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US4411823A Expired / Lapsed US ⏱️ 0.0 years remaining

Initiator system for radiation curable compositions, radiation curable compositions containing such an initiator system, a process for curing said compositions and products covered therewith

Assignee: Akzo NV
•
Filing: 1981-03-23
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Granted: 1983-10-25
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Expires: 2001-03-23
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Abstract

Abstract A new initiator system for radiation curable compositions is disclosed. In said system there are incorporated: (a) a compound of the formula: <IMAGE> where R1=H or a substituted or unsubstituted alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, a cycloalkyl or cycloalkenyl group having 5 to 8 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, a furfuryl group or the group <IMAGE> where Y represents a methyl group and Z an alkyl group having 2 to 4 carbon atoms or Y and Z together form a 1,3- or 1,4- alkylene group having 3 or 4 carbon atoms which is substituted or not with an alkoxy group having 1 to 4 carbon atoms; R2=a substituted or unsubstituted alkyl group or alkenyl group having 4 to 20 carbon atoms, a cycloalkyl group or cycloalkenyl group having 5 to 8 carbon atoms, an alkaryl group having 4 to 16 carbon atoms in the alkyl group or a furfuryl group; R3 and R4 may be the same or different and represent a hydrogen, a chlorine or a bromine atom or a phenyl group, a substituted or unsubstituted alkyl group or alkoxy group having 1 to 4 carbon atoms, or a dialkyl amino group of which the alkyl groups have 1 to 4 carbon atoms and may be substituted with a hydroxyl group, and (b) a synergistic amount of a Na, K and/or Li-salt of an organic acid that is compatible with the curable compositions; and optionally some amount of solvent c for component b. The initiator system cures rapidly and has good storage stability.

Inventors

  • 👤 Hendrik J. Hageman
  • 👤 Willem J. de Klein
  • 👤 Egenius A. Giezen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 23:35
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 252 words
An initiator system for radiation curable compositions, comprising (a) a compound of the formula: ##STR20## where R 1 =H or a substituted or unsubstituted alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, a cycloalkyl or cycloalkenyl group having 5 to 8 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, a furfuryl group or the group ##STR21## where Y represents a methyl group and Z an alkyl group having 2 to 4 carbon atoms or Y and Z together form a 1,3- or 1,4-alkylene group having 3 or 4 carbon atoms which is substituted or not with an alkoxy group having 1 to 4 carbon atoms; R 2 =a substituted or unsubstituted alkyl group or alkenyl group having 4 to 20 carbon atoms, a cycloalkyl group or cycloalkenyl group having 5 to 8 carbon atoms, an alkaryl group having 4 to 16 carbon atoms in the alkyl group or a furfuryl group; R 3 and R 4 may be the same or different and represent a hydrogen, a chlorine or a bromine atom or a phenyl group, a substituted or unsubstituted alkyl group or alkoxy group having 1 to 4 carbon atoms, or a dialkyl amino group of which the alkyl groups have 1 to 4 carbon atoms and may be substituted with a hydroxyl group, and (b) a synergistic amount of a Na, K and/or Li-salt of an organic acid that is compatible with the curable compositions.
Claim 2
Dependent Claim 252 words
An initiator system for radiation curable compositions, comprising (a) a compound of the formula: ##STR20## where R 1 =H or a substituted or unsubstituted alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, a cycloalkyl or cycloalkenyl group having 5 to 8 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, a furfuryl group or the group ##STR21## where Y represents a methyl group and Z an alkyl group having 2 to 4 carbon atoms or Y and Z together form a 1,3- or 1,4-alkylene group having 3 or 4 carbon atoms which is substituted or not with an alkoxy group having 1 to 4 carbon atoms; R 2 =a substituted or unsubstituted alkyl group or alkenyl group having 4 to 20 carbon atoms, a cycloalkyl group or cycloalkenyl group having 5 to 8 carbon atoms, an alkaryl group having 4 to 16 carbon atoms in the alkyl group or a furfuryl group; R 3 and R 4 may be the same or different and represent a hydrogen, a chlorine or a bromine atom or a phenyl group, a substituted or unsubstituted alkyl group or alkoxy group having 1 to 4 carbon atoms, or a dialkyl amino group of which the alkyl groups have 1 to 4 carbon atoms and may be substituted with a hydroxyl group, and (b) a synergistic amount of a Na, K and/or Li-salt of an organic acid that is compatible with the curable compositions.
Claim 3
Dependent Claim 39 words
An initiator system according to claim 1, characterized in that the acid is at least one of a carboxylic acid, sulphonic acid, sulphinic acid, a partially esterified sulphuric or phosphoric acid, a phosphonic acid, phosphinic acid, and an arylhydroxide.
Claim 4
Dependent Claim 29 words
An initiator system according to claim 1 or 2, characterized in that per 1 to 10 parts of compound a it contains 0,1 to 2 parts of compound b.
Claim 5
Dependent Claim 20 words
An initiator system according to claim 1, characterized in that it contains some amount of solvent c for component b.
Claim 6
Dependent Claim 24 words
An initiator system according to claim 4, characterized in that the amount of solvent is 20 to 80% by weight of the components a+b+c.
Claim 7
Dependent Claim 17 words
An initiator system according to claim 4 or 5, characterized in that the solvent used is water.
Claim 8
Dependent Claim 24 words
An initiator system according to claim 4 or 5, characterized in that the solvent is an aliphatic alcohol having 1 to 8 carbon atoms.
Claim 9
Dependent Claim 42 words
An initiator system according to claim 1, characterized in that compound a corresponds to the formula: ##STR22## where R 1 is a hydrogen atom or a lower alkyl group and R 2 is an alkyl group having 4 to 20 carbon atoms.
Claim 10
Dependent Claim 22 words
An initiator system according to claim 8, characterized in that R 2 represents an alkyl group having 8 to 16 carbon atoms.
Claim 11
Dependent Claim 54 words
An initiator system according to claim 1, characterized in that compound a corresponds to the formula: ##STR23## where R 1 represents a hydrogen atom or a lower alkyl group and R 2 represents a group of the formula ##STR24## where R represents an alkyl group or alkoxy group having 8 to 13 carbon atoms.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-24 1987-04-25 1987-10-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-24 1991-04-25 1991-10-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-24 1995-04-25 1995-10-25 $7700.00 Window Closed / Lapsed

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