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US4254168A Expired / Lapsed US ⏱️ 0.0 years remaining

Chip-resistant pigmented polyurethane protective coating

Assignee: 3M Co
•
Filing: 1979-07-27
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Granted: 1981-03-03
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Expires: 1999-07-27
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Abstract

Abstract The invention is a method of coating a substrate with a chip-resistant polyurethane protective coating which contains pigmented acrylic lacquer, acrylic enamel or nitro-cellulose lacquer. This blend provides a coating composition which matches the colors of the existing pigmented protective surface of a substrate such as an automobile. The method involves supplying to a substrate a liquid curable primary amine-free polyurethane coating composition containing a catalyzed mixture of polyester polyol, polyisocyanate compound, and organic solvent, permitting the organic solvent to flash evaporate until the coating exhibits a tacky surface condition, and then applying sufficient uniform coats to cover the substrate with a mixture of the unpigmented polyurethane coating composition and a liquid pigmented protective coating composition selected from the group consisting of acrylic lacquer, acrylic enamel, and nitrocellulose reduced with compatible solvent for use.

Inventors

  • 👤 Norman J. Monson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 13:51
CPC Classifications
C; C09; C09D; C09D175/00; C09D175/04; C09D175/06; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31573; Y10T428/31576; Y10T428/31591

