US4276191A
Expired / Lapsed
US
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Catalyst and process for polymerization of alpha-olefins
Assignee: BP Corp North America Inc
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Filing: 1979-06-04
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Granted: 1981-06-30
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Expires: 1999-06-04
Abstract
Abstract Catalyst and process for polymerization of alpha-olefins to predominantly atactic products, such catalyst comprising (A) an organoaluminum component and (B) a solid reaction product of (1) a titanium (IV) component and (2) a hydrocarbon-soluble organomagnesium-organoaluminum complex.
Inventors
- 👤 Nicholas M. Karayannis
- 👤 Harold Grams
- 👤 John S. Skryantz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 12:01
CPC Classifications
C; C08; C08F; C08F10/00
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
182 words
An alpha-olefin polymerization catalyst comprising (a) at least one organoaluminum component of the formula AlR g X 3-g wherein R is an alkyl radical of 1 to about 20 carbon atoms, X is halogen, and g ranges from 1 to 3, and (b) at least one component which is the solid reaction product of components consisting essentially of (1) at least one titanium(IV) halide or alkoxyhalide, and (2) at least one hydrocarbon-soluble organomagnesium-organoaluminum complex of the formula (MgR 1 2 ) m .(AlR 2 3 ) n wherein each R 1 and R 2 is independently an alkyl radical of 1 to about 20 carbon atoms, m and n are numbers greater than 0, and m/n is at least about 1, said components (1) and (2) being reacted at a temperature ranging from about -50° to about 150° C. and in amounts such that the atomic ratio of magnesium plus aluminum in (2) to titanium in (1) ranges from about 0.5:1 to about 4:1 to form a solid reaction product followed by separation of unreacted starting materials from said solid reaction product.
Claim 2
Dependent Claim
182 words
An alpha-olefin polymerization catalyst comprising (a) at least one organoaluminum component of the formula AlR g X 3-g wherein R is an alkyl radical of 1 to about 20 carbon atoms, X is halogen, and g ranges from 1 to 3, and (b) at least one component which is the solid reaction product of components consisting essentially of (1) at least one titanium(IV) halide or alkoxyhalide, and (2) at least one hydrocarbon-soluble organomagnesium-organoaluminum complex of the formula (MgR 1 2 ) m .(AlR 2 3 ) n wherein each R 1 and R 2 is independently an alkyl radical of 1 to about 20 carbon atoms, m and n are numbers greater than 0, and m/n is at least about 1, said components (1) and (2) being reacted at a temperature ranging from about -50° to about 150° C. and in amounts such that the atomic ratio of magnesium plus aluminum in (2) to titanium in (1) ranges from about 0.5:1 to about 4:1 to form a solid reaction product followed by separation of unreacted starting materials from said solid reaction product.
Claim 3
Dependent Claim
25 words
The catalyst of claim 1 wherein said solid reaction product is prepared in the presence of an inert hydrocarbon or halogenated hydrocarbon solvent for (2).
Claim 4
Dependent Claim
21 words
The catalyst of claim 2 wherein (a) is a dialkylaluminum chloride having 2 to about 8 carbon atoms per alkyl radical.
Claim 5
Dependent Claim
49 words
The catalyst of claim 3 wherein the titanium(IV) component in (b) is titanium tetrachloride and the organomagnesium-organoaluminum complex in (b) is a hydrocarbon-soluble dialkylmagnesium-trialkylaluminum complex wherein each alkyl radical is independently a radical of 2 to about 8 carbon atoms and m/n ranges from about 1 to about 10.
Claim 6
Dependent Claim
28 words
The catalyst of claim 4 wherein the dialkylmagnesium-trialkylaluminum complex in (b) is a hydrocarbon soluble di-n-butylmagnesium-triethylaluminum complex wherein the atomic ratio of magnesium to aluminum is about 6:1.
Claim 7
Dependent Claim
10 words
The catalyst of claim 5 wherein (a) is diethylaluminum chloride.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-06-29 | 1984-12-29 | 1985-06-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-06-29 | 1988-12-29 | 1989-06-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-06-29 | 1992-12-29 | 1993-06-30 | $7700.00 | Window Closed / Lapsed |