US4265668A
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High dielectric constant type ceramic composition
Assignee: TDK Corp
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Filing: 1979-10-29
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Granted: 1981-05-05
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Expires: 1999-10-29
Abstract
Abstract A basic ceramic composition of high dielectric constant type ceramic composition comprises from 68.67 to 69.19% of PbO, from 3.67 to 4.09% of MgO, from 24.17 to 26.99% of Nb2O5 and from 0.25 to 2.97% of TiO2, all percentages being by weight. Modified composition may comprise additive of Pb(Mn2/3W1/3)O3, Pb(Mn1/3Nb2/3)O3, Pb(Mn1/3Ta2/3)O3, Pb(Mn1/2W1/2)O3, MnO, and MgO. Modified composition may comprise Ba, Sr and Ca, which replace Pb of the basic ceramic composition. In a modified composition, the content of B site elements may be larger than that of A site element of an ABO3 crystal of the high dielectric constant type ceramic composition. A high dielectric constant, low dielectric loss, low temperature dependence of capacitance, high insulation resistance and a low sintering temperature are provided by the ceramic compositions of the present invention.
Inventors
- 👤 Shinobu Fujiwara
- 👤 Kiyoshi Furukawa
- 👤 Nobuaki Kikuchi
- 👤 Osamu Iizawa
- 👤 Hitoshi Tanaka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 23:35
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/01; C04B35/495; C04B35/497; C04B35/499; H; H01; H01B; H01B3/00; H01B3/02; H01B3/12; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; H01G4/1209; H01G4/1254; H01G4/1263
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
54 words
A high dielectric constant type ceramic composition, characterized in that said composition consists essentially of a basic ceramic composition of from 68.67 to 69.19% of PbO, from 3.67 to 4.09% of MgO, 24.17 to 26.99% of Nb 2 O 5 and from 0.25 to 2.97% of TiO 2 , all percentages being by weight.
Claim 2
Dependent Claim
54 words
A high dielectric constant type ceramic composition, characterized in that said composition consists essentially of a basic ceramic composition of from 68.67 to 69.19% of PbO, from 3.67 to 4.09% of MgO, 24.17 to 26.99% of Nb 2 O 5 and from 0.25 to 2.97% of TiO 2 , all percentages being by weight.
Claim 3
Dependent Claim
48 words
A high dielectric constant type ceramic composition according to claim 1, characterized in that said composition comprises from 68.7 to 69.0% of PbO; from 3.85 to 4.05% of MgO; from 25.45 to 26.50% of Nb 2 O 5 , and; from 0.70 to 1.75% of TiO 2 .
Claim 4
Dependent Claim
49 words
A high dielectric constant type ceramic composition according to claim 1, characterized in that said composition comprises said basic ceramic composition and Pb(Mn 2/3 W 1/3 )O 3 in an amount of from 0.05 to 5.0 parts by weight, based on 100 weight parts of the basic ceramic composition.
Claim 5
Dependent Claim
32 words
A high dielectric constant type ceramic composition according to claim 3, characterized in that the amount of said Pb(Mn 2/3 W 1/3 )O 3 is from 0.1 to 0.6 parts by weight.
Claim 6
Dependent Claim
49 words
A high dielectric constant type ceramic composition according to claim 1, characterized in that said composition comprises said basic ceramic composition and Pb(Mn 1/3 Nb 2/3 )O 3 in an amount of from 0.05 to 5.0 parts by weight based on 100 weight parts of the basic ceramic composition.
Claim 7
Dependent Claim
32 words
A high dielectric constant type ceramic composition according to claim 5, characterized in that the amount of said Pb(Mn 1/3 Nb 2/3 )O 3 is from 0.1 to 1.0 part by weight.
Claim 8
Dependent Claim
49 words
A high dielectric constant type ceramic composition according to claim 1, characterized in that said composition comprises said basic ceramic composition and Pb(Mn 1/3 Ta 2/3 )O 3 in an amount of from 0.05 to 5.0 parts by weight based on 100 weight parts of the basic ceramic composition.
Claim 9
Dependent Claim
32 words
A high dielectric constant type ceramic composition according to claim 7, characterized in that the amount of said Pb(Mn 1/3 Ta 2/3 )O 3 is from 0.5 to 3.0 parts by weight.
Claim 10
Dependent Claim
49 words
A high dielectric constant type ceramic composition according to claim 1, characterized in that said composition comprises said basic ceramic composition and Pb(Mn 1/2 W 1/2 )O 3 in an amount of from 0.05 to 5.0 parts by weight, based on 100 weight parts of the basic ceramic composition.
