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US4369136A Expired / Lapsed US ⏱️ 0.0 years remaining

Poly(aryl ether) containing blends

Assignee: BP Corp North America Inc
•
Filing: 1980-03-31
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Granted: 1983-01-18
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Expires: 2000-03-31
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Abstract

Abstract Described herein are molding compositions comprising a blend of a poly(aryl ether), a polyester and a compatibilizing amount of an aromatic polycarbonate. These compositions are especially suited for molding articles useful in electrical applications.

Inventors

  • 👤 Lloyd M. Robeson
  • 👤 William D. Claus, Jr.
  • 👤 Harvey L. Batleman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 08:40
CPC Classifications
H; H04; H04N; H04N9/00; H04N9/12; H04N9/16; H04N9/22; H04N9/24; C; C08; C08L; C08L67/00; C08L67/02; C08L71/00; C08L81/00; C08L81/06; C08L69/00; Y; Y10; Y10S; Y10S525/00; Y10S525/906

Claims Analysis

Total Claims: 32
Claim 1
Independent Claim 104 words
A molding composition comprising: (a) from about 20 to about 90 weight percent of a poly(aryl ether) having recurring units of the formula: O--E--O--E'-- wherein E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an inert electron withdrawing group in at least one of the positions ortho and para to the valence bonds wherein both of said residuum are valently bonded to the ether oxygens through aromatic carbon atoms, (b) from about 10 to about 60 weight percent of a polyester, and (c) from about 1 to about 25 weight percent of an aromatic polycarbonate.
Claim 2
Dependent Claim 104 words
A molding composition comprising: (a) from about 20 to about 90 weight percent of a poly(aryl ether) having recurring units of the formula: O--E--O--E'-- wherein E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an inert electron withdrawing group in at least one of the positions ortho and para to the valence bonds wherein both of said residuum are valently bonded to the ether oxygens through aromatic carbon atoms, (b) from about 10 to about 60 weight percent of a polyester, and (c) from about 1 to about 25 weight percent of an aromatic polycarbonate.
Claim 3
Dependent Claim 117 words
A molding composition comprising: (a) from about 20 to about 90 weight percent of a poly(aryl ether) having recurring units of the formula: O--E--O--E'-- wherein E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an inert electron withdrawing group in at least one of the positions ortho and para to the valence bonds wherein both of said residuum are valently bonded to the ether oxygens through aromatic carbon atoms, (b) from about 10 to about 60 weight percent of a polyester, (c) from about 1 to about 25 weight percent of an aromatic polycarbonate, and (d) from about 15 to about 30 weight percent of a fiber reinforcement.
Claim 4
Dependent Claim 117 words
A molding composition comprising: (a) from about 20 to about 90 weight percent of a poly(aryl ether) having recurring units of the formula: O--E--O--E'-- wherein E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an inert electron withdrawing group in at least one of the positions ortho and para to the valence bonds wherein both of said residuum are valently bonded to the ether oxygens through aromatic carbon atoms, (b) from about 10 to about 60 weight percent of a polyester, (c) from about 1 to about 25 weight percent of an aromatic polycarbonate, and (d) from about 15 to about 30 weight percent of a fiber reinforcement.
Claim 5
Dependent Claim 54 words
A molding composition comprising a poly(aryl ether), a polyester, a compatibilizing amount of an aromatic polycarbonate and an impact modifier which is a graft copolymer of a vinyl aromatic, an acrylate, an unsaturated nitrile or mixtures thereof, grafted onto an unsaturated elastomeric backbone and having a tensile modulus of less than about 10,000 psi.
Claim 6
Dependent Claim 54 words
A molding composition comprising a poly(aryl ether), a polyester, a compatibilizing amount of an aromatic polycarbonate and an impact modifier which is a graft copolymer of a vinyl aromatic, an acrylate, an unsaturated nitrile or mixtures thereof, grafted onto an unsaturated elastomeric backbone and having a tensile modulus of less than about 10,000 psi.
Claim 7
Dependent Claim 81 words
A molding composition comprising: (a) a poly(aryl ether) having recurring units of the formula O--E--O--E'-- wherein E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an inert electron withdrawing group in at least one of the positions ortho and para to the valence bonds wherein both of said residium are valently bonded to the ether oxygens through aromatic carbon atoms, (b) a polyester, and (c) a compatibilizing amount of an aromatic polycarbonate.
Claim 8
Dependent Claim 81 words
