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US4389482A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for forming photoresists with strong resistance to reactive ion etching and high sensitivity to mid- and deep UV-light

Assignee: SK Hynix Inc
•
Filing: 1981-12-14
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Granted: 1983-06-21
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Expires: 2001-12-14
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Abstract

Abstract A photoresist that has strong resistance to reactive ion etching, high photosensitivity to mid- and deep UV-light, and high resolution capability is formed by using as the resist material a copolymer of methacrylonitrile and methacrylic acid, and by baking the resist before the exposure to light for improved photosensitivity, and after exposure to light, development, and prior to treatment with reactive ion etching.

Inventors

  • 👤 Joachim Bargon
  • 👤 Hiroyuki Hiraoka
  • 👤 Lawrence W. Welsh, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 13:22
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/26; G03F7/40

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 107 words
In a process for forming a patterned photoresist by pattern-wise exposing a resist material to light and developing with a solvent, the improvement of increasing the resistance of the resist to reactive ion etching by employing as the resist a copolymer of methacrylonitrile and methacrylic acid and by baking the resist in two stages, one before and one after the exposure to light with the first baking being at a temperature and for a time sufficient to increase the photosensitivity of the photoresist, and with the second baking being at a temperature and for a time sufficient to increase the ion etching resistance of the patterned photoresist.
Claim 2
Dependent Claim 107 words
In a process for forming a patterned photoresist by pattern-wise exposing a resist material to light and developing with a solvent, the improvement of increasing the resistance of the resist to reactive ion etching by employing as the resist a copolymer of methacrylonitrile and methacrylic acid and by baking the resist in two stages, one before and one after the exposure to light with the first baking being at a temperature and for a time sufficient to increase the photosensitivity of the photoresist, and with the second baking being at a temperature and for a time sufficient to increase the ion etching resistance of the patterned photoresist.
Claim 3
Dependent Claim 61 words
In a process as claimed in claim 1 wherein the first baking is at a temperature of from about 120° C. to about 140° C. for a time of from about 10 to about 30 minutes, and the second baking is at a temperature of from about 140° C. to about 150° C. for from about 10 to about 30 minutes.
Claim 4
Dependent Claim 25 words
A process as claimed in claim 1 in which a positive resist is obtained by pattern-wise exposure of the resist to deep ultra violet radiation.
Claim 5
Dependent Claim 28 words
A process as claimed in claim 1 in which a negative resist is obtained by pattern-wise exposure of the resist to light of wavelength 300 nm or longer.
Claim 6
Dependent Claim 20 words
A process as claimed in claim 1 in which the resist has been sensitized by the presence of an additive.

References Cited (Backward Citations)

US2887376A Cited
US3914462A Cited
US3984582A Cited
US4080246A Cited
US4132586A Cited
US4184909A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-20 1986-12-20 1987-06-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-20 1990-12-20 1991-06-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-20 1994-12-20 1995-06-21 $7700.00 Window Closed / Lapsed

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