Claim 11
Dependent Claim
32 words
A high dielectric constant type ceramic composition according to claim 9, characterized in that the amount of said Pb(Mn 1/2 W 1/2 )0 3 is from 0.1 to 1.5 parts by weight.
Claim 12
Dependent Claim
44 words
A high dielectric constant type ceramic composition according to claim 1, characterized in that said composition comprises said basic ceramic composition and MnO in an amount of from 0.001 to 1.5 parts by weight, based on 100 weight parts of the basic ceramic composition.
Claim 13
Dependent Claim
27 words
A high dielectric constant type ceramic composition according to claim 11, characterized in that the amount of said MnO is from 0.005 to 0.2 parts by weight.
Claim 14
Dependent Claim
93 words
A high dielectric constant type ceramic composition according to claim 1, wherein said basic ceramic composition is mainly composed of a double oxide of Pb(Mg 1/3 Nb 2/3 )O 3 and a double oxide of PbTiO 3 , characterized in that said composition comprises an Mg oxide additive in addition to said double oxides and the amount of the Mg oxide additive is not more than 25 parts by weight, based on 100 parts by weight of an Mg oxide contained in the double oxide of Pb(Mg 1/3 Nb 2/3 )O 3 .
Claim 15
Dependent Claim
29 words
A high dielectric constant type ceramic composition according to claim 13, characterized in that the amount of said Mg oxide additive is from 3 to 9 parts by weight.
Claim 16
Dependent Claim
44 words
A high dielectric constant type ceramic composition according to claim 13, characterized in that said ceramic comprises Pb(Mn 1/3 Nb 2/3 )O 3 in an amount of from 0.05 to 5.0 parts by weight based on 100 parts by weight of said double oxides.
Claim 17
Dependent Claim
85 words
A high dielectric constant type ceramic composition according to claim 1, wherein said basic composition is mainly composed of a double oxide of Pb(Mg 1/3 Nb 2/3 )O 3 and a double oxide of PbTiO 3 , characterized in that said composition comprises said basic ceramic composition and at least one additive element selected from the group consisting of barium, strontium and calcium in an amount of not more than 10 atomic parts, based on 100 atomic parts of lead contained in said double oxides.
Claim 18
Dependent Claim
30 words
A high dielectric constant type ceramic composition according to claim 16, characterized in that the amount of said at least one additive element is from 3 to 10 atomic parts.
Claim 19
Dependent Claim
70 words
A high dielectric constant type ceramic composition according to claim 1, wherein said basic ceramic composition is mainly composed of a double oxide of Pb(Mg 1/3 Nb 2/3 )O 3 and a double oxide of PbTiO 3 , and said double oxides are expressed by a form of A x B y O 3 , characterized in that the molar ratio of A/B is from 0.9200 to less than 1.0000.
Claim 20
Dependent Claim
24 words
A high dielectric constant type ceramic composition according to claim 18, characterized in that said molar ratio of A/B is from 0.950 to 0.982.
Claim 21
Dependent Claim
86 words
A high dielectric constant type ceramic composition, characterized in that said composition consists essentially of from 60 to 98 molar% of Pb(Mg 1/3 Nb 2/3 )O 3 and from 2 to 40 molar% of PbTiO 3 , and further, from 0.2 to 8.0 parts by weight of at least one additive oxide selected from the group consisting of Bi 2 O 3 and WO 3 , based on 100 parts by weight of total weight of Pb(Mg 1/3 Nb 2/3 )O 3 and PbTiO 3 .
Claim 22
Dependent Claim
86 words
A high dielectric constant type ceramic composition, characterized in that said composition consists essentially of from 60 to 98 molar% of Pb(Mg 1/3 Nb 2/3 )O 3 and from 2 to 40 molar% of PbTiO 3 , and further, from 0.2 to 8.0 parts by weight of at least one additive oxide selected from the group consisting of Bi 2 O 3 and WO 3 , based on 100 parts by weight of total weight of Pb(Mg 1/3 Nb 2/3 )O 3 and PbTiO 3 .
Claim 23
Dependent Claim
31 words
A high dielectric constant type ceramic composition according to claim 20, characterized in that the content of said at least one additive oxide is from 2 to 6 parts by weight.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-05-04 | 1984-11-03 | 1985-05-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-05-04 | 1988-11-03 | 1989-05-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-05-04 | 1992-11-03 | 1993-05-05 | $7700.00 | Window Closed / Lapsed |