Coating composition and process for producing synthetic resin moldings by using the same

Claim 2

A coating composition comprising (a) a monomer mixture of 30 to 90% by weight of at least one poly(meth)acrylate of mono or polypentaerythritol having at least three (meth)acryloyloxy groups in one molecule of formula (I) ##STR20## wherein at least three of X 11 , X 12 , X 13 , X 22 , X 23 , . . . X n .sbsb.2, X n .sbsb.3 and X 14 are CH 2 ═CR--COO-- groups and the rest of them are --OH groups, n is an integer of 1 to 5 and R represents hydrogen or a methyl group, and 70 to 10% by weight of at least one monofunctional acrylate or methacrylate having at least one ether bond in one molecule, a boiling point above 150° C. under normal pressure and a viscosity below 20 centipoises at 20° C.; (b) 0.01 to 10 parts by weight of a photosensitizing agent per 100 parts by weight of said monomer mixture; (c) 0.0001 to 2.0 parts by weight per 100 parts by weight of said monomer mixture of at least one silicon containing surface active agent of the formula (II) or (III): ##STR21## wherein X is ##STR22## m and n are positive integers being smaller than 200 and x and y represent 0 or positive integers being smaller than 200 and satisfy the formula 0.1≦(xn+yn/2m)≦10 and R 1 represents --H or an alkyl, acyl or aryl group having 1 to 6 carbon atoms or ##STR23## wherein Y is ##STR24## m and n represent positive integers being smaller than 200, x and y represent 0 or positive integers being smaller than 200 and z represents 0 or a positive integer of 1 to 5 and satisfy the formula 0.1≦(xn+yn/2m+n)≦10, R 2 represents ##STR25## acyl or aryl group having 1 to 6 carbon atoms, and R 3 represents --H or an alkyl, acyl or aryl group having 1 to 6 carbon atoms; and (d) 10 to 1900 parts by weight per 100 parts by weight of said monomer mixture of at least one organic solvent capable of forming a uniform solution upon mixing with said monomer mixture.

Claim 3

The coating composition of claim 1, wherein said monomer of formula (I) is at least one compound selected from the group consisting of dipentaerythritol triacrylate, dipentaerythritol tetraacrylate, dipentaerythritol pentaacrylate and dipentaerythritol hexaacrylate.

Claim 4

The coating composition of claim 1, wherein said monofunctional acrylate or methacrylate has a cyclic ether bond having at least two ether bonds.

Claim 5

The coating composition of claim 1, wherein said monofunctional acrylate or methacrylate is at least one compound selected from the group consisting of ethylcarbitol acrylate, butylcarbitol acrylate and tetrahydrofurfuryl acrylate.

Claim 6

The coating composition of claim 1, 2, 3 or 4 wherein said organic solvent is a solvent having a boiling point of 50° to 200° C. under normal pressure and a viscosity below 10 centipoises at 20° C.

Claim 7

The coating composition of claim 1, wherein said monomer mixture contains 0.05 to 3% by weight of an alkyl ester of straight chain higher saturated fatty acid.

Claim 8

The coating composition of claim 6, wherein said alkyl ester of of straight chain higher saturated fatty acid is an ester of a straight chain higher saturated fatty acid having 14 to 18 carbon atoms with a monohydric alcohol having 3 to 10 carbon atoms and containing a hydrocarbon side chain.

