US4386944A
Expired / Lapsed
US
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System and process for increasing the combustible component content of a gaseous mixture
Assignee: General Electric Co
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Filing: 1982-04-16
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Granted: 1983-06-07
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Expires: 2002-04-16
Abstract
Abstract A system and process are described for increasing the concentration of a combustible component of a gaseous mixture containing such component (e.g. methane) and an additional gaseous component (e.g. carbon dioxide), wherein the gaseous mixture is contacted with a permselective membrane which is permeable to both such components and has selectivity for the additional component. A pressure difference is maintained across the membrane. At least a portion of the energy employed to maintain the pressure difference is provided by combustion of at least a portion of the combustible component which has permeated through the membrane.
Inventors
- 👤 Shiro G. Kimura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 21:40
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/22
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
215 words
A process for increasing the combustible component content of a gaseous mixture, comprising (A) contacting a first gaseous mixture comprising a combustible gaseous component and at least one additional gaseous component with a first major surface of a permselective membrane having at least a minor permeability (Pr c ) and a selectivity (Pr a /Pr c ) of greater than 1.0 at the temperature of said mixture, wherein Pr c and Pr a are the permeabilities of said combustible and said additional components respectively, (B) developing and maintaining a pressure difference across said membrane of P m -P o >0, wherein P m and P o are the external pressures on said first major surface and on the opposite major surface of said membrane respectively, such that said additional component preferentially permeates said membrane to form both (1) a second gaseous mixture relatively rich in said combustible component and relatively lean in said additional component adjacent said first major surface and (2) a third gaseous mixture relatively lean in said combustible component and relatively rich in said additional component adjacent said opposite surface, and (C) providing at least a portion of the energy employed to develop and maintain said pressure difference by combusting at least a portion of the combustible component in said third mixture.
Claim 2
Dependent Claim
215 words
A process for increasing the combustible component content of a gaseous mixture, comprising (A) contacting a first gaseous mixture comprising a combustible gaseous component and at least one additional gaseous component with a first major surface of a permselective membrane having at least a minor permeability (Pr c ) and a selectivity (Pr a /Pr c ) of greater than 1.0 at the temperature of said mixture, wherein Pr c and Pr a are the permeabilities of said combustible and said additional components respectively, (B) developing and maintaining a pressure difference across said membrane of P m -P o >0, wherein P m and P o are the external pressures on said first major surface and on the opposite major surface of said membrane respectively, such that said additional component preferentially permeates said membrane to form both (1) a second gaseous mixture relatively rich in said combustible component and relatively lean in said additional component adjacent said first major surface and (2) a third gaseous mixture relatively lean in said combustible component and relatively rich in said additional component adjacent said opposite surface, and (C) providing at least a portion of the energy employed to develop and maintain said pressure difference by combusting at least a portion of the combustible component in said third mixture.
Claim 3
Dependent Claim
22 words
The process of claim 1, wherein said combustible gaseous component is CH 4 and said additional gaseous component is CO 2 .
Claim 4
Dependent Claim
14 words
The process of claim 2, wherein said first gaseous mixture is sewage digester gas.
Claim 5
Dependent Claim
41 words
The process of claim 2, wherein said membrane is formed of a polymeric composition comprising a polymer selected from the group consisting of poly(phenylene oxide), sulfonated poly(phenylene oxide), polycarbonate, and mixtures thereof, said selectivity being from about 10 to about 100.
Claim 6
Independent Claim
256 words
A system for increasing the combustible component of a gaseous mixture, comprising: housing means for contacting a first gaseous mixture comprising a combustible component and at least one additional gaseous component, with a first major surface of a permselective membrane disposed within said housing so as to define a first and second chamber therein, said membrane having at least a minor permeability, Pr c , and a selectivity, Pr a /Pr c , of greater than 1.0 at the temperature of said first mixture, wherein Pr c and Pr a are the permeabilities of said combustible components and said additional component respectively; and means for developing and maintaining a net pressure difference across said membrane of P m -P o >0, wherein P m and P o are the total external pressures on said first major surface and on the opposite major surface of said membrane, respectively, such that said additional component preferentially permeates said membrane to form both a second gaseous mixture relatively rich in said combustible component and relatively lean in said additional component adjacent said first major membrane surface and in said first chamber and a third gaseous mixture relatively lean in said combustible component and relatively rich in said additional component adjacent said opposite surface and in said second chamber, said pressure developing and maintaining means being powered by combusting at least a portion of the combustible component in said third mixture, whereby combustion products are formed, said housing being configured so that said combustion products are segregated from said first chamber.
Claim 7
Independent Claim
256 words
A system for increasing the combustible component of a gaseous mixture, comprising: housing means for contacting a first gaseous mixture comprising a combustible component and at least one additional gaseous component, with a first major surface of a permselective membrane disposed within said housing so as to define a first and second chamber therein, said membrane having at least a minor permeability, Pr c , and a selectivity, Pr a /Pr c , of greater than 1.0 at the temperature of said first mixture, wherein Pr c and Pr a are the permeabilities of said combustible components and said additional component respectively; and means for developing and maintaining a net pressure difference across said membrane of P m -P o >0, wherein P m and P o are the total external pressures on said first major surface and on the opposite major surface of said membrane, respectively, such that said additional component preferentially permeates said membrane to form both a second gaseous mixture relatively rich in said combustible component and relatively lean in said additional component adjacent said first major membrane surface and in said first chamber and a third gaseous mixture relatively lean in said combustible component and relatively rich in said additional component adjacent said opposite surface and in said second chamber, said pressure developing and maintaining means being powered by combusting at least a portion of the combustible component in said third mixture, whereby combustion products are formed, said housing being configured so that said combustion products are segregated from said first chamber.
Claim 8
Dependent Claim
145 words
The apparatus of claim 5, wherein: (I) said pressure-difference providing-and-maintaining means includes an ejector, the suction opening thereof being in flow communication with said opposite major surface of said membrane such that suction is applied thereto, (II) said energy-providing means includes a fluid flow circuit comprising (a) said ejector, (b) combustion means for combusting at least a portion of the combustible component contained in said third mixture, (c) transfer means for transferring at least a portion of the heat generated by the combustion to a vaporizable liquid supplied to the transfer means to form pressurized vapor, (d) first conductor means for conducting said pressurized vapor to the motive-fluid inlet of said ejector, and (e) second conductor means for conducting, from the outlet of said ejector to said combustion means, ejector discharge flow containing at least a portion of the combustible component of said third mixture.
Claim 9
Dependent Claim
33 words
The system of claim 6, wherein said second conductor means (e) includes removal means for removing from said ejector discharge flow at least a portion of the pressurized vapor or condensate formed therefrom.
Claim 10
Dependent Claim
23 words
The system of claim 7, further including means for conducting the removed vapor or condensate to the liquid supply for said transfer means.
Claim 11
Dependent Claim
20 words
The system of claim 5, wherein said selectivity of said membrane is for CO 2 relative to CH 4 .
Claim 12
Dependent Claim
32 words
The system of claim 9, wherein said membrane is formed of a polymeric composition comprising a polymer selected from the group consisting of poly(phenylene oxide), sulfonated poly(phenylene oxide), polycarbonate, and mixtures thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-06-06 | 1986-12-06 | 1987-06-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-06-06 | 1990-12-06 | 1991-06-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-06-06 | 1994-12-06 | 1995-06-07 | $7700.00 | Window Closed / Lapsed |