A molding composition comprising: (a) a poly(aryl ether) having recurring units of the formula O--E--O--E'-- wherein E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an inert electron withdrawing group in at least one of the positions ortho and para to the valence bonds wherein both of said residium are valently bonded to the ether oxygens through aromatic carbon atoms, (b) a polyester, and (c) a compatibilizing amount of an aromatic polycarbonate.
Claim 9
Dependent Claim 19 words
A molding composition as defined in claim 4 wherein the poly(aryl ether) has repeating units of the formula: ##STR21##
Claim 10
Dependent Claim 19 words
A molding composition as defined in claim 4 wherein the poly(aryl ether) has repeating units of the formula: ##STR22##
Claim 11
Dependent Claim 19 words
A molding composition as defined in claim 4 wherein the poly(aryl ether) has repeating units of the formula: ##STR23##
Claim 12
Dependent Claim 29 words
A molding composition as defined in claim 4 wherein the polyester has repeating units of the general formula: ##STR24## wherein n is an integer of from 2 to 4.
Claim 13
Dependent Claim 14 words
A molding composition as defined in claim 8 wherein the polyester is poly(ethylene terephthalate).
Claim 14
Dependent Claim 14 words
A molding composition as defined in claim 8 wherein the polyester is poly(butylene terephthalate).
Claim 15
Dependent Claim 25 words
A molding composition as defined in claim 4 wherein the polycarbonate is prepared from the reaction product of a dihydric phenol and a carbonate precursor.
Claim 16
Dependent Claim 21 words
A molding composition as defined in claim 11 wherein the dihydric phenol is bisphenol-A and the carbonate precursor is carbonyl chloride.
Claim 17
Dependent Claim 24 words
A molding composition as in claim 4 wherein the poly(aryl ether) is used in amounts of from about 20 to about 90 weight percent.
Claim 18
Dependent Claim 23 words
A molding composition as in claim 4 wherein the polyester is used in amounts of from about 10 to about 60 weight percent.
Claim 19
Dependent Claim 23 words
A molding composition as in claim 4 wherein the polycarbonate is used in amounts of from about 1 to about 25 weight percent.
Claim 20
Dependent Claim 46 words
A molding composition as in claim 4 which contains an impact modifier which is a graft copolymer of a vinyl aromatic, an acrylate, an unsaturated nitrile, or mixtures thereof, grafted onto an unsaturated elastomeric backbone and having a tensile modulus of less than about 100,000 psi.
Claim 21
Dependent Claim 46 words
A molding composition as in claim 16 which contains an impact modifier which is a graft copolymer of a vinyl aromatic, an acrylate, an unsaturated nitrile, or mixtures thereof, grafted onto an acrylate elastomeric backbone and having a tensile modulus of less than about 100,000 psi.
Claim 22
Dependent Claim 11 words
A molding composition as in claim 4 which contains fiber reinforcement.
Claim 23
Dependent Claim 16 words
A molding composition as in claim 18 wherein the fiber reinforcement is fiberglass or carbon fibers.
Claim 24
Dependent Claim 13 words
A molding composition as in claim 4 which contains an inorganic particulate filler.
Claim 25
Dependent Claim 12 words
A molding composition as in claim 20 wherein the filler is wollastonite.
Claim 26
Dependent Claim 16 words
A molding composition as in claim 4 which contains fiber reinforcement and an inorganic particulate filler.
Claim 27
Dependent Claim 13 words
A molding composition as in claim 4 which contains a flame retardant additive.
Claim 28
Dependent Claim 15 words
A molding composition as in claim 23 wherein the flame retardant additive is decabromodiphenyl oxide.
Claim 29
Dependent Claim 55 words
A molding composition as in claim 1 which contains from about 3 to about 15 weight percent of an impact modifier which is a graft copolymer of a vinyl aromatic, an acrylate, an unsaturated nitrile, or mixtures thereof, grafted onto an unsaturated elastomeric backbone and having a tensile modulus of less than about 100,000 psi.
Claim 30
Dependent Claim 22 words
A molding composition as in claim 2 which contains from about 2 to about 10 weight percent of a flame retardant additive.
Claim 31
Dependent Claim 14 words
An article molded from the composition of claims 4, 1, 2, 3 or 25.
Claim 32
Dependent Claim 15 words
An electrical connector molded from the composition of claims 4, 1, 2, 3 or 25.

References Cited (Backward Citations)

US3365517A Cited
US3646162A Cited
US3742087A Cited
US3649712A Cited
US4013613A Cited
US3819759A Cited
US4259458A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-01-17 1986-07-19 1987-01-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-01-17 1990-07-19 1991-01-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-01-17 1994-07-19 1995-01-18 $7700.00 Window Closed / Lapsed

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