Process for mass-dyeing of thermoplastics: polystyrene and styrene copolymers with indoline methine dyes

Claim 2

Process for mass-dyeing of polystyrene and styrene copolymers, characterised in that the dyestuffs used are of the formula ##STR15## in which X designates a radical ##STR16## R designates hydrogen or alkyl, R 1 and R 2 designate alkyl, R 3 designates hydrogen, cyano, aroyl, alkoxycarbonyl, alkylcarbonyl or carbamoyl, R 4 designates aryl, R 5 designates alkyl, alkylcarbonyl, alkoxycarbonyl or aryl, R 6 designates alkyl, aryl, aralkyl or aralkenyl, and Y designates O or NR 7 , with R 7 having the meaning hydrogen, alkyl, aralkyl or aryl, it being possible for the radicals which have been mentioned for R 7 and R 1 -R 7 and which contain C--H or N--H bonds to be substituted, and wherein the ring A can carry 1, 2 or 3 substituents from the series comprising halogen, cyano, alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, aralkoxycarbonyl, carbamoyl, sulphamoyl, alkylsulphonyl and arylsulphonyl, or can have a benzene ring fused to it, it being possible for the radicals which have been mentioned as substituents of the ring A and which contain C--H or N--H bonds to be substituted.

Claim 3

Process according to claim 1, characterised in that compounds of the formula ##STR17## are used, in which X' represents ##STR18## and R' designates hydrogen, methyl or ethyl, R 1 ' and R 2 ' designate methyl or ethyl, R 3 ' designates hydrogen, cyano, aroyl, in particular benzoyl and naphthoyl, alkoxycarbonyl, in particular (C 1 -C 4 -alkoxy)-carbonyl or carbamoyl, R 4 ' designates phenyl which can be substituted by methyl, ethyl, methoxy, ethoxy or chlorine, R 5 ' designates methyl, methoxycarbonyl or ethoxycarbonyl, or phenyl which can be substituted by methyl and/or ethyl, R 6 ' designates C 1 -C 4 -alkyl, phenyl, chlorophenyl or methylphenyl, or phenyl-C 1 -C 3 -alkyl which can be substituted in the phenyl nucleus by chlorine and/or methyl, or designates phenylallyl or phenoxyethyl, Y' designates O or NR 7 ', wherein R 7 ' represents alkyl, in particular C 1 -C 4 -alkyl, or aralkyl, in particular phenyl-C 1 -C 3 -alkyl, L designates hydrogen, chlorine, cyano, methyl, ethyl, methoxy, ethoxy, methoxycarbonyl, ethoxycarbonyl or benzyloxycarbonyl, or sulphamoyl or carbamoyl which is optionally substituted by methyl, ethyl or phenyl, or designates methylsulphonyl or phenylsulphonyl, and M and Q designate hydrogen, methyl, ethyl, methoxy, ethoxy, chlorine or methoxycarbonyl, and two of the substituents L, M and Q together can form a fused benzene ring.

Claim 4

Process according to claim 1, characterised in that compounds of the formula II are used, in which R' designates hydrogen or methyl, R 1 ' and R 2 ' designate methyl, R 3 ' designates hydrogen, cyano or benzoyl, R 4 ' designates phenyl which can be substituted by methyl, methoxy and/or chlorine, R 5 ' designates methyl or methoxycarbonyl, L designates hydrogen, methoxycarbonyl, cyano, methoxy or chlorine, M and Q designate hydrogen, Y' designates O, and R 6 ' designates C 1 -C 4 -alkyl, phenyl, chlorophenyl or methylphenyl, or phenyl-C 1 -C 3 -alkyl, the phenyl radical of which can be substituted by chlorine or methyl, or designates phenoxyethyl.

Claim 5

Process according to claim 1, characterised in that the dyestuff of the formula ##STR19## is used.

Claim 6

Process according to claim 1, characterised in that the dyestuff of the formula ##STR20## is used.

Claim 7

Process according to claim 1, for dyeing polystyrene.

Claim 8

Process according to claim 1, for dyeing polystyrene copolymers.

Claim 9

Process according to claim 1, for dyeing ABS.