Photoresist formulations

Claim 2

In a photopolymerizable composition for use in photoresists, comprising: a non-gaseous photopolymerizable compound containing 1 to 4 centers of ethylenic unsaturation and capable of photo-initiated addition polymerization; a thermoplastic polymer binder; an addition polymerization initiator activatable by actinic radiation; and an adhesion promoter; the improvement of using an adhesion promoter having the formula ##STR4## wherein R 4 is a benzene or naphthalene radical, each unsubstituted or mono- or di-substituted with alkyl radicals having from 1 to 12 carbon atoms or aralkyl radicals having from 7 to 9 carbon atoms; R 2 is a radical of the formula R 7 O[(alkylene)O] x -(alkylene)-, wherein R 7 is hydrogen or an alkyl radical having from 1 to 20 carbon atoms, "alkylene" is a straight or branched chain alkylene radical having 2 or 3 carbon atoms and x is 0, 1, 2, 3 or 4; an alkenyl radical having from 2 to 20 carbon atoms or a cyanoalkyl radical having from 2 to 5 carbon atoms; and R 3 is the same as R 2 or hydrogen; an alkyl radical having from 1 to 20 carbon atoms; an aryl radical having from 6 to 10 carbon atoms; a cycloalkyl radical having from 5 to 12 carbon atoms; an aralkyl radical having from 7 to 9 carbon atoms; a heterocyclic radical or a radical of formula: ##STR5## wherein R 4 has its previous significance.

Claim 3

A composition in accordance with claim 1, wherein R 4 is a benzene radical.

Claim 4

A composition in accordance with claim 1 wherein R 3 or R 2 in said adhesion promoter is a radical having the formula R.sub.7 O[(alkylene)O].sub.x -alkylene wherein R 7 and x are as defined in claim 1.

Claim 5

A composition in accordance with claim 3, wherein R 7 is H and x is O.

Claim 6

A composition in accordance with claim 1, wherein R 4 in said adhesion promoter is an unsubstituted benzene radical or a benzene radical substituted by a methyl or dimethylbenzene radical and wherein R 2 is a R 7 O-alkylene-radical, wherein R 7 is hydrogen or an alkyl radical having from 1 to 4 carbon atoms and R 3 is the same as R 2 , a hydrogen or a 1-4C alkyl radical.

Claim 7

A composition in accordance with claim 1, wherein said promoter is selected from the group consisting of 1-diethanolaminomethyl benzotriazole 1-di-isopropanolaminomethyl benzotriazole N,N-bis(1'-benzotriazolylmethyl)-ethanolamine N,N-bis(1'-benzotriazolylmethyl)-isopropanolamine N,N-bis(1'-benzotriazolylmethyl)-ethoxyethoxypropylamine N,N-bis(1'-benzotriazolylmethyl)-palmitoylamine and N,N-bis(1'-benzotriazolylmethyl)-allylamine.

Claim 8

A composition in accordance with claim 1, wherein at least one coloring dye selected from Brilliant Green dye, Victoria Blue and substituted naphthalimide dyes, is included.

Claim 9

A composition in accordance with claim 1, wherein at least one leuco coloring dye selected from leuco Crystal Violet, leuco Malachite Green, leuco Basic Blue, leuco Pararosaniline, leuco Rosaniline, leuco Patent Blue A and leuco Patent Blue V is included.

Claim 10

A photopolymerizable composition in accordance with claim 1, wherein the non-gaseous photopolymerizable compound containing 1 to 4 centers of ethylenic unsaturation constitutes from about 15-30 weight percent of the composition; the addition polymerization initiator constitutes from about 0.01 to 1.0 weight percent of the composition; the thermoplastic polymer binder constitutes from about 40 to 80 weight percent of the composition; and the adhesion promoter constitutes from about 0.01 to 5 weight percent of the composition.

Claim 11

A composition in accordance with claim 1, wherein said composition is constituted as a solution in a solvent, and containing from about 10 to 30 weight percent solids.

Claim 12

In a photoresist element comprising: (a) a solid support comprising a metal or metal alloy foil laminated to an epoxy or fiberglass or polyester resin board; and (b) laminated onto said support, a photopolymerizable composition comprising: an addition photopolymerizable monomer containing 1 to 4 centers of ethylenic unsaturation; a thermoplastic polymer binder; an addition polymerization initiator activatable by actinic radiation; and an adhesion promoter; the improvement of using an adhesion promoter having the formula ##STR6## wherein R 4 is a benzene or naphthalene radical, each unsubstituted or mono- or di-substituted with alkyl radicals having from 1 to 12 carbon atoms or aralkyl radicals having from 7 to 9 carbon atoms, R 2 is a radical of the formula R 7 O[(alkylene)O] x -(alkylene)-, wherein R 7 is hydrogen or an alkyl radical having from 1 to 20 carbon atoms, "alkylene" is a straight or branched chain alkylene radical having 2 or 3 carbon atoms and x is 0, 1, 2, 3 or 4; an alkenyl radical having from 2 to 20 carbon atoms or a cyanoalkyl radical having from 2 to 5 carbon atoms; and R 3 is the same as R 2 or hydrogen; an alkyl radical having from 1 to 20 carbon atoms; and aryl radical having from 6 to 10 carbon atoms; a cycloalkyl radical having from 5 to 12 carbon atoms; an aralkyl radical having from 7 to 9 carbon atoms; a heterocyclic radical or a radical of formula: ##STR7## wherein R 4 has its previous significance.

