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US4417066A Expired / Lapsed US ⏱️ 0.0 years remaining

Siloxane quaternary ammonium salt preparation

Assignee: Dow Silicones UK Ltd
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Filing: 1982-09-22
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Granted: 1983-11-22
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Expires: 2002-09-22
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Abstract

Abstract Process for the preparation of organosiloxane polymers wherein there are reacted together (A) a silanol-terminated polydiorganosiloxane in which at least 50% of the organic substituents are methyl, and (B) a quaternary ammonium silane RR'.sub.2 Si--Q--N.sup.+ X.sub.2 YZ.sup.31 wherein R' represents an alkoxy or alkoxyalkoxy group, R represents alkyl, phenyl, vinyl or a group as defined for R', Q represents a divalent group, X represents alkyl, aryl, aralkyl or alkaryl, Y represents a monovalent hydrocarbon group or the group (--OM) a OD, wherein M represents an alkylene group having 2 or 3 carbon atoms, a has a value of from 1 to 20 and D represents H, alkyl or acyl, and Z is a halogen atom. The organosiloxane polymers can be crosslinked and are useful for the treatment of textiles.

Inventors

  • 👤 Stephen Westall

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 15:05
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/643; D06M15/6436; C; C08; C08G; C08G77/00; C08G77/04; C08G77/22; C08G77/26; D06M13/00; D06M13/50; D06M13/51; D06M13/513

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 222 words
A process for the preparation of organosiloxanes which comprises reacting together (A) a silanol-terminated polydiorganosiloxane wherein at least 50 percent of the total substituents are methyl groups, any remaining organic substituents being monovalent hydrocarbon or fluorinated hydrocarbon groups having from 2 to 20 carbon atoms, and (B) an organosilane represented by the general formula RR'.sub.2 Si--Q--N.sup.+ X.sub.2 YZ.sup.- wherein R represents a group selected from alkyl groups having from 1 to 5 carbon atoms, the phenyl group, a vinyl group and groups as defined for R', each R' represents independently a group having less than 9 carbon atoms selected from alkoxy groups and alkoxyalkoxy groups, Q represents a divalent group having from 1 to 18 carbon atoms the said group being composed of carbon, hydrogen and, optionally, oxygen, any oxygen present being in the form of ether linkages, hydroxyl groups, or both, each X represents independently a group having from 1 to 12 carbon atoms selected from alkyl, aryl, aralkyl and alkaryl groups Y represents a monovalent hydrocarbon group have from 1 to 22 carbon atoms or the group (--OM) a OD, wherein M represents an alkylene group having 2 or 3 carbon atoms, a has a value of from 1 to 20 and D represents a hydrogen atom, an alkyl group or an acyl group, and Z represents a halogen atom.
Claim 2
Dependent Claim 222 words
A process for the preparation of organosiloxanes which comprises reacting together (A) a silanol-terminated polydiorganosiloxane wherein at least 50 percent of the total substituents are methyl groups, any remaining organic substituents being monovalent hydrocarbon or fluorinated hydrocarbon groups having from 2 to 20 carbon atoms, and (B) an organosilane represented by the general formula RR'.sub.2 Si--Q--N.sup.+ X.sub.2 YZ.sup.- wherein R represents a group selected from alkyl groups having from 1 to 5 carbon atoms, the phenyl group, a vinyl group and groups as defined for R', each R' represents independently a group having less than 9 carbon atoms selected from alkoxy groups and alkoxyalkoxy groups, Q represents a divalent group having from 1 to 18 carbon atoms the said group being composed of carbon, hydrogen and, optionally, oxygen, any oxygen present being in the form of ether linkages, hydroxyl groups, or both, each X represents independently a group having from 1 to 12 carbon atoms selected from alkyl, aryl, aralkyl and alkaryl groups Y represents a monovalent hydrocarbon group have from 1 to 22 carbon atoms or the group (--OM) a OD, wherein M represents an alkylene group having 2 or 3 carbon atoms, a has a value of from 1 to 20 and D represents a hydrogen atom, an alkyl group or an acyl group, and Z represents a halogen atom.
Claim 3
Dependent Claim 21 words
A process as claimed in claim 1 wherein polydiorganosiloxane (A) has a molecular weight within the range from 500 to 100,000.
Claim 4
Dependent Claim 33 words
A process as claimed in claim 1 or claim 2 wherein Q represents the group --(CH 2 ) 3 , --(CH 2 ) 4 -- or --CH 2 CH.CH 3 CH 2 --.
Claim 5
Dependent Claim 27 words
A process as claimed in claim 1 which also includes the further step of contacting the reaction product of (A) and (B) with a siloxane rearrangement catalyst.
Claim 6
Dependent Claim 18 words
A process as claimed in claim 1 when carried out in the presence of a siloxane rearrangement catalyst.
Claim 7
Dependent Claim 22 words
A process as claimed in claim 1 wherein the organosiloxane reaction product is subsequently crosslinked by reaction with an organosilicon crosslinking agent.

References Cited (Backward Citations)

US3389160A Cited
US3539605A Cited
US3819675A Cited
US3624120A Cited
US3658867A Cited
US4352917A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-11-21 1987-05-23 1987-11-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-11-21 1991-05-23 1991-11-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-11-21 1995-05-23 1995-11-22 $7700.00 Window Closed / Lapsed

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