (a) from 70 to 98.9% by weight of one or a mixture of two or more compounds having the formula (R.sup.1).sub.l Si(OR.sup.2).sub.m wherein R 1 is C 1-4 alkyl, vinyl, γ-methacryloxypropyl, phenyl, γ-glycidoxypropyl, γ-chloropropyl, γ-mercaptopropyl, γ-β(aminoethyl)γ-aminopropyl or γ-aminopropyl; R 2 is a hydroxyethylalkyl ether or C 1-4 alkyl; l is 0 to 2; m is 2 to 4, (b) from 1 to 20% by weight of one or a mixture of two or more copolymers of first monomer having the formula ##STR9## wherein R 3 is hydrogen or methyl; R 4 is hydrogen or C 1-4 alkyl; n is 1 to 4; and q is 1 to 3, with second monomer selected from the group consisting of maleic anhydride and monomer having the formula ##STR10## wherein R 5 is hydrogen or methyl; R 6 is --COOR 7 , --CN, --OCOCH 3 , --CONH 2 , ##STR11## and wherein R 7 is hydrogen or C 1-12 alkyl, hydroxyalkyl, glycidyl or dimethylaminoalkyl, and (c) from 0.1 to 10% by weight of one or a mixture of two or more compounds having the formula ##STR12## wherein R 8 is C 1-4 alkyl or phenyl; and z is 2 to 25.
Claim 2
Dependent Claim 244 words
A photosensitive material for use in electrophotography which comprises an electroconductive substrate, a photoconductive layer coated on said electroconductive substrate and a transparent protective layer coated on said photoconductive layer, said transparent protective layer consisting essentially of a material obtained by partial hydrolysis of a mixture of (a) from 70 to 98.9% by weight of one or a mixture of two or more compounds having the formula (R.sup.1).sub.l Si(OR.sup.2).sub.m wherein R 1 is C 1-4 alkyl, vinyl, γ-methacryloxypropyl, phenyl, γ-glycidoxypropyl, γ-chloropropyl, γ-mercaptopropyl, γ-β(aminoethyl)γ-aminopropyl or γ-aminopropyl; R 2 is a hydroxyethylalkyl ether or C 1-4 alkyl; l is 0 to 2; m is 2 to 4, (b) from 1 to 20% by weight of one or a mixture of two or more copolymers of first monomer having the formula ##STR9## wherein R 3 is hydrogen or methyl; R 4 is hydrogen or C 1-4 alkyl; n is 1 to 4; and q is 1 to 3, with second monomer selected from the group consisting of maleic anhydride and monomer having the formula ##STR10## wherein R 5 is hydrogen or methyl; R 6 is --COOR 7 , --CN, --OCOCH 3 , --CONH 2 , ##STR11## and wherein R 7 is hydrogen or C 1-12 alkyl, hydroxyalkyl, glycidyl or dimethylaminoalkyl, and (c) from 0.1 to 10% by weight of one or a mixture of two or more compounds having the formula ##STR12## wherein R 8 is C 1-4 alkyl or phenyl; and z is 2 to 25.
Claim 3
Dependent Claim 33 words
A photosensitive material according to claim 1 wherein the component (a) is at least one substrate selected from the group consisting of methyltrimethoxy silane, vinyltriethoxy silane, γ-methacryloxypropyltrimethoxy silane, tetraethoxy silane and vinyltrihydroxyethylmethylether silane.
Claim 4
Dependent Claim 14 words
A photosensitive material according to claim 1 wherein the first monomer is γ-methacryloxypropyltrimethoxy silane.
Claim 5
Dependent Claim 34 words
A photosensitive material according to claim 1 wherein the second monomer is at least one monomer selected from the group consisting of styrene, vinyl acetate, methyl methacrylate, butyl acrylate, glycidyl methacrylate and acrylic acid.
Claim 6
Dependent Claim 18 words
A photosensitive material according to claim 1 wherein the thickness of the transparent protective layer is 5-20 μm.

References Cited (Backward Citations)

US3312547A Cited
US3775115A Cited
US4148637A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-10 1984-08-11 1985-02-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-10 1988-08-11 1989-02-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-10 1992-08-11 1993-02-10 $7700.00 Window Closed / Lapsed

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