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US4419463A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of cross-linked hydrogel copolymers for contact lenses

Assignee: Individual
•
Filing: 1982-03-16
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Granted: 1983-12-06
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Expires: 2002-03-16
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Abstract

Abstract The invention relates to soft contact lenses having a water content of at least about 45% and comprising a hydrated copolymer of a major proportion of an hydroxyalkyl acrylate or methacrylate, up to 12% by weight of an ethylenically unsaturated acid or anhydride, a minor proportion of a cross-linking monomer and a minor proportion of styrene or a substituted styrene, the free acid or anhydride groups being in salt form.

Inventors

  • 👤 Ivor B. Atkinson
  • 👤 Barry C. Holdstock

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 05:24
CPC Classifications
G; G02; G02C; G02C7/00; G02C7/02; G02C7/04; Y; Y10; Y10S; Y10S425/00; Y10S425/808; Y10S526/00; Y10S526/93; Y10S526/936

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 114 words
A method of producing a soft contact lens having a water content of at least about 30% by weight based on the weight of the hydrated lens which comprises: (a) preparing a monomer mixture containing a major proportion of a hydroxyalkyl acrylate or methacrylate, up to 12% by weight of an unsaturated carboxylic acid, a minor proportion of a cross-linking monomer, from about 4 to about 30% by weight of styrene or a substituted styrene and a polymerisation initiator, (b) removing oxygen from mixture, (c) filling the mixture into a suitably-shaped mould and effecting polymerisation in the absence of oxygen and, (d) converting free carboxylic acid groups in the resulting copolymer to salt form.
Claim 2
Independent Claim 114 words
A method of producing a soft contact lens having a water content of at least about 30% by weight based on the weight of the hydrated lens which comprises: (a) preparing a monomer mixture containing a major proportion of a hydroxyalkyl acrylate or methacrylate, up to 12% by weight of an unsaturated carboxylic acid, a minor proportion of a cross-linking monomer, from about 4 to about 30% by weight of styrene or a substituted styrene and a polymerisation initiator, (b) removing oxygen from mixture, (c) filling the mixture into a suitably-shaped mould and effecting polymerisation in the absence of oxygen and, (d) converting free carboxylic acid groups in the resulting copolymer to salt form.
Claim 3
Dependent Claim 48 words
A method according to claim 1 wherein, prior to step (d), the resulting shaped, hard copolymer is machined to form a lens and the lens is then swollen by immersion in an aqueous solution and free carboxylic groups converted to salt form by treatment with a mild alkali.

References Cited (Backward Citations)

US3876581A Cited
GB1475605A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-12-05 1987-06-06 1987-12-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-12-05 1991-06-06 1991-12-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-12-05 1995-06-06 1995-12-06 $7700.00 Window Closed / Lapsed

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