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US4279962A Expired / Lapsed US ⏱️ 0.0 years remaining

Protective coating for cathodically protected metal surfaces

Assignee: Individual
•
Filing: 1979-12-04
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Granted: 1981-07-21
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Expires: 1999-12-04
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Abstract

Abstract To provide a cover coating for metal surfaces subject to corrosion by water, typically steel surfaces in salt water, for ships, structural components, and the like, in which cathodic protection by application of a negative voltage to the metal is provided, a two-layer coating is applied in which the base coating applied to the metal comprises a mixture of finely divided zinc and polyisocyanate prepolymers capable of hardening or curing under ambient humidity, with dryers, gelling, and pigment agents, and high boiling point solvents, covered by a cover coating, preferably in two to three layers, of a mixture of tar with polyisocyanates, fillers, dryers, solvents, and micaceous iron ore or hematite powder.

Inventors

  • 👤 Rainer-Leo Meyer
  • 👤 Rainmar John
  • 👤 Bernhard Eisenhauer
  • 👤 Herta Baumstark

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 14:20
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/08; C09D5/10; C09D5/106; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/088; C08G18/0885; C09D175/00; C08G2150/00; C08G2150/90; Y; Y10; Y10T; Y10T428/00; Y10T428/26; Y10T428/29; Y10T428/2982; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31529; Y10T428/31551; Y10T428/31554; Y10T428/31609; Y10T428/31678; Y10T428/31717

