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US4460675A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for preparing an overcoated photopolymer printing plate

Assignee: EIDP Inc
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Filing: 1983-10-27
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Granted: 1984-07-17
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Expires: 2003-10-27
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Abstract

Abstract Process for preparing flexographic photopolymer elements by passing into the nip of a calender a photopolymer composition mass comprising elastomeric binder, monomeric compound, and photoinitiator and calendering the photopolymer composition either between (1) a support and multilayer cover element consisting essentially of a flexible cover film, optionally a flexible polymeric film, e.g., polyamide, and a layer of elastomeric composition which is photosensitive or becomes photosensitive during or after calendering, or between (2) two supports, one of which is removed prior to contact, e.g., by lamination or pressing, with the multilayer cover element. The flexographic photopolymer elements are useful for flexographic printing, e.g., dry-offset, letterpress printing.

Inventors

  • 👤 Robert R. Gruetzmacher
  • 👤 Stanley H. Munger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 19:52
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/09; G03F7/095; G03F7/0955; G03F7/16

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 250 words
A process for preparing a flexographic printing plate which comprises (1) exposing to actinic radiation through an image a flexographic photopolymerizable element prepared by passing into the nip of a calender a mass of a hot photopolymerizable composition comprising an elastomeric binder, an ethylenically unsaturated compound having at least one terminal ethylenic group, and a photoinitiator or photoinitiator system, and, while hot, calendering the photopolymerizable composition between a support and a multilayer cover element to form a photopolymerizable layer therebetween, wherein the multilayer cover element consists essentially of a flexible cover film and a layer of an elastomeric composition and optionally between the flexible cover film and the layer of elastomeric composition a flexible polymeric film, the layer of elastomeric composition being adjacent to the photopolymerizable layer and being photosensitive or becoming photosensitive during or after calendering by contact with the photopolymerizable layer, said layer of elastomeric composition comprising an elastomeric polymeric binder and optionally a second polymeric binder and a nonmigratory dye or pigment and, in addition, when said layer of elastomeric composition is photosensitive one or more ethylenically unsaturated monomeric compounds and/or photoinitiator or initiator system, the cover film of said photopolymerizable element optionally has been removed after calendering but prior to exposure, (2) removing the image and cover film if still present, and (3) removing by liquid development the flexible polymeric film, if present, and the unexposed areas of the layer of elastomeric composition and photopolymerizable layer; and (4) optionally removing any residual liquid developer by drying.
Claim 2
Dependent Claim 250 words
A process for preparing a flexographic printing plate which comprises (1) exposing to actinic radiation through an image a flexographic photopolymerizable element prepared by passing into the nip of a calender a mass of a hot photopolymerizable composition comprising an elastomeric binder, an ethylenically unsaturated compound having at least one terminal ethylenic group, and a photoinitiator or photoinitiator system, and, while hot, calendering the photopolymerizable composition between a support and a multilayer cover element to form a photopolymerizable layer therebetween, wherein the multilayer cover element consists essentially of a flexible cover film and a layer of an elastomeric composition and optionally between the flexible cover film and the layer of elastomeric composition a flexible polymeric film, the layer of elastomeric composition being adjacent to the photopolymerizable layer and being photosensitive or becoming photosensitive during or after calendering by contact with the photopolymerizable layer, said layer of elastomeric composition comprising an elastomeric polymeric binder and optionally a second polymeric binder and a nonmigratory dye or pigment and, in addition, when said layer of elastomeric composition is photosensitive one or more ethylenically unsaturated monomeric compounds and/or photoinitiator or initiator system, the cover film of said photopolymerizable element optionally has been removed after calendering but prior to exposure, (2) removing the image and cover film if still present, and (3) removing by liquid development the flexible polymeric film, if present, and the unexposed areas of the layer of elastomeric composition and photopolymerizable layer; and (4) optionally removing any residual liquid developer by drying.
Claim 3
Dependent Claim 33 words
A process according to claim 1 wherein after liquid development and optional drying the element is, in either order, detackified by treating with a solution containing free halogen, and postexposed to actinic radiation.
Claim 4
Dependent Claim 29 words
A process according to claim 1 wherein the flexible polymeric film is present in the multilayer cover element between the flexible cover film and the layer of elastomeric composition.
Claim 5
Dependent Claim 21 words
A process according to claim 1 wherein the mass of photopolymerizable composition is passed into the calender nip by an extruder.
Claim 6
Dependent Claim 26 words
A process according to claim 1 wherein the mass of photopolymerizable composition is passed into the calender nip as a hot melt from a mixing mill.
Claim 7
Dependent Claim 34 words
A process according to claim 1 wherein calendering occurs between two flexible supports, one of which is subsequently removed from the photopolymerizable layer, and the multilayer cover element is laminated to the photopolymerizable layer.
Claim 8
Dependent Claim 35 words
A process according to claim 1 wherein calendering occurs between two flexible sheets, one of which is subsequently removed from the photopolymerizable layer, and the multilayer cover element and photopolymerizable layer are pressed into contact.
Claim 9
Dependent Claim 20 words
A process according to claim 1 wherein the elastomeric layer in the multilayer cover element is a photopolymerizable elastomeric layer.
Claim 10
Dependent Claim 24 words
A process according to claim 1 wherein the flexible cover film in the multilayer cover element is a film bearing a silicone subbing layer.
Claim 11
Dependent Claim 15 words
A process according to claim 3 wherein the flexible polymeric film is a polyamide film.
Claim 12
Dependent Claim 20 words
A process according to claim 1 wherein the elastomeric composition in the multilayer cover element comprises an elastomeric block copolymer.
Claim 13
Dependent Claim 15 words
A process according to claim 11 wherein the block copolymer is a polystyrene-isoprene-polystyrene block copolymer.
Claim 14
Dependent Claim 15 words
A process according to claim 11 wherein the block copolymer is a polystyrene-polybutadiene-polystyrene block copolymer.
Claim 15
Dependent Claim 32 words
A process according to claim 1 wherein the photopolymerizable composition is passed into the nip of the calender by extruding at a temperature in the range of about 130° to 200° C.
Claim 16
Dependent Claim 19 words
A process according to claim 1 wherein the elastomeric binder of the photopolymerizable composition is an elastomeric block copolymer.
Claim 17
Dependent Claim 16 words
A process according to claim 15 wherein the ethylenically unsaturated compound has two terminal ethylenic groups.
Claim 18
Dependent Claim 23 words
A process according to claim 16 wherein the ethylenically unsaturated compound is hexamethylene glycol diacrylate, hexamethylene glycol dimethacrylate or a mixture of both.
Claim 19
Dependent Claim 15 words
A process according to claim 1 wherein a colorant is present in the photopolymerizable layer.
Claim 20
Dependent Claim 37 words
A process according to claim 18 wherein a nonmigrating dye or pigment is present in the layer of elastomeric composition of the multilayer cover element which provides a contrasting color with the colorant in the photopolymerizable layer.

References Cited (Backward Citations)

US3287152A Cited
GB1366769A Cited
US4323636A Cited
US4323637A Cited
US4369246A Cited
US3990897A Cited
US4228534A Cited
US4179531A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-07-17 1988-01-16 1988-07-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-07-17 1992-01-16 1992-07-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-07-17 1996-01-16 1996-07-17 $7700.00 Window Closed / Lapsed

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