Claim 9

A process for producing synthetic resin moldings high in abrasion resistance and surface smoothness, which comprises applying a coating composition comprising: (a) a monomer mixture of 30 to 90% by weight of at least one poly(meth)acrylate of mono or polypentaerythritol having at least three (meth)acryloyloxy groups in one molecule of the formula (I) ##STR26## wherein at least three of X 11 , X 12 , X 13 , X 22 , X 23 , . . . X n .sbsb.2, X n .sbsb.3 and X 14 are CH 2 ═CR--COO-- groups and the rest of them are --OH groups, n is an integer of 1 to 5 and R represents hydrogen or a methyl group, and 70 to 10% by weight of at least one monofunctional acrylate or methacrylate having at least one ether bond in one molecule, a boiling point above 150° C. under normal pressure and a viscosity below 20 centipoises at 20° C.; (b) 0.01 to 10 parts by weight of a photosensitizing agent per 100 parts by weight of said monomer mixture; (c) 0.0001 to 2.0 parts by weight per 100 parts by weight of said monomer mixture of at least one silicon containing surface active agent of the formula (II) or (III): ##STR27## wherein X is ##STR28## m and n are positive integers being smaller than 200 and x and y represent 0 or positive integers being smaller than 200 and satisfy the formula 0.1≦xn+yn/2m≦10 and R 1 represents --H or an alkyl, acyl or aryl group having 1 to 6 carbon atoms or ##STR29## wherein Y is ##STR30## m and n represent positive integers being smaller than 200, x and y represent 0 or positive integers being smaller than 200 and z represents 0 or a positive integer of 1 to 5 and satisfies the formula 0.1≦(xn+yn)/2m+n≦10, R 2 represents ##STR31## acyl or aryl group having 1 to 6 carbon atoms, and R 3 represents --H or alkyl, acyl or aryl group having 1 to 6 carbon atoms; and (d) 10 to 1900 parts by weight per 100 parts by weight of said monomer mixture of at least one organic solvent forming a uniform solution by mixing with said monomer mixture to coat the surface of a synthetic resin molding and then irradiating with actinic radiation in air to form a hard, cross-linked film on the surface of the synthetic resin molding.

Claim 10

A process for producing synthetic resin moldings high in abrasion resistance and surface smoothness, which comprises applying a coating composition comprising: (a) a monomer mixture of 30 to 90% by weight of at least one poly(meth)acrylate of mono or polypentaerythritol having at least three (meth)acryloyloxy groups in one molecule of the formula (I) ##STR26## wherein at least three of X 11 , X 12 , X 13 , X 22 , X 23 , . . . X n .sbsb.2, X n .sbsb.3 and X 14 are CH 2 ═CR--COO-- groups and the rest of them are --OH groups, n is an integer of 1 to 5 and R represents hydrogen or a methyl group, and 70 to 10% by weight of at least one monofunctional acrylate or methacrylate having at least one ether bond in one molecule, a boiling point above 150° C. under normal pressure and a viscosity below 20 centipoises at 20° C.; (b) 0.01 to 10 parts by weight of a photosensitizing agent per 100 parts by weight of said monomer mixture; (c) 0.0001 to 2.0 parts by weight per 100 parts by weight of said monomer mixture of at least one silicon containing surface active agent of the formula (II) or (III): ##STR27## wherein X is ##STR28## m and n are positive integers being smaller than 200 and x and y represent 0 or positive integers being smaller than 200 and satisfy the formula 0.1≦xn+yn/2m≦10 and R 1 represents --H or an alkyl, acyl or aryl group having 1 to 6 carbon atoms or ##STR29## wherein Y is ##STR30## m and n represent positive integers being smaller than 200, x and y represent 0 or positive integers being smaller than 200 and z represents 0 or a positive integer of 1 to 5 and satisfies the formula 0.1≦(xn+yn)/2m+n≦10, R 2 represents ##STR31## acyl or aryl group having 1 to 6 carbon atoms, and R 3 represents --H or alkyl, acyl or aryl group having 1 to 6 carbon atoms; and (d) 10 to 1900 parts by weight per 100 parts by weight of said monomer mixture of at least one organic solvent forming a uniform solution by mixing with said monomer mixture to coat the surface of a synthetic resin molding and then irradiating with actinic radiation in air to form a hard, cross-linked film on the surface of the synthetic resin molding.

Claim 11

The process of claim 8, wherein said monomer of formula (I) is at least one compound selected from the group consisting of dipentaerythritol triacrylate, dipentaerythritol tetraacrylate, dipentaerythritol pentaacrylate and dipentaerythritol hexaacrylate.

Claim 12

The process of claim 9, wherein said monofunctional acrylate or methacrylate has a cyclic ether bond or at least two ether bonds.

Claim 13

The process of claim 8, wherein said monofunctional acrylate or methacrylate is at least one compound selected from the group consisting of ethylcarbitol acrylate, butylcarbitol acrylate and tetrahydrofurfuryl acrylate.

Claim 14

The process of claim 8, wherein said monomer mixture contains 0.05 to 3% by weight of an alkyl ester of straight chain higher saturated fatty acid.

Claim 15

The process of claim 12, wherein said alkyl ester of straight chain higher saturated fatty acid is an ester of a straight chain higher saturated fatty acid having 14 to 18 carbon atoms with a monohydric alcohol having 3 to 10 carbon atoms and containing a hydrocarbon side chain.