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 180 words
Protective coating on a cathodically protected metal surface comprising a base coating and a cover coating, in which the base coating includes a zinc powder capable of hardening or curing under ambient air humidity and having a composition, all parts being approximate and by weight, comprising: 6-10 parts polyisocyanate-prepolymer with an NCO content of about 16% and capable of hardening under ambient humidity, 7-9 parts high boiling point aromatic solvent, 0.01-0.03 parts deaeration substance, 0.3-0.8 parts drying and stabilizing substance, 3-6 parts gelling substance, 0.3-0.5 parts wetting agent, 4-7 parts pigment in flake form and 65-75 parts zinc powder and a cover coating which comprises a polyurethane-tar coating capable of hardening under ambient air humidity comprising: 16-20 parts aromatic polyisocyanate with an NCO content of 5-7%, 1-3 parts liquid higher molecular polyisocyanate with an NCO content of 3-4%, 5-20 parts tar with a viscosity of 5600 to 6400 poise/25° C., 6.5-8 parts drying agent, 0.05-0.1 parts deaeration agent, 3.5-4.5 parts precipitation prevention agent, 30-40 parts micaceous iron ore or hematite powder, 5-10 parts inorganic filler, and 2-5 parts stabilizing agent.
Claim 2
Dependent Claim 180 words
Protective coating on a cathodically protected metal surface comprising a base coating and a cover coating, in which the base coating includes a zinc powder capable of hardening or curing under ambient air humidity and having a composition, all parts being approximate and by weight, comprising: 6-10 parts polyisocyanate-prepolymer with an NCO content of about 16% and capable of hardening under ambient humidity, 7-9 parts high boiling point aromatic solvent, 0.01-0.03 parts deaeration substance, 0.3-0.8 parts drying and stabilizing substance, 3-6 parts gelling substance, 0.3-0.5 parts wetting agent, 4-7 parts pigment in flake form and 65-75 parts zinc powder and a cover coating which comprises a polyurethane-tar coating capable of hardening under ambient air humidity comprising: 16-20 parts aromatic polyisocyanate with an NCO content of 5-7%, 1-3 parts liquid higher molecular polyisocyanate with an NCO content of 3-4%, 5-20 parts tar with a viscosity of 5600 to 6400 poise/25° C., 6.5-8 parts drying agent, 0.05-0.1 parts deaeration agent, 3.5-4.5 parts precipitation prevention agent, 30-40 parts micaceous iron ore or hematite powder, 5-10 parts inorganic filler, and 2-5 parts stabilizing agent.
Claim 3
Dependent Claim 42 words
Coating according to claim 1, wherein the gelling substance in the zinc-based coating comprises at least one of the materials selected from the group consisting of: dimethyldioctadecyclammonium-montmorillonite; an organic derivative of montmorillonite derived from montmorillonite by iron exchange reaction with alkylammonium bases.
Claim 4
Dependent Claim 28 words
Coating according to claim 1, wherein the flaked pigment in the zinc-based coating is a finely ground flour of a naturally occurring mixture of muscovite, chlorite and quartz.
Claim 5
Dependent Claim 18 words
Coating according to claim 1, wherein the precipitation prevention agent of the cover coating is finely dispersed clay.
Claim 6
Dependent Claim 15 words
Coating according to claim 1, wherein the filler in the cover coating is microfine talcum.
Claim 7
Dependent Claim 42 words
Coating according to claim 1, wherein the base coating comprises a two-layer coating, each having a dry film thickness of about 75 μm, and the top coating comprises at least two layers, each with a dry film thickness of about 125 μm.
Claim 8
Dependent Claim 14 words
Coating according to claim 1, wherein the tar is present in about 10-12 parts.
Claim 9
Dependent Claim 16 words
Coating according to claim 1, wherein the cover coating includes up to about 10 parts solvent.
Claim 10
Dependent Claim 21 words
Coating according to claim 1, wherein the components are present in quantities approximately midway within the ranges recited in claim 1.
Claim 11
Dependent Claim 159 words
Protective coating on cathodically protected surface comprising a base coating and a cover coating, in which the base coating includes a zinc powder capable of hardening or curing under ambient air humidity and having a composition, all parts being approximate and by weight, comprising: 6-10 parts of an epoxy-type resin, 7-9 parts high boiling point aromatic solvent, 0.01-0.03 parts deaeration substance, 0.03-0.8 parts drying and stabilizing substance, 3-6 parts gelling substance, 0.3-0.5 parts wetting agent, 4-7 parts pigment in flake form and 65-75 parts zinc powder and a cover coating which comprises a polyurethane-tar coating capable of hardening comprising 16-20 parts of an epoxy-type resin, 1-3 parts liquid higher molecular polyisocyanate with an NCO content of 3-4%, 5-20 parts tar with a viscosity of 5600 to 6400 poise/25° C., 6.5-8 parts drying agent, 0.05-0.1 parts deaeration agent, 3.5-4.5 parts precipitation prevention agent, 30-40 parts micaceous iron ore or hematite powder, 5-10 parts inorganic filler, and 2-5 parts stabilizing agent.
Claim 12
Dependent Claim 159 words
Protective coating on cathodically protected surface comprising a base coating and a cover coating, in which the base coating includes a zinc powder capable of hardening or curing under ambient air humidity and having a composition, all parts being approximate and by weight, comprising: 6-10 parts of an epoxy-type resin, 7-9 parts high boiling point aromatic solvent, 0.01-0.03 parts deaeration substance, 0.03-0.8 parts drying and stabilizing substance, 3-6 parts gelling substance, 0.3-0.5 parts wetting agent, 4-7 parts pigment in flake form and 65-75 parts zinc powder and a cover coating which comprises a polyurethane-tar coating capable of hardening comprising 16-20 parts of an epoxy-type resin, 1-3 parts liquid higher molecular polyisocyanate with an NCO content of 3-4%, 5-20 parts tar with a viscosity of 5600 to 6400 poise/25° C., 6.5-8 parts drying agent, 0.05-0.1 parts deaeration agent, 3.5-4.5 parts precipitation prevention agent, 30-40 parts micaceous iron ore or hematite powder, 5-10 parts inorganic filler, and 2-5 parts stabilizing agent.
Claim 13
Dependent Claim 17 words
Coating according to claim 10, wherein at least one of the epoxy resins is a two-component resin.
Claim 14
Dependent Claim 25 words
Coating according to claim 10, wherein at least one of the epoxy resins is a one-component resin capable of hardening under ambient air humidity condition.

References Cited (Backward Citations)

US3360391A Cited
US3499783A Cited
US3598659A Cited
US3756845A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-07-20 1985-01-19 1985-07-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-07-20 1989-01-19 1989-07-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-07-20 1993-01-19 1993-07-21 $7700.00 Window Closed / Lapsed

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