US4340546A
Expired / Lapsed
US
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Process for the reduction of unsaturated carboxylic acids
Assignee: Honeywell UOP LLC
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Filing: 1981-03-09
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Granted: 1982-07-20
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Expires: 2001-03-09
Abstract
Abstract Unsaturated carboxylic acids, as exemplified by oleic acid, erucic acid, crotonic acid, etc., may be subjected to a reduction reaction by treatment with hydrogen in the presence of a catalyst comprising cadmium and rhenium composited on a solid support such as alumina. The reduction reaction is effected at elevated temperatures and pressures, a specific feature of the reaction process being that hydrogen is continuously bled from the reactor during the reaction period. This feature results in obtaining a higher selectivity of esters and alcohols which retain the unsaturation of the original starting material.
Inventors
- 👤 Gail M. Qualeatti
- 👤 Dalia Germanas
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 06:13
CPC Classifications
C; C11; C11C; C11C3/00; C11C3/12; C11C3/126; B; B01; B01J; B01J23/00; B01J23/16; B01J23/32; B01J23/36; C07; C07C; C07C29/00; C07C29/132; C07C29/136; C07C29/147; C07C29/149; C07C67/00; C07B; C07B2200/00; C07B2200/09
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
58 words
A process for the reduction of an unsaturated carboxylic acid comprising treating an unsaturated carboxylic acid in a reaction system in the presence of hydrogen and a reduction catalyst comprising cadmium and rhenium composited on a solid support at treatment conditions, continuously bleeding hydrogen from said reaction system during the reaction period, and recovering the resultant unsaturated product.
Claim 2
Dependent Claim
58 words
A process for the reduction of an unsaturated carboxylic acid comprising treating an unsaturated carboxylic acid in a reaction system in the presence of hydrogen and a reduction catalyst comprising cadmium and rhenium composited on a solid support at treatment conditions, continuously bleeding hydrogen from said reaction system during the reaction period, and recovering the resultant unsaturated product.
Claim 3
Dependent Claim
44 words
The process as set forth in claim 1 in which said treatment conditions include a temperature in the range of from about 100° to about 500° C., and a pressure in the range of from about 100 to about 5000 pounds per square inch.
Claim 4
Dependent Claim
24 words
The process as set forth in claim 1 in which said catalyst also contains a noble metal of Group VIII of the Periodic Table.
Claim 5
Dependent Claim
19 words
The process as set forth in claim 1 in which said solid support comprises a high surface area alumina.
Claim 6
Dependent Claim
17 words
The process as set forth in claim 4 in which said high surface area alumina is gamma-alumina.
Claim 7
Dependent Claim
15 words
The process as set forth in claim 4 in which said noble metal is platinum.
Claim 8
Dependent Claim
32 words
The process as set forth in claim 1 in which said unsaturated carboxylic acid is oleic acid and said unsaturated product is oleyl oleate, oleyl alcohol and geometric and positional isomers thereof.
Claim 9
Dependent Claim
27 words
The process as set forth in claim 1 in which said unsaturated carboxylic acid is crotonic acid and said unsaturated product is crotonyl crotonate and crotonyl alcohol.
Claim 10
Dependent Claim
32 words
The process as set forth in claim 1 in which said unsaturated carboxylic acid is hypogeic acid and said unsaturated product is hypogeyl hypogeate, hypogeyl alcohol and geometric and positional isomers thereof.
Claim 11
Dependent Claim
32 words
The process as set forth in claim 1 in which said unsaturated carboxylic acid is erucic acid and said unsaturated product is erucyl erucate, erucyl alcohol and geometric and positional isomers thereof.
Claim 12
Dependent Claim
27 words
The process as set forth in claim 1 in which said unsaturated carboxylic acid is hexenoic acid and said unsaturated product is hexenyl hexenate and hexenyl alcohol.
References Cited (Backward Citations)
US3123626A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-07-19 | 1986-01-18 | 1986-07-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-07-19 | 1990-01-18 | 1990-07-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-07-19 | 1994-01-18 | 1994-07-20 | $7700.00 | Window Closed / Lapsed |