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US4388276A Expired / Lapsed US ⏱️ 0.0 years remaining

Device for regenerating hydrochloric copper chloride etching solutions

Assignee: Siemens AG
•
Filing: 1981-08-17
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Granted: 1983-06-14
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Expires: 2001-08-17
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Abstract

Abstract Spent hydrochloric copper chloride etching solution used in production of printed circuit boards for etching non-galvanized printed circuits is continuously or cyclically regenerated by spraying spent etching liquid from an interconnected etching machine, as with mist projectors, into an upper area of an enclosed regeneration housing, which is also provided with an oxidating gas selected from oxygen, chlorine and a mixture of oxygen and chlorine. The chemical regeneration reaction takes place within the falling mist and a regenerated etching liquid falls to the bottom of the regeneration housing from where it is pumped back to the connected etching machine or station. Two level switches are positioned at different levels within the interior of the regeneration housing to respectively open or close the gas supply so as to equalize the sub-atmospheric pressure arising within the regeneration housing due to gas consumption and thus maintain a relatively slow increase of the etching solution along the bottom of the housing within optimum limits.

Inventors

  • 👤 Efthimios Konstantouros
  • 👤 Karl Hoeck

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 04:52
CPC Classifications
C; C23; C23F; C23F1/00; C23F1/46; Y; Y10; Y10T; Y10T137/00; Y10T137/7287

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 290 words
In a device for regeneration of spent hydrochloric copper chloride etching solution which is utilized in printed circuit board manufacture for etching non-galvanized printed circuits, wherein etching and regeneration occur in separate etching and regeneration means between which the etching solution is circulated cyclically or continuously and regeneration occurs with an oxidizing gas, the improvement comprising wherein: in combination said regeneration means comprises; an enclosed regeneration housing positioned in a flat upright container which holds a hydrochloric copper chloride etching solution therein, said housing having an interior wall defining a chamber in fluid communication with said upright container; a means for providing an oxidizing gas in controllable fluid communication with an upper area of said chamber, said oxidizing gas being selected from the group consisting of oxygen, chlorine and a mixture of oxygen and chlorine; said etching means including a means for providing spent hydrochloric copper chloride etching solution in fluid communication with said upright container and with said upper area of said chamber; means for spraying said spent etching solution into said upper area of the chamber for contacting said etching solution with said oxidizing gas so that regeneration of said etching solution occurs, consumption of at least a portion of said oxidizing gas occurs and regenerated etching solution collects in said upright container from where such regenerated solution flows back to said etching means; and two level switch means positioned at different levels along the interior wall of said regeneration housing within the chamber thereof for respectively opening and closing said means for providing an oxidizing gas so as to equalize the subatmospheric pressure arising within said chamber because of gas consumption and thus maintain the relatively slow increase of etching solution within said chamber within optimum limits.
Claim 2
Dependent Claim 290 words
In a device for regeneration of spent hydrochloric copper chloride etching solution which is utilized in printed circuit board manufacture for etching non-galvanized printed circuits, wherein etching and regeneration occur in separate etching and regeneration means between which the etching solution is circulated cyclically or continuously and regeneration occurs with an oxidizing gas, the improvement comprising wherein: in combination said regeneration means comprises; an enclosed regeneration housing positioned in a flat upright container which holds a hydrochloric copper chloride etching solution therein, said housing having an interior wall defining a chamber in fluid communication with said upright container; a means for providing an oxidizing gas in controllable fluid communication with an upper area of said chamber, said oxidizing gas being selected from the group consisting of oxygen, chlorine and a mixture of oxygen and chlorine; said etching means including a means for providing spent hydrochloric copper chloride etching solution in fluid communication with said upright container and with said upper area of said chamber; means for spraying said spent etching solution into said upper area of the chamber for contacting said etching solution with said oxidizing gas so that regeneration of said etching solution occurs, consumption of at least a portion of said oxidizing gas occurs and regenerated etching solution collects in said upright container from where such regenerated solution flows back to said etching means; and two level switch means positioned at different levels along the interior wall of said regeneration housing within the chamber thereof for respectively opening and closing said means for providing an oxidizing gas so as to equalize the subatmospheric pressure arising within said chamber because of gas consumption and thus maintain the relatively slow increase of etching solution within said chamber within optimum limits.
Claim 3
Dependent Claim 52 words
In a device as defined in claim 1 wherein said means for spraying the spent etching solution into the upper area of the regeneration housing chamber comprises mist projectors so as to enlarge the phase boundary between the sprayed etching solution and the oxidizing gas and thereby increase the rate of regeneration.
Claim 4
Dependent Claim 47 words
In a device as defined in claim 1 wherein a plurality of corrosion-resistant and etching solution-absorbant webs are hung across the regeneration housing chamber so as to enlarge the phase boundary between the sprayed etching solution and the oxidizing gas and thereby increase the rate of regeneration.
Claim 5
Dependent Claim 70 words
In a device as defined in claim 1 wherein said means for spraying the spent etching solution into the upper area of the regeneration housing chamber comprises mist projectors and a plurality of corrosion-resistant and etching solution-absorbant webs are positioned across said chamber below said mist projectors so as to enlarge the phase boundary between said sprayed etching solution and said oxidizing gas and thereby increase the rate of regeneration.
Claim 6
Dependent Claim 14 words
In a device as defined in claim 1 wherein said regeneration housing is bell-shaped.
Claim 7
Dependent Claim 67 words
In a device as defined in claim 1 wherein said means for providing oxidizing gas comprises a means for providing oxygen to a conduit in fluid communication with the upper chamber area of the housing and a means for providing chlorine to such conduit so that the gas mixture in the conduit comprises a mixture of about 80 to 90% oxygen and about 20 to 10% chlorine.
Claim 8
Dependent Claim 19 words
In a device as defined in claim 1 wherein said regeneration housing is formed of a transparent corrosion-resistant material.
Claim 9
Dependent Claim 35 words
In a device as defined in claim 1 wherein a control means is operationally coupled between said level switch means and said means providing an oxidizing gas for controlling the gas volume within said housing.

References Cited (Backward Citations)

US1514939A Cited
US2771460A Cited
US3306792A Cited
US3883309A Cited
US4101608A Cited
US4042444A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-13 1986-12-13 1987-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-13 1990-12-13 1991-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-13 1994-12-13 1995-06-14 $7700.00 Window Closed / Lapsed

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