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US4258079A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of continuous films of diacetylenic polymers

Assignee: International Business Machines Corp
•
Filing: 1979-12-13
•
Granted: 1981-03-24
•
Expires: 1999-12-13
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Abstract

Abstract Continuous films are formed on a substrate by coating said substrate with a solution of a diacetylenic prepolymer in a liquid phenylacetylene solvent and reacting the solvent with the prepolymer.

Inventors

  • 👤 James Economy
  • 👤 Mary Ann Flandera
  • 👤 Cheng-Yih Liu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:49
CPC Classifications
B; B05; B05D; B05D3/00; B05D3/10; C; C09; C09D; C09D4/00

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 75 words
A process for preparing a continuous film of a diacetylene polymer, said process comprising the steps of: (1) forming a solution of a diacetylenic prepolymer in a solvent which is liquid phenylacetylene compound having the formula: ##STR2## wherein R is H, halogen, lower alkyl or lower alkoxy; (2) coating a substrate with said solution to form a film thereon; and (3) cross-linking the diacetylene prepolymer and reacting the residual phenylacetylene solvent into the polymer structure.
Claim 2
Dependent Claim 75 words
A process for preparing a continuous film of a diacetylene polymer, said process comprising the steps of: (1) forming a solution of a diacetylenic prepolymer in a solvent which is liquid phenylacetylene compound having the formula: ##STR2## wherein R is H, halogen, lower alkyl or lower alkoxy; (2) coating a substrate with said solution to form a film thereon; and (3) cross-linking the diacetylene prepolymer and reacting the residual phenylacetylene solvent into the polymer structure.
Claim 3
Dependent Claim 17 words
A process as claimed in claim 1 wherein the cross-linking is completed by the application of heat.
Claim 4
Dependent Claim 17 words
A process as claimed in claim 1 wherein the cross-linking is completed by the application of radiation.
Claim 5
Dependent Claim 17 words
A process a claimed in claim 1 wherein the substrate is coated by spin-coating of the solution.
Claim 6
Dependent Claim 13 words
A process as claimed in claim 1 wherein the phenylacetylene compound is phenylacetylene.
Claim 7
Dependent Claim 15 words
A process as claimed in claim 1 wherein the diacetylene prepolymer is a poly(triethynylbenzene) prepolymer.
Claim 8
Dependent Claim 46 words
A process for preparing a continuous polymeric film, said process comprising the steps of (1) forming a solution of a poly(triethynylbenzene) prepolymer in phenylacetylene; (2) spin-coating the substrate with said solution to form a film thereon; and (3) curing said film by the application of heat.
Claim 9
Dependent Claim 46 words
A process for preparing a continuous polymeric film, said process comprising the steps of (1) forming a solution of a poly(triethynylbenzene) prepolymer in phenylacetylene; (2) spin-coating the substrate with said solution to form a film thereon; and (3) curing said film by the application of heat.

References Cited (Backward Citations)

US3300456A Cited
US3494326A Cited
US3857821A Cited
US3935167A Cited
CA1043945A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-23 1984-09-22 1985-03-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-23 1988-09-22 1989-03-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-23 1992-09-22 1993-03-24 $7700.00 Window Closed / Lapsed

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