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 246 words
Method of applying to a substrate a chip-resistant pigmented polyurethane protective coating particularly suited for matching existing pigmented protected surfaces on said substrate wherein said existing protected surface is provided by an acrylic lacquer, acrylic enamel or nitrocellulose lacquer containing the same pigmentation, said method comprising: (1) blending (a) liquid curable primary amine-free non-coloring polyurethane coating composition curable to form a polyurethane having an elongation at break of at least 75% and being formed of a catalyzed mixture of polyester polyol having more than one terminal hydroxyl group and an equivalent weight between 250 and 1500, sufficient polyisocyanate compound characterized by having at least two terminal isocyanate groups each attached to a non-benzenoid carbon to provide an NCO:OH ratio of about 2:1 to about 0.8:1, and compatible organic solvent to make a solids content about 20% to 70% by weight and a vicosity of about 20 to 300 cps as determined using a Brookfield RVF viscometer at 25° C. using a No. 1 spindle at 20 rpm; and (b) liquid pigmented protective coating composition selected from the group consisting of acrylic lacquer, acrylic enamel and nitrocellulose lacquer reduced with compatible solvent for use in a wet volume ratio of pigmented protective coating composition to polyurethane coating composition of about 2:1 to 1:20; (2) applying at least one coating of the resultant blend to said surface to provide a uniform dry coating thickness of from about 1 to 20 mils; and (3) permitting said coating to dry.
Claim 2
Dependent Claim 246 words
Method of applying to a substrate a chip-resistant pigmented polyurethane protective coating particularly suited for matching existing pigmented protected surfaces on said substrate wherein said existing protected surface is provided by an acrylic lacquer, acrylic enamel or nitrocellulose lacquer containing the same pigmentation, said method comprising: (1) blending (a) liquid curable primary amine-free non-coloring polyurethane coating composition curable to form a polyurethane having an elongation at break of at least 75% and being formed of a catalyzed mixture of polyester polyol having more than one terminal hydroxyl group and an equivalent weight between 250 and 1500, sufficient polyisocyanate compound characterized by having at least two terminal isocyanate groups each attached to a non-benzenoid carbon to provide an NCO:OH ratio of about 2:1 to about 0.8:1, and compatible organic solvent to make a solids content about 20% to 70% by weight and a vicosity of about 20 to 300 cps as determined using a Brookfield RVF viscometer at 25° C. using a No. 1 spindle at 20 rpm; and (b) liquid pigmented protective coating composition selected from the group consisting of acrylic lacquer, acrylic enamel and nitrocellulose lacquer reduced with compatible solvent for use in a wet volume ratio of pigmented protective coating composition to polyurethane coating composition of about 2:1 to 1:20; (2) applying at least one coating of the resultant blend to said surface to provide a uniform dry coating thickness of from about 1 to 20 mils; and (3) permitting said coating to dry.
Claim 3
Dependent Claim 26 words
The method of claim 1 wherein there is initially coated on the surface of said substrate at least one unpigmented coating of said polyurethane coating composition.
Claim 4
Dependent Claim 14 words
The method of claim 1 wherein said substrate is coated initially with a primer.
Claim 5
Dependent Claim 275 words
Method of applying to a substrate a chip-resistant pigmented polyurethane protective coating particularly suited for matching existing pigmented surfaces on said substrate wherein said existing protected surface is provided by an acrylic lacquer, acrylic enamel or nitrocellulose lacquer containing the same pigmentation, said method comprising: (1) applying to said substrate at least three uniform coats comprising an unpigmented liquid curable primary amine-free nondiscoloring polyurethane coating composition curable to form a polyurethane having an elongation at break of at least 75% and being formed of a catalyzed mixture of polyester polyol having more than one terminal hydroxyl group and an equivalent weight between 250 and 1500, sufficient polyisocyanate compound characterized by having at least two terminal isocyanate groups each attached to a non-benzenoid carbon to provide an NCO:OH ratio of about 2:1 to about 0.8:1, and compatible organic solvent to make a solids content about 20% to 70% by weight and a viscosity of about 20 to 300 cps as determined using a Brookfield RVF viscometer at 25° C. using a No. 1 spindle at 20 rpm; (2) permitting said organic solvent to flash evaporate to provide a coating having a tacky surface condition between coats; (3) applying sufficient uniform coats of a blend of said unpigmented polyurethane coating composition and a liquid pigmented protective coating composition selected from the group consisting of acrylic lacquer, acrylic enamel and nitrocellulose lacquer reduced with compatible solvent for use in a wet volume ratio of pigmented protective coating composition to polyurethane coating composition of about 2:1 to 1:20 to provide a uniform dry coating thickness of from about 1 to 20 mils; and (4) permitting said coats to dry.
Claim 6
Dependent Claim 275 words
Method of applying to a substrate a chip-resistant pigmented polyurethane protective coating particularly suited for matching existing pigmented surfaces on said substrate wherein said existing protected surface is provided by an acrylic lacquer, acrylic enamel or nitrocellulose lacquer containing the same pigmentation, said method comprising: (1) applying to said substrate at least three uniform coats comprising an unpigmented liquid curable primary amine-free nondiscoloring polyurethane coating composition curable to form a polyurethane having an elongation at break of at least 75% and being formed of a catalyzed mixture of polyester polyol having more than one terminal hydroxyl group and an equivalent weight between 250 and 1500, sufficient polyisocyanate compound characterized by having at least two terminal isocyanate groups each attached to a non-benzenoid carbon to provide an NCO:OH ratio of about 2:1 to about 0.8:1, and compatible organic solvent to make a solids content about 20% to 70% by weight and a viscosity of about 20 to 300 cps as determined using a Brookfield RVF viscometer at 25° C. using a No. 1 spindle at 20 rpm; (2) permitting said organic solvent to flash evaporate to provide a coating having a tacky surface condition between coats; (3) applying sufficient uniform coats of a blend of said unpigmented polyurethane coating composition and a liquid pigmented protective coating composition selected from the group consisting of acrylic lacquer, acrylic enamel and nitrocellulose lacquer reduced with compatible solvent for use in a wet volume ratio of pigmented protective coating composition to polyurethane coating composition of about 2:1 to 1:20 to provide a uniform dry coating thickness of from about 1 to 20 mils; and (4) permitting said coats to dry.

References Cited (Backward Citations)

US3396210A Cited
US3458459A Cited
US3401143A Cited
US3557043A Cited
US3769069A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-02 1984-09-01 1985-03-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-02 1988-09-01 1989-03-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-02 1992-09-01 1993-03-03 $7700.00 Window Closed / Lapsed

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