US4267019A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Nuclear fuel particles
Assignee: General Atomics Corp
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Filing: 1978-05-10
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Granted: 1981-05-12
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Expires: 1998-05-10
Abstract
Abstract Coated nuclear fuel particles are made by first pyrolytically depositing low density carbon onto fuel cores and thereafter depositing a fission-product retentive, higher density exterior coating. In the improvement, cores of uranium, thorium or plutonium oxides are coated by co-depositing silicon carbide or zirconium carbide along with the low density pyrocarbon to create a uniform dispersion. Silicon or zirconium is deposited in an amount equal to at least about one atom for each fission anticipated during the fuel lifetime.
Inventors
- 👤 James L. Kaae
- 👤 George H. Reynolds
- 👤 Stewart A. Sterling
- 👤 Ling Yang
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 00:09
CPC Classifications
G; G21; G21C; G21C3/00; G21C3/42; G21C3/58; G21C3/62; G21C3/626; Y; Y02; Y02E; Y02E30/00; Y02E30/30
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
164 words
A nuclear fuel particle having a core of nuclear fuel material, a surrounding layer of low density pyrolytic carbon adjacent said core and a continuous layer of higher density material exterior of said low density layer wherein the improvement comprises said core being formed of nuclear fuel selected from the group consisting of uranium oxide, thorium oxide, plutonium oxide and mixtures thereof and therefore being subject to undergo thermal migration and also being subject to undergo the loss of oxygen upon fissioning which forms CO with carbon in said surrounding low density layer and wherein particles of a substance selected from the group consisting of silicon carbide, zirconium carbide and mixtures thereof are dispersed throughout said low density pyrolytic carbon layer whereby not only is the build-up of carbon monoxide within said high density outer layer effectively counteracted but thermal migration of said core is also reduced to such an extent that the amoeba effect is no longer of consequence during normal fuel life.
Claim 2
Dependent Claim
164 words
A nuclear fuel particle having a core of nuclear fuel material, a surrounding layer of low density pyrolytic carbon adjacent said core and a continuous layer of higher density material exterior of said low density layer wherein the improvement comprises said core being formed of nuclear fuel selected from the group consisting of uranium oxide, thorium oxide, plutonium oxide and mixtures thereof and therefore being subject to undergo thermal migration and also being subject to undergo the loss of oxygen upon fissioning which forms CO with carbon in said surrounding low density layer and wherein particles of a substance selected from the group consisting of silicon carbide, zirconium carbide and mixtures thereof are dispersed throughout said low density pyrolytic carbon layer whereby not only is the build-up of carbon monoxide within said high density outer layer effectively counteracted but thermal migration of said core is also reduced to such an extent that the amoeba effect is no longer of consequence during normal fuel life.
Claim 3
Dependent Claim
43 words
A nuclear fuel particle in accordance with claim 1 wherein said substance is present in an amount equal to at least about one atom of silicon or zirconium for each fission that is anticipated during the expected irradiation lifetime of said fuel particle.
Claim 4
Dependent Claim
25 words
A nuclear fuel particle in accordance with claim 1 wherein said substance is silicon carbide having an average particle size of about 1000A or less.
Claim 5
Dependent Claim
25 words
A nuclear fuel particle in accordance with claim 1 wherein substance is zirconium carbide having an average particle size of about one micron or less.
Claim 6
Dependent Claim
38 words
A nuclear fuel particle in accordance with claim 1 wherein said substance is present in an amount equal to between about 2 and about 30 weight percent based upon weight of pyrolytic carbon in said low density layer.
Claim 7
Dependent Claim
39 words
A nuclear fuel particle in accordance with claim 3 wherein said silicon carbide is present in an amount equal to between about 2 and about 30 weight percent based upon weight of pyrolytic carbon in said low density layer.
Claim 8
Dependent Claim
39 words
A nuclear fuel particle in accordance with claim 4 wherein said zirconium carbide is present in an amount equal to between about 2 and about 30 weight percent based upon weight of pyrolytic carbon in said low density layer.
Claim 9
Dependent Claim
166 words
A nuclear fuel particle having a spheroidal core of nuclear fuel material comprising uranium oxide, a surrounding layer of low density, poorly crystalline pyrolytic carbon adjacent said core having a density of not greater than 1.3 g./cm. 3 and a thickness between about 80 and about 120 microns, a continuous layer of higher density material exterior of said low density layer which provides a pressure-tight shell, said oxide core being subject to undergo thermal migration and to undergo the loss of oxygen upon fissioning which forms CO with carbon in said surrounding low density layer, and fine particles of zirconium carbide dispersed throughout said low density pyrolytic carbon layer, said ZrC being present in an amount equal to about 25 weight percent of said carbon in said low density layer, which fine particles effectively counteract the build-up of carbon monoxide within the high density outer layer and reduce the amoeba effect to such an extend that it is no longer of consequence during normal fuel life.
Claim 10
Dependent Claim
166 words
A nuclear fuel particle having a spheroidal core of nuclear fuel material comprising uranium oxide, a surrounding layer of low density, poorly crystalline pyrolytic carbon adjacent said core having a density of not greater than 1.3 g./cm. 3 and a thickness between about 80 and about 120 microns, a continuous layer of higher density material exterior of said low density layer which provides a pressure-tight shell, said oxide core being subject to undergo thermal migration and to undergo the loss of oxygen upon fissioning which forms CO with carbon in said surrounding low density layer, and fine particles of zirconium carbide dispersed throughout said low density pyrolytic carbon layer, said ZrC being present in an amount equal to about 25 weight percent of said carbon in said low density layer, which fine particles effectively counteract the build-up of carbon monoxide within the high density outer layer and reduce the amoeba effect to such an extend that it is no longer of consequence during normal fuel life.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-05-11 | 1984-11-10 | 1985-05-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-05-11 | 1988-11-10 | 1989-05-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-05-11 | 1992-11-10 | 1993-05-12 | $7700.00 | Window Closed / Lapsed |