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US4398753A Expired / Lapsed US ⏱️ 0.0 years remaining

Pressure sensitive recording unit

Assignee: Mitsui Toatsu Chemicals Inc
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Filing: 1981-12-14
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Granted: 1983-08-16
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Expires: 2001-12-14
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Abstract

Abstract Disclosed is a pressure sensitive recording unit which comprises a single base web sheet and a methine-type dyestuff and an organic oxidizing compound both supported on the single base web sheet, or a combination of first and second base web sheets and the methine-type dyestuff and organic oxidizing compound supported individually on the first and second base web sheets. Such a recording unit includes for example a pressure sensitive recording unit formed in combination of (a) a back-coated topsheet (CB-sheet) making use of microscopic capsules containing a solution obtained by dissolving a methine-type dyestuff in a solvent having a high boiling point and (b) a front-coated undersheet (CF-sheet) carrying an organic oxidizing compound coated thereon. Also disclosed is a pressure sensitive recording unit which includes a base web sheet carrying thereon such a methine-type dyestuff together with a metal ion sequestering agent and/or alkanol amine.

Inventors

  • 👤 Makoto Asano
  • 👤 Kiyoharu Hasegawa
  • 👤 Hiroyuki Akahori
  • 👤 Michihiro Tsujimoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 02:42
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/124; B41M5/132; B41M5/136; B41M5/1366; Y; Y10; Y10S; Y10S428/00; Y10S428/914

