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US4396670A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of microcapsules

Assignee: Arjo Wiggins Ltd
•
Filing: 1981-03-24
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Granted: 1983-08-02
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Expires: 2001-03-24
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Abstract

Abstract In a process for the production of microcapsules containing a liquid fill material, a dispersion-stabilizing species is produced in an aqueous acidic medium by interaction of a melamine formaldehyde precondensate and a water soluble polymer, neither of which alone is dispersion stabilizing with respect to the liquid fill material, and the precondensate is condensed by acid catalysis to produce a condensate which separates from solution and enwraps the liquid fill material to produce microcapsules.

Inventors

  • 👤 Peter Sinclair

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 23:12
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/124; B41M5/165; B01; B01J; B01J13/00; B01J13/02; B01J13/06; B01J13/14; B01J13/18; Y; Y10; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249994; Y10T428/249995; Y10T428/249997

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 174 words
A process for the production of microcapsules containing a liquid fill material, comprising the steps of: establishing an aqueous medium which is at an acidic pH and which contains both a melamine formaldehyde precondensate condensable at said acidic pH and a polymer which contains at least one acid, amide, amine, imine, ester, ether, hydroxyl, urethane, thiol or mercaptan group, said melamine formaldehyde precondensate interacting with said polymer in the absence of any substantial amount of urea formaldehyde precondensate to form a species which imparts dispersion-stabilizing properties to the liquid fill material, neither said melamine formaldehyde precondensate nor said polymer alone being dispersion-stabilizing with respect to the liquid fill material at the conditions at which a stable dispersion is to be established; establishing a stable dispersion of liquid fill material in the aqueous medium after formation of said dispersion stabilizing species; and condensing said melamine formaldehyde precondensate by acid catalysis after formation of said dispersion to produce a melamine formaldehyde condensate which separates from solution and enwraps the dispersed liquid fill to produce said microcapsules.
Claim 2
Dependent Claim 174 words
A process for the production of microcapsules containing a liquid fill material, comprising the steps of: establishing an aqueous medium which is at an acidic pH and which contains both a melamine formaldehyde precondensate condensable at said acidic pH and a polymer which contains at least one acid, amide, amine, imine, ester, ether, hydroxyl, urethane, thiol or mercaptan group, said melamine formaldehyde precondensate interacting with said polymer in the absence of any substantial amount of urea formaldehyde precondensate to form a species which imparts dispersion-stabilizing properties to the liquid fill material, neither said melamine formaldehyde precondensate nor said polymer alone being dispersion-stabilizing with respect to the liquid fill material at the conditions at which a stable dispersion is to be established; establishing a stable dispersion of liquid fill material in the aqueous medium after formation of said dispersion stabilizing species; and condensing said melamine formaldehyde precondensate by acid catalysis after formation of said dispersion to produce a melamine formaldehyde condensate which separates from solution and enwraps the dispersed liquid fill to produce said microcapsules.
Claim 3
Dependent Claim 17 words
A process according to claim 1 wherein said melamine formaldehyde precondensate is a methylated melamine formaldehyde precondensate.
Claim 4
Dependent Claim 46 words
A process as claimed in claim 1 wherein said water soluble polymer is an acrylamide/acrylic acid copolymer, starch or a starch derivative, hydroxyethyl cellulose carboxymethyl cellulose, an alginate, a polyurethane, polyethylene oxide, polypropylene glycol, a polyquaternary amine, a polyamide polyamine epichlorohydrin resin, polyethyleneimine or xanthan gum.
Claim 5
Dependent Claim 19 words
A process as claimed in any preceding claim wherein said acidic pH is in the range 3.9 to 5.5.
Claim 6
Dependent Claim 30 words
A process as claimed in any of claims 1, 2 or 3 where the precondensate is partially condensed in the presence of the polymer to produce the dispersion stabilising species.
Claim 7
Dependent Claim 29 words
A process as claimed in any of claims 1, 2 or 3 wherein the dispersion stabilising species is formed without initial partial condensation in the presence of the polymer.
Claim 8
Dependent Claim 29 words
A process as claimed in any of claims 1, 2 or 3 wherein the weight ratio of said polymer to said precondensate is in the range 0.03:5 to 5:1.
Claim 9
Dependent Claim 28 words
A process as claimed in any of claims 1, 2 or 3 wherein once a stable dispersion has formed the temperature is raised to accelerate the condensation reaction.
Claim 10
Dependent Claim 38 words
A process as claimed in any of claims 1, 2 or 3 wherein the weight ratio of liquid fill material droplets to microcapsule wall precursor material in aqueous acidic medium is in the range of 4.5:1 to 20:1.
Claim 11
Dependent Claim 25 words
A process as claimed in any of claims 1, 2 or 3 wherein additional melamine formaldehyde precondensate is added after formation of a stable dispersion.
Claim 12
Dependent Claim 15 words
Microcapsules produced by a process as claimed in any of claims 1, 2 or 3.
Claim 13
Dependent Claim 10 words
A sheet material carrying microcapsules as claimed in claim 11.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-01 1987-01-31 1987-08-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-01 1991-01-31 1991-08-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-01 1995-01-31 1995-08-02 $7700.00 Window Closed / Lapsed

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