Photosensitive resin composition comprised of a polymer obtained from an aliphatic amino group-containing monomer as a comonomer

Claim 2

A solvent developable photosensitive resin composition consisting essentially of (a) a film forming property imparting polymer obtained by using as a comonomer in an amount of 0.1 to 10% by weight, a monomer containing an aliphatic amino group represented by the formula: ##STR4## wherein R 1 , R 2 and R 3 are independently hydrogen or a methyl group; R 4 and R 5 are independently an alkyl group having 1 to 4 carbon atoms, or R 4 and R 5 may form a saturated alicyclic 4- to 7-membered ring together with the nitrogen atom; and n is zero or an integer of 1 to 3, (b) an ethylenic unsaturated compound other than the monomer represented by formula (1), (c) a photosensitizer and/or a photosensitizer system capable of forming free radicals by actinic light, and (d) an organic halogen compound capable of liberating halogen radicals by exposure to actinic light or by chain transfer.

Claim 3

A composition according to claim 1, wherein the polymer of the component (a) is derived from the monomer of the formula (1) in an amount of 0.2 to 5% by weight.

Claim 4

A composition according to claim 1 or 2, wherein the monomer of the formula (1) is a N,N-dialkylaminoethyl acrylate or a N,N-dialkylaminoethyl methacrylate.

Claim 5

A composition according to claim 2, wherein the monomer of the formula (1) is dimethylaminoethyl methacrylate, dimethylaminoethyl acrylate, or diethylaminoethyl methacrylate.

Claim 6

A composition according to claim 1, wherein the component (d) is an aliphatic halogen compound.

Claim 7

A composition according to claim 5, wherein the aliphatic halogen compound has at least one carbon atom which is bonded to two or more halogen atoms.

Claim 8

A composition according to claim 1, wherein the component (d) is an organic bromine compound.

Claim 9

A composition according to claim 1, wherein the component (d) is an organic halogen compound having a tribromomethyl group.

Claim 10

A composition according to claim 1, wherein the component (b) is an acrylate or methacrylate monomer.

Claim 11

A composition according to claim 1, wherein the amount of the component (a) is 30 to 80 parts by weight, the amount of the component (b) is 70 to 20 parts by weight, the total being 100 parts by weight, and the amount of the component (c) is 0.5 to 10 parts by weight and the amount of the component (d) is 0.2 to 10 parts by weight, each (c) and (d) being based on 100 parts by weight of the total of (a) and (b).

Claim 12

A composition according to claim 1 or claim 10, wherein the component (a) is derived from the monomer of the formula (1) and one or more comonomers selected from the group consisting of methyl methacrylate, butyl methacrylate, lauryl methacrylate, ethyl acrylate, methyl acrylate, styrene, vinyltoluene, α-methylstyrene, 2-hydroxyethyl methacrylate, 2-hydroxyethyl acrylate and acrylamide in an amount of 99.9 to 90% by weight.

Claim 13

A photosensitive element comprising a support film and formed on said support film a layer of a solvent developable photosensitive resin composition consisting essentially of (a) a film forming property imparting polymer obtained by using as a comonomer in an amount of 0.1 to 10% by weight, a monomer containing an aliphatic amino group represented by the formula: ##STR5## wherein R 1 , R 2 and R 3 are independently hydrogen or a methyl group; R 4 and R 5 are independently an alkyl group having 1 to 4 carbon atoms, or R 4 and R 5 may form a saturated alicyclic 4- to 7-membered ring together with the nitrogen atom; and n is zero or an integer of 1 to 3, (b) an ethylenic unsaturated compound other than the monomer represented by formula (1), (c) a photosensitizer and/or a photosensitizer system capable of forming free radicals by actinic light, and (d) an organic halogen compound capable of liberating halogen radicals by exposure to actinic light or by chain transfer.

Claim 14

A photosensitive element comprising a support film and formed on said support film a layer of a solvent developable photosensitive resin composition consisting essentially of (a) a film forming property imparting polymer obtained by using as a comonomer in an amount of 0.1 to 10% by weight, a monomer containing an aliphatic amino group represented by the formula: ##STR5## wherein R 1 , R 2 and R 3 are independently hydrogen or a methyl group; R 4 and R 5 are independently an alkyl group having 1 to 4 carbon atoms, or R 4 and R 5 may form a saturated alicyclic 4- to 7-membered ring together with the nitrogen atom; and n is zero or an integer of 1 to 3, (b) an ethylenic unsaturated compound other than the monomer represented by formula (1), (c) a photosensitizer and/or a photosensitizer system capable of forming free radicals by actinic light, and (d) an organic halogen compound capable of liberating halogen radicals by exposure to actinic light or by chain transfer.

Claim 15

A photosensitive element according to claim 12, wherein the amount of the component (a) is 30 to 80 parts by weight, the amount of the component (b) is 70 to 20 parts by weight, the total being 100 parts by weight, and the amount of the component (c) is 0.5 to 10 parts by weight and the amount of the component (d) is 0.2 to 10 parts by weight, each (c) and (d) being based on 100 parts by weight of the total of (a) and (b).

Claim 16

A photosensitive element according to claim 12, wherein the monomer of the formula (1) is a N,N-dialkylaminoethyl acrylate or a N,N-dialkylaminoethyl methacrylate.

Claim 17

A photosensitive element according to claim 12, wherein the component (d) is an aliphatic halogen compound.

Claim 18

A photosensitive element according to claim 12, wherein the polymer of the component (a) is derived from the monomer of the formula (1) in an amount of 0.2 to 5% by weight.

Claim 19

A photosensitive element according to claim 12, wherein the monomer of the formula (1) is dimethylaminoethyl methacrylate, dimethylaminoethyl acrylate, or diethylaminoethyl methacrylate.

Claim 20

A photosensitive element according to claim 15, wherein the aliphatic halogen compound has at least one carbon atom which is bonded to two or more halogen atoms.

Claim 21

A photosensitive element according to claim 12, wherein the component (d) is an organic bromine compound.

Claim 22

A photosensitive element according to claim 12, wherein the component (d) is an organic halogen compound having a tribromomethyl group.

Claim 23

A photosensitive element according to claim 12, wherein the component (b) is an acrylate or methacrylate monomer.

Claim 24

A photosensitive element according to claim 12 or claim 13, wherein the component (a) is derived from the monomer of the formula (1) and one or more comonomers selected from the group consisting of methyl methacrylate, butyl methacrylate, lauryl methacrylate, ethyl acrylate, methyl acrylate, styrene, vinyltoluene, α-methylstyrene, 2-hydroxyethyl methacrylate, 2-hydroxyethyl acrylate and acrylamide in an amount of 99.9 to 90% by weight.