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US4341533A Expired / Lapsed US ⏱️ 0.0 years remaining

High-hardness abrasive product based on alumina and aluminium oxycarbides and process for preparing same

Assignee: FRANCAISE D`ELECTROMETALLURGIE-SOFREM A CORP OF FRANCE Ste
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Filing: 1980-07-03
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Granted: 1982-07-27
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Expires: 2000-07-03
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Abstract

Abstract The invention relates to a new class of high-hardness abrasive products and wear resistant parts based on alumina and aluminium oxycarbides. By fusing alumina in the presence of a carbonaceous substance and by controlled cooling, it is possible to obtain a large number of products in which the ratio ρ of the number of carbon atoms to the number of carbon atoms plus oxygen atoms is between 0.01 and 0.50, and preferably between 0.02 and 0.20. These products are essentially constituted by primary alumina crystals in a eutectic matrix Al 2 O 3 - Al 4 O 4 C or Al 2 O 3 - Al 2 OC.

Inventors

  • 👤 Marc Daire
  • 👤 Yves Larrere
  • 👤 Andre Mangin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 11:44
CPC Classifications
C; C09; C09K; C09K3/00; C09K3/14; C09K3/1409; C09K3/1427; C04; C04B; C04B35/00; C04B35/01; C04B35/10; C04B35/107

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 63 words
A high-hardness abrasive product, characterised in that it is constituted by the combination of crystalline phases of alumina and of at least one of the two aluminium oxycarbides Al 2 OC and Al 4 O 4 C, in which the ratio ρ of the number of carbon atoms to the number of carbon atoms plus oxygen atoms (C/C+O) is between 0.01 and 0.50.
Claim 2
Dependent Claim 63 words
A high-hardness abrasive product, characterised in that it is constituted by the combination of crystalline phases of alumina and of at least one of the two aluminium oxycarbides Al 2 OC and Al 4 O 4 C, in which the ratio ρ of the number of carbon atoms to the number of carbon atoms plus oxygen atoms (C/C+O) is between 0.01 and 0.50.
Claim 3
Dependent Claim 20 words
A high-hardness abrasive product, according to claim 1, characterised in that the ratio ρ is preferably between 0.02 and 0.20.
Claim 4
Dependent Claim 45 words
A high-hardness abrasive product, according to claim 1 or 2, characterised in that it is constituted by a dispersion of primary alumina crystals in a eutectic matrix (Al 2 O 3 -Al 4 O 4 C) with a ratio ρ of between 0.01 and 0.1.
Claim 5
Dependent Claim 36 words
A high-hardness abrasive product, according to claim 1 or 2, characterised in that it is constituted by the eutectic Al 2 O 3 -Al 4 O 4 C with a ratio ρ substantially equal to 0.10.
Claim 6
Dependent Claim 48 words
A high-hardness abrasive product, according to claim 1 or 2, characterised in that it is constituted by a dispersion of Al 4 O 4 C particles in a eutectic matrix Al 2 O 3 -Al 4 O 4 C with a ratio ρ of between 0.10 and 0.20.
Claim 7
Dependent Claim 42 words
A high-hardness abrasive product, according to claim 1 or 2, characterised in that it is constituted by a dispersion of primary alumina crystals in a eutectic matrix Al 2 O 3 -Al 2 OC with a ratio ρ between 0.01 and 0.13.
Claim 8
Dependent Claim 34 words
A high-hardness abrasive product, according to claim 1 or 2, characterised in that it is constituted by the eutectic Al 2 O 3 -Al 2 OC with a ratio ρ substantially equal to 0.13.
Claim 9
Dependent Claim 49 words
A high-hardness abrasive product, according to claim 1 or 2, characterised in that it is constituted by a dispersion of Al 2 OC particles in a eutectic matrix Al 2 O 3 -Al 2 OC with a ratio ρ of between 0.13 and 0.50, preferably between 0.13 and 0.20.
Claim 10
Dependent Claim 44 words
A high-hardness abrasive product, according to claim 1 or 2, characterised by a ternary combination of crystalline phases Al 2 O 3 -Al 2 OC-Al 4 O 4 C with a ratio ρ of between 0.02 and 0.50 and preferably between 0.02 and 0.20.
Claim 11
Dependent Claim 88 words
A process for the preparation of high-hardness abrasive products comprising the steps of fusing alumina in the presence of a carbonaceous substance to derive a reaction product constituted by alumina and at least one of the two aluminum oxycarbides Al 2 OC and Al 4 O 4 C in which the ratio ρ of the number of carbon atoms to the number of carbon atoms plus oxygen atoms (C/C+O) is between 0.01 and 0.50 and cooling the the reaction product to a solid at a controlled, predetermined rate.
Claim 12
Dependent Claim 88 words
A process for the preparation of high-hardness abrasive products comprising the steps of fusing alumina in the presence of a carbonaceous substance to derive a reaction product constituted by alumina and at least one of the two aluminum oxycarbides Al 2 OC and Al 4 O 4 C in which the ratio ρ of the number of carbon atoms to the number of carbon atoms plus oxygen atoms (C/C+O) is between 0.01 and 0.50 and cooling the the reaction product to a solid at a controlled, predetermined rate.
Claim 13
Dependent Claim 40 words
A process for the preparation of high-hardness abrasive products according to claim 10, characterised in that the carbonaceous substance is selected from the group comprising graphite, coke, lamp black, amorphous carbon aluminum carbide and a mixture of carbon and aluminum.
Claim 14
Dependent Claim 27 words
A process for the preparation of high-hardness abrasive products according to claim 10, characterised in that the carbonaceous substance is aluminium carbide Al 4 C 3 .
Claim 15
Dependent Claim 26 words
A process for the preparation of high-hardness abrasive products according to claim 10, characterised in that the carbonaceous substance is a mixture of carbon and aluminium.
Claim 16
Dependent Claim 31 words
A process for the preparation of high-hardness abrasive products according to any one of claims 10 to 13, characterised in that the fusing is carried out under a dry inert gas.
Claim 17
Dependent Claim 37 words
A process for the preparation of high-hardness abrasive products according to claim 10, 11, 12 or 13, characterized in that the fusing and at least the beginning of the cooling are carried out under dry inert gas.
Claim 18
Dependent Claim 43 words
A process for the preparation of high-hardness abrasive products according to claim 10, 11, 12 or 15, characterised in that the reaction product is cooled at a high rate by casting over a plurality of metallic masses or into a large metallic mould.

References Cited (Backward Citations)

US3615307A Cited
US3615308A Cited
US3580708A Cited
GB1323282A Cited
US3792553A Cited
US4059417A Cited
US4063908A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-07-26 1986-01-25 1986-07-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-07-26 1990-01-25 1990-07-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-07-26 1994-01-25 1994-07-27 $7700.00 Window Closed / Lapsed

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