Claim 13

In a photoresist element comprising: (a) a solid support comprising a metal or metal alloy foil laminated to an epoxy or fiberglass or polyester resin board; and (b) laminated onto said support, a photopolymerizable composition comprising: an addition photopolymerizable monomer containing 1 to 4 centers of ethylenic unsaturation; a thermoplastic polymer binder; an addition polymerization initiator activatable by actinic radiation; and an adhesion promoter; the improvement of using an adhesion promoter having the formula ##STR6## wherein R 4 is a benzene or naphthalene radical, each unsubstituted or mono- or di-substituted with alkyl radicals having from 1 to 12 carbon atoms or aralkyl radicals having from 7 to 9 carbon atoms, R 2 is a radical of the formula R 7 O[(alkylene)O] x -(alkylene)-, wherein R 7 is hydrogen or an alkyl radical having from 1 to 20 carbon atoms, "alkylene" is a straight or branched chain alkylene radical having 2 or 3 carbon atoms and x is 0, 1, 2, 3 or 4; an alkenyl radical having from 2 to 20 carbon atoms or a cyanoalkyl radical having from 2 to 5 carbon atoms; and R 3 is the same as R 2 or hydrogen; an alkyl radical having from 1 to 20 carbon atoms; and aryl radical having from 6 to 10 carbon atoms; a cycloalkyl radical having from 5 to 12 carbon atoms; an aralkyl radical having from 7 to 9 carbon atoms; a heterocyclic radical or a radical of formula: ##STR7## wherein R 4 has its previous significance.

Claim 14

In a method for preparing an improved printed circuit board comprising the steps of: (a) image-wise exposing a photopolymerizable composition laminated onto a solid support and covered with a protective film, through a transparency, to actinic light to form an insoluble polymer image in the exposed areas of the photopolymerizable layer; (b) removing the protective film from said laminate; (c) washing away the unexposed portions of the photopolymerizable layer by means of a solvent therefor; (d) plating onto said element sufficient amount of a metal; and (e) treating said laminate to strip said resist mask from said laminate; the improvement of including in said photopolymerizable composition an adhesion promoter having the formula ##STR8## wherein R 4 is a benzene or npahthalene radical, each unsubstituted or mono- or di-substituted with alkyl radicals having from 1 to 12 carbon atoms or aralkyl radicals having from 7 to 9 carbon atoms, R 2 is a radical of the formula R 7 O[(alkylene)O] x -(alkylene)-, wherein R 7 is hydrogen or an alkyl radical having from 1 to 20 carbon atoms, "alkylene" is a straight or branched chain alkylene radical having 2 or 3 carbon atoms and x is 0, 1, 2, 3 or 4; an alkenyl radical having from 2 to 20 carbon atoms or a cyanoalkyl radical having from 2 to 5 carbon atoms; and R 3 is the same as R 2 or hydrogen; an alkyl radical having from 1 to 20 carbon atoms; and aryl radical having from 6 to 10 carbon atoms, a cycloalkyl radical having from 5 to 12 carbon atoms; an aralkyl radical having from 7 to 9 carbon atoms; a heterocyclic radical or a radical of formula: ##STR9## wherein R 4 has its previous significance.

Claim 15

In a method for preparing an improved printed circuit board comprising the steps of: (a) image-wise exposing a photopolymerizable composition laminated onto a solid support and covered with a protective film, through a transparency, to actinic light to form an insoluble polymer image in the exposed areas of the photopolymerizable layer; (b) removing the protective film from said laminate; (c) washing away the unexposed portions of the photopolymerizable layer by means of a solvent therefor; (d) plating onto said element sufficient amount of a metal; and (e) treating said laminate to strip said resist mask from said laminate; the improvement of including in said photopolymerizable composition an adhesion promoter having the formula ##STR8## wherein R 4 is a benzene or npahthalene radical, each unsubstituted or mono- or di-substituted with alkyl radicals having from 1 to 12 carbon atoms or aralkyl radicals having from 7 to 9 carbon atoms, R 2 is a radical of the formula R 7 O[(alkylene)O] x -(alkylene)-, wherein R 7 is hydrogen or an alkyl radical having from 1 to 20 carbon atoms, "alkylene" is a straight or branched chain alkylene radical having 2 or 3 carbon atoms and x is 0, 1, 2, 3 or 4; an alkenyl radical having from 2 to 20 carbon atoms or a cyanoalkyl radical having from 2 to 5 carbon atoms; and R 3 is the same as R 2 or hydrogen; an alkyl radical having from 1 to 20 carbon atoms; and aryl radical having from 6 to 10 carbon atoms, a cycloalkyl radical having from 5 to 12 carbon atoms; an aralkyl radical having from 7 to 9 carbon atoms; a heterocyclic radical or a radical of formula: ##STR9## wherein R 4 has its previous significance.