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 142 words
A pressure sensitive recording unit comprising a single base web sheet and a colorless or light-colored methine-type dyestuff represented by the formula (I): ##STR8## wherein, X, Y and Z represent individually a phenyl, naphthyl, or β-styryl group or a residue of an aromatic heterocyclic ring which group or ring may optionally be substituted, X, Y and Z may be the same or different, and either two of X, Y and Z may be coupled together to form a ring, and an organic oxidizing compound selected from oxidizing quinone derivatives substituted by a multiplicity of electron attractive groups, both the dyestuff and the oxidizing compound being supported on the single base web sheet; or a combination of a first base web sheet on which said methine-type dyestuff is supported and a second base web sheet on which said organic oxidizing compound is supported.
Claim 2
Dependent Claim 142 words
A pressure sensitive recording unit comprising a single base web sheet and a colorless or light-colored methine-type dyestuff represented by the formula (I): ##STR8## wherein, X, Y and Z represent individually a phenyl, naphthyl, or β-styryl group or a residue of an aromatic heterocyclic ring which group or ring may optionally be substituted, X, Y and Z may be the same or different, and either two of X, Y and Z may be coupled together to form a ring, and an organic oxidizing compound selected from oxidizing quinone derivatives substituted by a multiplicity of electron attractive groups, both the dyestuff and the oxidizing compound being supported on the single base web sheet; or a combination of a first base web sheet on which said methine-type dyestuff is supported and a second base web sheet on which said organic oxidizing compound is supported.
Claim 3
Dependent Claim 25 words
The pressure sensitive recording unit according to claim 1, wherein the methine-type dyestuff is supported together with an alkanol amine on its base web sheet.
Claim 4
Dependent Claim 32 words
The pressure sensitive recording unit according to claim 1, wherein the methine-type dyestuff is supported together with an alkanol amine and a metal ion sequestering agent on its respective base web sheet.
Claim 5
Dependent Claim 130 words
A pressure sensitive recording unit comprising, in combination: (A) a first sheet carrying thereon a layer which contains (a) microscopic capsules enclosing a solution of a colorless or light-colored methine-type dyestuff represented by the general formula (I): ##STR9## wherein, X, Y and Z represent individually a phenyl, naphthyl, or β-styryl group or a residue of an aromatic heterocyclic ring which group or ring may optionally be substituted, X, Y and Z may be the same or different, and either two of X, Y and Z may be coupled together to form a ring, and (b) an alkanol amine and/or metal ion sequestering agent; and (B) a second sheet carrying thereon a layer containing an organic oxidizing compound selected from oxidizing quinone derivatives substituted by a multiplicity of electron attractive groups.
Claim 6
Dependent Claim 130 words
A pressure sensitive recording unit comprising, in combination: (A) a first sheet carrying thereon a layer which contains (a) microscopic capsules enclosing a solution of a colorless or light-colored methine-type dyestuff represented by the general formula (I): ##STR9## wherein, X, Y and Z represent individually a phenyl, naphthyl, or β-styryl group or a residue of an aromatic heterocyclic ring which group or ring may optionally be substituted, X, Y and Z may be the same or different, and either two of X, Y and Z may be coupled together to form a ring, and (b) an alkanol amine and/or metal ion sequestering agent; and (B) a second sheet carrying thereon a layer containing an organic oxidizing compound selected from oxidizing quinone derivatives substituted by a multiplicity of electron attractive groups.
Claim 7
Dependent Claim 130 words
A pressure sensitive recording unit comprising a single base web sheet; and a layer supported on a same surface of the single base web sheet and containing (a) microscopic capsules enclosing a colorless or light-colored solution of a methine-type dyestuff represented by the general formula (I): ##STR10## wherein, X, Y and Z represent individually a phenyl, naphthyl, or β-styryl group or a residue of an aromatic heterocyclic ring which group or ring may optionally be substituted, X, Y and Z may be the same or different, and either two of X, Y and Z may be coupled together to form a ring, (b) an alkanol amine and/or metal ion sequestering agent, and (c) an organic oxidizing agent selected from oxidizing quinone derivatives substituted by a multiplicity of electron attractive groups.
Claim 8
Dependent Claim 130 words
A pressure sensitive recording unit comprising a single base web sheet; and a layer supported on a same surface of the single base web sheet and containing (a) microscopic capsules enclosing a colorless or light-colored solution of a methine-type dyestuff represented by the general formula (I): ##STR10## wherein, X, Y and Z represent individually a phenyl, naphthyl, or β-styryl group or a residue of an aromatic heterocyclic ring which group or ring may optionally be substituted, X, Y and Z may be the same or different, and either two of X, Y and Z may be coupled together to form a ring, (b) an alkanol amine and/or metal ion sequestering agent, and (c) an organic oxidizing agent selected from oxidizing quinone derivatives substituted by a multiplicity of electron attractive groups.
Claim 9
Dependent Claim 34 words
The pressure sensitive recording unit according to any one of claims 1, 4 or 5, wherein the methine-type dyestuff has been microencapsulated as a solution of a hydrophobic solvent having a high boiling point.
Claim 10
Dependent Claim 17 words
The pressure sensitive recording unit according to claim 6, wherein the methine-type dyestuff is a triphenylmethane-type dyestuff.
Claim 11
Dependent Claim 27 words
The pressure sensitive recording unit according to any one of claims 1, 4 or 5, wherein the organic oxidizing compound has its oxidation-reduction potential at 0.4 eV.
Claim 12
Dependent Claim 23 words
The pressure sensitive recording unit according to any one of claims 1, 4 or 5, wherein the organic oxidizing compound is a 2,3,5,6-tetra-substituted-1,4-benzoquinone.
Claim 13
Dependent Claim 20 words
The pressure sensitive recording unit according to claim 4 or 5, wherein the alkanol amine is a tertiary alkanol amine.
Claim 14
Dependent Claim 25 words
The pressure sensitive recording unit according to claim 4 or 5, wherein the metal ion sequestering agent is a water-soluble organic metal ion sequestering agent.
Claim 15
Dependent Claim 20 words
The pressure sensitive recording unit according to claim 4 or 5, wherein the metal ion sequestering agent is a polyphosphate.

References Cited (Backward Citations)

US4154463A Cited
US4254032A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-15 1987-02-14 1987-08-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-15 1991-02-14 1991-08-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-15 1995-02-14 1995-08-16 $7700.00 Window Closed / Lapsed

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