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US4416740A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and bath for the electrodeposition of palladium/nickel alloys

Assignee: Langbein Pfanhauser Werke AG
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Filing: 1982-03-05
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Granted: 1983-11-22
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Expires: 2002-03-05
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Abstract

Abstract A method of electrodepositing a palladium/nickel alloy coating upon a substrate wherein the coating is plated onto the substrate by electrodeposition from a bath containing 5 to 30 g per liter of palladium and 5 to 30 g per liter of nickel and having a palladium-nickel ratio such that the coating contains 30 to 90% by weight of palladium. The bath is provided during the electrodeposition of the coating with at least one acetylene amine or amino alcohol capable of improving the brightness and mechanical properties of the coating.

Inventors

  • 👤 Klaus Schulze-Berge

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 15:04
CPC Classifications
C; C25; C25D; C25D3/00; C25D3/02; C25D3/56; C25D3/562; C25D3/567

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 109 words
In a method of electrodepositing a palladium/nickel alloy coating upon a substrate wherein said coating is plated onto said substrate by electrodeposition from a bath containing 5 to 30 g per liter of palladium and 5 to 30 g per liter of nickel and having a palladium-nickel ratio such that the coating contains 30 to 90% by weight of palladium, the improvement which comprises providing in said bath during the electrodeposition of said coating at least one acetyleneamine or amino alcohol capable of improving the brightness and mechanical properties of said coating and selected from the group which consists of: dimethylpropyn-2-ylamine, 1-diethylaminopropyn-(2), 1-diethylaminopentyn-2-ol-(4), 1-dimethylaminopropyn-(2), and 1,1-diethylpropyn-2-ylamine, and mixtures thereof.
Claim 2
Dependent Claim 109 words
In a method of electrodepositing a palladium/nickel alloy coating upon a substrate wherein said coating is plated onto said substrate by electrodeposition from a bath containing 5 to 30 g per liter of palladium and 5 to 30 g per liter of nickel and having a palladium-nickel ratio such that the coating contains 30 to 90% by weight of palladium, the improvement which comprises providing in said bath during the electrodeposition of said coating at least one acetyleneamine or amino alcohol capable of improving the brightness and mechanical properties of said coating and selected from the group which consists of: dimethylpropyn-2-ylamine, 1-diethylaminopropyn-(2), 1-diethylaminopentyn-2-ol-(4), 1-dimethylaminopropyn-(2), and 1,1-diethylpropyn-2-ylamine, and mixtures thereof.
Claim 3
Dependent Claim 125 words
A bath for the electrodeposition of palladium/nickel alloy coatings upon a substrate, said bath comprising an aqueous solution of a palladium amine in an amount sufficient to provide a palladium content in said bath of 5 to 30 g per liter, a nickel amine in an amount sufficient to provide a nickel content in said bath of 5 to 30 g per liter, the palladium-nickel ratio being sufficient to deposit a coating of 30 to 90 weight % palladium, and at least one acetyleneamine or acetyleneamino alcohol compound in an amount of 0.01 g per liter to 10 g per liter, sufficient to improve the brightness of said coating and selected from the group which consists of: dimethylpropyn-2-ylamine 1-diethylaminopropyn-(2) 1-diethylaminopentyn-2-ol-(4) 1-dimethylaminopropyn-(2) 1,1-diethylpropyn-2-ylamine and mixtures thereof.
Claim 4
Dependent Claim 125 words
A bath for the electrodeposition of palladium/nickel alloy coatings upon a substrate, said bath comprising an aqueous solution of a palladium amine in an amount sufficient to provide a palladium content in said bath of 5 to 30 g per liter, a nickel amine in an amount sufficient to provide a nickel content in said bath of 5 to 30 g per liter, the palladium-nickel ratio being sufficient to deposit a coating of 30 to 90 weight % palladium, and at least one acetyleneamine or acetyleneamino alcohol compound in an amount of 0.01 g per liter to 10 g per liter, sufficient to improve the brightness of said coating and selected from the group which consists of: dimethylpropyn-2-ylamine 1-diethylaminopropyn-(2) 1-diethylaminopentyn-2-ol-(4) 1-dimethylaminopropyn-(2) 1,1-diethylpropyn-2-ylamine and mixtures thereof.

References Cited (Backward Citations)

US2781306A Cited
US3002903A Cited
US3133006A Cited
US3186926A Cited
GB1143178A Cited
US4077855A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-11-21 1987-05-23 1987-11-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-11-21 1991-05-23 1991-11-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-11-21 1995-05-23 1995-11-22 $7700.00 Window Closed / Lapsed

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