US4279707A
Expired / Lapsed
US
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Electroplating of nickel-iron alloys for uniformity of nickel/iron ratio using a low density plating current
Assignee: International Business Machines Corp
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Filing: 1980-02-19
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Granted: 1981-07-21
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Expires: 2000-02-19
Abstract
Abstract Electroplating nickel-iron alloys onto objects having complex topographical shapes with projections and hollows such as upper pole pieces of thin film magnetic recording heads has been found to yield a substantial variation in nickel-iron alloy composition from point to point within a single pattern. Providing a low total dischargeable ion concentration in the bath is helpful to reduce such variations when plating in the 80:20 Ni:Fe alloy range. That is, it is desirable to use a low value of Fe ++ and Ni ++ ion concentrations and a relatively low current density to operate at the relatively flat peak of the curve of the iron percentage in the plated alloy vs. current density curve. The curve can be raised or lowered by increasing or decreasing the total dischargeable ion concentration respectively for a given Ni ++ /Fe ++ ion ratio. The preferred Fe ++ ion concentration range for Ni:Fe alloy ratio near 80:20 is about 0.15-0.3 g/l for a range of 10-14 g/l of Ni ++ ion in a solution with a pH of about 3, a temperature of about 20°-35° C. where the Ni ++ /Fe ++ ratio in the solution ranges from about 45 to 1 to about 70 to 1. Preferably, an electrolyte for reducing pitting such as 0-100 g/l of NaCl is employed. The cation (Na + ) of the latter electrolyte should not be a dischargeable ion. Plating current density is preferably between about 2 ma/cm 2 and 12 ma/cm 2 , and optimum results are achieved for values from about 4 to 8 ma/cm 2 .
Inventors
- 👤 Nathaniel C. Anderson
- 👤 Charles R. Grover, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 20:06
CPC Classifications
H; H01; H01F; H01F41/00; H01F41/14; H01F41/24; H01F41/26; C; C25; C25D; C25D3/00; C25D3/02; C25D3/56; C25D3/562
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
185 words
A nickel-iron electroplating method for plating NiFe alloy onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron alloy composition over a range of plating current densities comprising, an aqueous plating bath solution at a temperature in the range from about 20° C. to about 35° C., placing a substrate with a complex topographical shape in said plating bath solution, employing a constant current plating density from about 2 milliamperes per centimeter squared to about 12 milliamperes per centimeter squared, said plating bath solution having ferrous ion concentration in the range from about 0.15 to about 0.3 grams per liter and a nickel ion concentration in the range from about 10 to about 14 grams per liter, with a pH of the bath of about 3, maintaining continuous agitation of a paddle moving over the surface of the cathode at a distance of about 2-3 millimeters at a rate of about 1 cycle per second, and thereby providing differences of less than about 2% by weight in the nickel/iron composition ratio of the NiFe magnetic alloy produced across said complex topographical shape.
Claim 2
Dependent Claim
185 words
A nickel-iron electroplating method for plating NiFe alloy onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron alloy composition over a range of plating current densities comprising, an aqueous plating bath solution at a temperature in the range from about 20° C. to about 35° C., placing a substrate with a complex topographical shape in said plating bath solution, employing a constant current plating density from about 2 milliamperes per centimeter squared to about 12 milliamperes per centimeter squared, said plating bath solution having ferrous ion concentration in the range from about 0.15 to about 0.3 grams per liter and a nickel ion concentration in the range from about 10 to about 14 grams per liter, with a pH of the bath of about 3, maintaining continuous agitation of a paddle moving over the surface of the cathode at a distance of about 2-3 millimeters at a rate of about 1 cycle per second, and thereby providing differences of less than about 2% by weight in the nickel/iron composition ratio of the NiFe magnetic alloy produced across said complex topographical shape.
Claim 3
Dependent Claim
30 words
A method in accordance with claim 1 wherein said current density is within a preferred range from about 4 milliamperes per centimeter squared to about 8 milliamperes per centimeter squared.
Claim 4
Dependent Claim
151 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 13.7 g/l with selected Cl and SO 4 ions Fe ions: 0.2 to 0.3 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 1.5 g/l NaCl: 0 to 50 g/l said bath being maintained in a container at a temperature of about 30° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continuous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 5-10 ma/cm 2 .
Claim 5
Dependent Claim
151 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 13.7 g/l with selected Cl and SO 4 ions Fe ions: 0.2 to 0.3 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 1.5 g/l NaCl: 0 to 50 g/l said bath being maintained in a container at a temperature of about 30° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continuous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 5-10 ma/cm 2 .
Claim 6
Dependent Claim
147 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 12.4 g/l with selected Cl and SO 4 ions Fe ions: 0.24 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 0.75 g/l NaCl: 25 g/l said bath being maintained in a container at a temperature of about 23° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continuous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 4 ma/cm 2 .
Claim 7
Dependent Claim
147 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 12.4 g/l with selected Cl and SO 4 ions Fe ions: 0.24 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 0.75 g/l NaCl: 25 g/l said bath being maintained in a container at a temperature of about 23° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continuous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 4 ma/cm 2 .
Claim 8
Dependent Claim
158 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 13.7 g/l with selected Cl and SO 4 ions Fe ions: 0.04 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 1.5 g/l NaCl: 0 to 50 g/l said bath being maintained in a container at a temperature of about 30° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 4 ma/cm 2 , whereby about 5% Fe is provided in the alloy.
