US4393020A
Expired / Lapsed
US
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Method for manufacturing a fiber-reinforced thermoplastic molded article
Assignee: Standard Oil Co
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Filing: 1981-10-19
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Granted: 1983-07-12
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Expires: 2001-10-19
Abstract
Abstract Molded fiber-reinforced thermoplastic articles are prepared by a novel two-step process involving an in situ polymerization of monomers onto the fiber followed by compression molding of the product.
Inventors
- 👤 George S. Li
- 👤 John F. Jones
- 👤 William M. Giffen, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 17:36
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
76 words
The method for manufacturing a molded article from a fiber-reinforced thermoplastic resin comprising (A) copolymerizing at least two vinyl monomers in the presence of fibers which are unidirectionally disposed to produce a resin-fiber composite composed of from about 60 to 95% by weight of fibers and correspondingly from about 5 to 40% by weight of resin, and (B) compression molding the substantially oriented resin-fiber composite at a suitable temperature and pressure to form said molded article.
Claim 2
Independent Claim
76 words
The method for manufacturing a molded article from a fiber-reinforced thermoplastic resin comprising (A) copolymerizing at least two vinyl monomers in the presence of fibers which are unidirectionally disposed to produce a resin-fiber composite composed of from about 60 to 95% by weight of fibers and correspondingly from about 5 to 40% by weight of resin, and (B) compression molding the substantially oriented resin-fiber composite at a suitable temperature and pressure to form said molded article.
Claim 3
Dependent Claim
93 words
The method of claim 1 wherein the monomers are selected from the group consisting of maleic anhydride, maleic acid, maleic esters, itaconic anhydride, itaconic acid, fumaric acid, fumaric esters, styrene, alpha-methyl styrene, the vinyl toluenes, the vinyl xylenes, indene, acrylonitrile, methacrylonitrile, acrylic acid, methacrylic acid, acrylic esters, methacrylic esters, acrylamide, methacrylamide, vinyl chloride, vinyl bromide, vinyl fluoride, vinylidene chloride, vinylidene bromide, vinylidene fluoride, vinyl acetate, isopropenyl acetate, vinyl propionates, vinyl butyrates, ethylene, propylene, dipropylene, isobutylene, diisobutylene, vinyl methyl ether, vinyl ethyl ether, the vinyl propyl ethers, the vinyl butyl ethers, butadiene, and isoprene.
Claim 4
Dependent Claim
36 words
The method of claim 2 wherein the fibers are selected from at least one member of the group consisting of glass, wool, cotton, wood, natural cellulosics, rayon, nylon, polyamide, polyimide, polyesters, carbon, acrylics, and mod acrylics.
Claim 5
Dependent Claim
18 words
The method of claim 1 wherein the monomers are maleic anhydride and styrene and the fibers are glass.
Claim 6
Dependent Claim
17 words
The method of claim 1 wherein the monomers are styrene and acrylonitrile and the fibers are glass.
Claim 7
Dependent Claim
18 words
The method of claim 1 wherein the monomers are styrene and dimethyl itaconate and the fibers are glass.
Claim 8
Dependent Claim
18 words
The method of claim 1 wherein the monomers are styrene and acrylic acid and the fibers are glass.
Claim 9
Dependent Claim
18 words
The method of claim 1 wherein the monomers are styrene and methyl methacrylate and the fibers are glass.
Claim 10
Dependent Claim
19 words
The method of claim 1 wherein the monomers are methyl methacrylate and maleic anhydride and the fibers are glass.
Claim 11
Dependent Claim
19 words
The method of claim 1 wherein the monomers are alpha-methyl styrene and maleic anhydride and the fibers are glass.
Claim 12
Dependent Claim
11 words
The process of claim 1 wherein said polymerization is bulk polymerization.
Claim 13
Dependent Claim
15 words
The process of claim 1 wherein the polymerization takes place in the absence of water.
Claim 14
Dependent Claim
13 words
The process of claim 1 wherein the resin fiber composite is oriented lengthwise.
Claim 15
Dependent Claim
16 words
The process of claim 1 wherein the resin fiber composite is oriented both lengthwise and widthwise.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-07-11 | 1987-01-10 | 1987-07-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-07-11 | 1991-01-10 | 1991-07-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-07-11 | 1995-01-10 | 1995-07-12 | $7700.00 | Window Closed / Lapsed |