US4339367A
Expired / Lapsed
US
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Modified cyclopentadiene resins, process for preparing the same, and a composition for printing ink containing said modified resins as vehicle component
Assignee: Zeon Corp
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Filing: 1980-12-18
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Granted: 1982-07-13
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Expires: 2000-12-18
Abstract
Abstract A process for producing a novel modified resin, which comprises reacting (I) a hydroxyl-containing resin with (II) a polyisocyanate compound, said resin (I) being prepared by reacting (a) the reaction product of a cyclopentadiene resin, a higher fatty acid ester having a conjugated double bond and an α,β-unsaturated dicarboxylic acid anhydride with (b) a hydroxyl group-imparting agent; a modified resin obtained by the aforesaid process; and a printing ink comprising the modified resin as a vehicle component.
Inventors
- 👤 Yasuyoshi Chino
- 👤 Akinori Miyaguchi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 07:03
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/02; C09D11/10; C09D11/102; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/62; C08G18/6216; C08G18/625; C08G18/6258; C08G18/67; C08G18/68; C08G18/683; C08G18/686; Y; Y10; Y10S; Y10S260/00; Y10S260/38
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
56 words
A process for producing a modified resin, which comprises reacting (I) a hydroxyl-containing resin with (II) a polyisocyanate compound, said resin (I) being prepared by reacting (a) the reaction product of a cyclopentadiene resin, a higher fatty acid ester having a conjugated double bond and an α,β-unsaturated dicarboxylic acid anhydride with (b) a hydroxyl group-imparting agent.
Claim 2
Dependent Claim
56 words
A process for producing a modified resin, which comprises reacting (I) a hydroxyl-containing resin with (II) a polyisocyanate compound, said resin (I) being prepared by reacting (a) the reaction product of a cyclopentadiene resin, a higher fatty acid ester having a conjugated double bond and an α,β-unsaturated dicarboxylic acid anhydride with (b) a hydroxyl group-imparting agent.
Claim 3
Dependent Claim
18 words
The process of claim 1 wherein the modified resin has a softening point of 40° to 180° C.
Claim 4
Dependent Claim
49 words
The process of claim 1 wherein the reaction of the hydroxyl-containing resin (I) with the polyisocyanate compound (II) is carried out such that the equivalent ratio of the isocyanate groups in the polyisocyanate compound (II) to the hydroxyl groups in the hydroxyl-containing resin (I) is from 0.05 to 2.
Claim 5
Dependent Claim
27 words
The process of claim 1 wherein the hydroxyl-containing resin (I) has a softening point of 40 to 180° C. and a hydroxyl value of 3 to 120.
Claim 6
Dependent Claim
27 words
The process of claim 1 wherein the hydroxyl group-imparting agent is a polyhydric alcohol, an alkanolamine, or a hydroxyl-containing vinyl monomer derived from an unsaturated monocarboxylic acid.
Claim 7
Dependent Claim
45 words
The process of claim 1 wherein the reaction product (a) is derived from 35 to 98% by weight of the cyclopentadiene resin, 2 to 65% by weight of the higher fatty acid ester and 0.3 to 30% by weight of the α, β-unsaturated dicarboxylic acid.
Claim 8
Dependent Claim
15 words
A modified resin obtained by the process of any one of claims 1 to 6.
Claim 9
Dependent Claim
125 words
A vehicle component cmpositon for printing inks, comprising a modified resin having a softening point of 40 to 180° C., said modified resin being prepared by reacting (I) a hydroxyl-containing resin obtained by reacting the reaction product of 35 to 95% by weight of a cyclopentadiene resin, 2 to 65% by weight of a higher fatty acid ester having a conjugated double bond and 0.3 to 30% by weight of an α,β-unsaturated dicarboxylic acid anhydride, with a polyhydric alcohol, an alkanolamine or a hydroxyl-containing vinyl monomer derived from an unsaturated monocarboxylic acid, with (II) a polyisocyanate compound in such proportions that the equivalent ratio of the isocyanate groups in the compound (II) to the hydroxyl groups in the resin (I) is from 0.05 to 2.
Claim 10
Dependent Claim
125 words
A vehicle component cmpositon for printing inks, comprising a modified resin having a softening point of 40 to 180° C., said modified resin being prepared by reacting (I) a hydroxyl-containing resin obtained by reacting the reaction product of 35 to 95% by weight of a cyclopentadiene resin, 2 to 65% by weight of a higher fatty acid ester having a conjugated double bond and 0.3 to 30% by weight of an α,β-unsaturated dicarboxylic acid anhydride, with a polyhydric alcohol, an alkanolamine or a hydroxyl-containing vinyl monomer derived from an unsaturated monocarboxylic acid, with (II) a polyisocyanate compound in such proportions that the equivalent ratio of the isocyanate groups in the compound (II) to the hydroxyl groups in the resin (I) is from 0.05 to 2.
Claim 11
Dependent Claim
24 words
In an ink comprising a vehicle component, a pigment and a solvent, the improvement wherein the vehicle component is the composition of claim 8.
Claim 12
Dependent Claim
27 words
The vehicle component composition for printing inks according to claim 8 wherein the modified resin is the reaction product of the hydroxyl-containing resin with a polyhydric alcohol.
Claim 13
Dependent Claim
26 words
The vehicle component composition for printing inks according to claim 8 wherein the modified resin is the reaction product of the hydroxyl-containing resin with an alkanolamine.
Claim 14
Dependent Claim
46 words
The vehicle component composition for printing inks according to claim 11 wherein said alkanolamine is a monoalkanolamine selected from the group consisting of monoethanolamine, monopropanolamine, monobutanolamine, monopetanolamine, monooctanolamine and monocyclohexanolamine; or a dialkanolamine selected from the group consisting of diethanolamine, dipropanolamine, dibutanolamine, dipentanolamine, dioctanolamine, and dicyclohexanolamine.
Claim 15
Dependent Claim
30 words
The vehicle component composition for printing inks according to claim 8 wherein the modified resin is the reaction product of the hydroxyl-containing vinyl monomer derived from an unsaturated monocarboxylic acid.
Claim 16
Dependent Claim
40 words
The vehicle component composition for printing inks according to claim 13 wherein said hydroxyl-containing vinyl monomer is selected from the group consisting of hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxybutyl acrylate, hydroxyhexyl acrylate, hydroxyoctyl acrylate, hydroxyethyl methacrylate, glycerol diacrylate and pentaerythritol triacrylate.
Claim 17
Dependent Claim
36 words
The vehicle component composition for printing inks according to claim 8 wherein said α,β-unsaturated dicarboxylic acid anhydride is selected from the group consisting of maleic anhydride, citraconic anhydride and itaconic anhydride or the alkyl-substituted derivatives thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-07-12 | 1986-01-11 | 1986-07-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-07-12 | 1990-01-11 | 1990-07-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-07-12 | 1994-01-11 | 1994-07-13 | $7700.00 | Window Closed / Lapsed |