Claim 9
Dependent Claim
158 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 13.7 g/l with selected Cl and SO 4 ions Fe ions: 0.04 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 1.5 g/l NaCl: 0 to 50 g/l said bath being maintained in a container at a temperature of about 30° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 4 ma/cm 2 , whereby about 5% Fe is provided in the alloy.
Claim 10
Dependent Claim
158 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 13.7 g/l with selected Cl and SO 4 ions Fe ions: 0.12 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 1.5 g/l NaCl: 0 to 50 g/l said bath being maintained in a container at a temperature of about 30° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continuous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 4 ma/cm 2 , whereby about 10% Fe is provided in the alloy.
Claim 11
Dependent Claim
158 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 13.7 g/l with selected Cl and SO 4 ions Fe ions: 0.12 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 1.5 g/l NaCl: 0 to 50 g/l said bath being maintained in a container at a temperature of about 30° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continuous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 4 ma/cm 2 , whereby about 10% Fe is provided in the alloy.
Claim 12
Dependent Claim
158 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 13.7 g/l with selected Cl and SO 4 ions Fe ions: 0.21 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 1.5 g/l NaCl: 0 to 50 g/l said bath being maintained in a container at a temperature of about 30° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continuous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 4 ma/cm 2 , whereby about 15% Fe is provided in the alloy.
Claim 13
Dependent Claim
158 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 13.7 g/l with selected Cl and SO 4 ions Fe ions: 0.21 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 1.5 g/l NaCl: 0 to 50 g/l said bath being maintained in a container at a temperature of about 30° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continuous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 4 ma/cm 2 , whereby about 15% Fe is provided in the alloy.
Claim 14
Dependent Claim
158 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 13.7 g/l with selected Cl and SO 4 ions Fe ions: 0.29 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 1.5 g/l NaCl: 0 to 50 g/l said bath being maintained in a container at a temperature of about 30° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continuous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 4 ma/cm 2 , whereby about 20% Fe is provided in the alloy.
Claim 15
Dependent Claim
158 words
A nickel-iron electroplating method for plating alloys of NiFe onto a substrate with a relatively high degree of uniformity of magnetic nickel-iron composition over a range of plating current densities comprising, an aqueous plating bath solution including about Ni ions: 13.7 g/l with selected Cl and SO 4 ions Fe ions: 0.29 g/l pH: 3 H 3 BO 3 : 25 g/l Sodium Saccharin: 1.5 g/l NaCl: 0 to 50 g/l said bath being maintained in a container at a temperature of about 30° C., continuously reciprocating a paddle at a rate of about 1 cycle per second moving over the surface of the cathode to be plated providing continuous agitation of the bath near the surface to be plated for the purpose of maintaining substantially constant bath compositions throughout the thickness of the film being plated, and providing a continuous current density of about 4 ma/cm 2 , whereby about 20% Fe is provided in the alloy.
Claim 16
Dependent Claim
206 words
A nickel-iron electroplating method for plating Ni-Fe alloy onto a substrate with a relatively high degree of unformity of magnetic nickel-iron alloy composition over a range of plating current densities comprising an aqueous plating bath solution at a temperature in the range from about 20° C. to about 35° C., placing a substrate with a complex topographical shape in said plating bath solution, employing a constant current plating density from about 2 milliamperes per centimeter squared to about 12 milliamperes per centimeter squared, said plating bath solution consisting essentially of ferrous ion concentration in the range from about 0.15 to about 0.3 grams per liter with Cl and SO 4 ions and a nickel ion concentration in the range from about 10 to about 14 grams per liter with ions of SO 4 with boric acid, sodium saccharin and sodium chloride, with a pH of the bath of about 3, maintaining continuous agitation of a paddle moving over the surface of the cathode at a distance of about 2-3 millimeters at a rate of about 1 cycle per second, and thereby providing differences of less than about 2% by weight in the nickel/iron composition ratio of the NiFe magnetic alloy produced across said complex topographical shape.
Claim 17
Dependent Claim
206 words
A nickel-iron electroplating method for plating Ni-Fe alloy onto a substrate with a relatively high degree of unformity of magnetic nickel-iron alloy composition over a range of plating current densities comprising an aqueous plating bath solution at a temperature in the range from about 20° C. to about 35° C., placing a substrate with a complex topographical shape in said plating bath solution, employing a constant current plating density from about 2 milliamperes per centimeter squared to about 12 milliamperes per centimeter squared, said plating bath solution consisting essentially of ferrous ion concentration in the range from about 0.15 to about 0.3 grams per liter with Cl and SO 4 ions and a nickel ion concentration in the range from about 10 to about 14 grams per liter with ions of SO 4 with boric acid, sodium saccharin and sodium chloride, with a pH of the bath of about 3, maintaining continuous agitation of a paddle moving over the surface of the cathode at a distance of about 2-3 millimeters at a rate of about 1 cycle per second, and thereby providing differences of less than about 2% by weight in the nickel/iron composition ratio of the NiFe magnetic alloy produced across said complex topographical shape.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-07-20 | 1985-01-19 | 1985-07-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-07-20 | 1989-01-19 | 1989-07-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-07-20 | 1993-01-19 | 1993-07-21 | $7700.00 | Window Closed / Lapsed |