US4458039A
Expired / Lapsed
US
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Thermotropic liquid crystalline polymer blend with reduced surface abrasion
Assignee: Celanese Corp
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Filing: 1983-02-07
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Granted: 1984-07-03
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Expires: 2003-02-07
Abstract
Abstract A thermotropic liquid crystalline polymer matrix having wollastonite fibers incorporated therein for reinforcement to prepare a molding compound. The wollastonite fibers have an average aspect ratio of greater than 3 to 1, and may be coated on their surface with a coupling agent to produce better bonding between the fibers and the thermotropic liquid crystalline polymer. The surface abrasion of an article produced from a blend of wollastonite with a thermotropic liquid crystalline polymer is reduced as compared to that of unfilled polymer.
Inventors
- 👤 Nancy C. Eickman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 16:38
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/34; C08K7/00; C08K7/02; C08K7/04; C08K7/10; C08K9/00; C08K9/04; C08K2201/00; C08K2201/016
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
30 words
A molding compound comprising a thermotropic liquid crystalline polymer matrix having wollastonite fibers incorporated therein, the wollastonite fibers having an average aspect ratio of greater than about 3 to 1.
Claim 2
Dependent Claim
30 words
A molding compound comprising a thermotropic liquid crystalline polymer matrix having wollastonite fibers incorporated therein, the wollastonite fibers having an average aspect ratio of greater than about 3 to 1.
Claim 3
Dependent Claim
21 words
The molding compound of claim 1 wherein the wollastonite fibers have an average aspect ratio of at least 10 to 1.
Claim 4
Dependent Claim
21 words
The molding compound of claim 1 wherein the wollastonite fibers have an average aspect ratio of at least 20 to 1.
Claim 5
Dependent Claim
32 words
The molding compound of claim 1 wherein the wollastonite fibers are treated with a titanate coupling agent prior to being blended with the thermotropic liquid crystalline polymer to produce the molding compound.
Claim 6
Dependent Claim
25 words
The molding compound of claim 1 wherein the wollastonite fibers are present in the molding compound at between about 10 and about 70% by weight.
Claim 7
Dependent Claim
25 words
The molding compound of claim 1 wherein the wollastonite fibers are present in the molding compound at between about 10 and about 40% by weight.
Claim 8
Dependent Claim
39 words
The molding compound of claim 1 wherein the thermotropic liquid crystalline polymer has an inherent viscosity of between about 1.0 and about 15 dl./g. when dissolved in a concentration of 0.1 percent by weight of pentafluorophenol at 60° C.
Claim 9
Dependent Claim
42 words
The molding compound of claim 1 wherein the thermotropic liquid crystalline polymer is selected from the group consisting of a wholly aromatic polyester, an aromatic-aliphatic polyester, a wholly aromatic poly(ester-amide), an aromatic-aliphatic poly(ester-amide), an aromatic polyazomethine, an aromatic polyester-carbonate, and mixtures thereof.
Claim 10
Dependent Claim
33 words
The molding compound of claim 1, wherein the thermotropic liquid crystalline polymer is selected from the group consisting of a wholly aromatic polyester, a wholly aromatic poly(ester-amide), an aromatic-aliphatic poly(ester-amide), and mixtures thereof.
Claim 11
Dependent Claim
209 words
The molding compound of claim 1, wherein the thermotropic liquid crystalline polymer is a melt processable poly(ester-amide) capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of recurring moieties I, II, III, and, optionally, IV wherein: ##STR8## where A is a divalent radical comprising at least one aromatic ring or a divalent trans-1,4-cyclohexylene radical; III is --Y--Ar--Z--, where Ar is a divalent radical comprising at least one aromatic ring, Y is O, NH, or NR, and Z is NH or NR, where R is an alkyl group of 1 to 6 carbon atoms or an aryl group; and IV is --O--Ar'--O--, where Ar' is a divalent radical comprising at least one aromatic ring; wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures thereof, and wherein said poly(ester-amide) comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, approximately 5 to 45 mole percent of moiety III, and approximately 0 to 40 mole percent of moiety IV.
Claim 12
Dependent Claim
180 words
The molding compound of claim 1, wherein the thermotropic liquid crystalline polymer is a melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 400° C., consisting essentially of the recurring moieties I, II, and III which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: ##STR9## II is a dioxy aryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, and III is a dicarboxy aryl moiety of the formula ##STR10## where Ar' is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group and mixtures of the foregoing, and wherein said polyester comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, and approximately 5 to 45 mole percent of moiety III.
Claim 13
Dependent Claim
122 words
The molding compound of claim 1, wherein the thermotropic liquid crystalline polymer is a melt processable wholly aromatic polyester capable of forming a thermotropic melt phase at a temperature below approximately 350° C. consisting essentially of the recurring moieties I and II which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: ##STR11## with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures of the foregoing, and wherein said polyester comprises approximately 10 to 90 mole percent of moiety I, and approximately 10 to 90 percent of moiety II.
Claim 14
Dependent Claim
11 words
A molded article produced from the molding compound of claim 1.
Claim 15
Dependent Claim
11 words
An extruded article produced from the molding compound of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-07-03 | 1988-01-02 | 1988-07-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-07-03 | 1992-01-02 | 1992-07-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-07-03 | 1996-01-02 | 1996-07-03 | $7700.00 | Window Closed / Lapsed |