Process and apparatus for the separation of particles into three fractions of similar compositions

Claim 2

In a process for the separation of higher-grade limestone from lower-grade limestone and the gangue present in particulate limestone ore by the steps of conditioning the particulate limestone ore with at least one surface-active agent selected from saturated and unsaturated carboxylic acids containing from about 4 to about 22 carbon atoms, said surface-active agent selectively coating the calcium carbonate in the limestone ore to the substantial exclusion of coating gangue in combination with providing at least one fluorescent dye to said surface-active agent, irradiating the conditioned particulate limestone ore to excite and induce fluorescence of the fluorescent dye and separating the ore particles into a first fraction of fluorescing coated higher-grade limestone particles and a second fraction of coated lower-grade limestone and non-fluorescing gangue particles, the improvement comprising the step of separating the limestone particles into three fractions each of similar concentration of calcium carbonate by distinguishing among the intensities of fluorescence of the provided fluorescent dye on the particles with a first fraction comprising particles exhibiting a relatively high intensity of fluorescence, a second fraction comprising particles exhibiting a relative intensity of fluorescence lower than particles in the first fraction and a third fraction comprising particles exhibiting a relative intensity of fluorescence lower than particles in the second fraction.

Claim 3

A process as recited in claim 1 wherein the particles are separated into three fractions while in free-fall by deflecting some of the free-fall particles into either of two deflected free-fall paths and by permitting some of the particles to free-fall in an undeflected path based upon the intensity of fluorescence of the particles.

Claim 4

In a process for the separation for higher-grade limestone from lower-grade limestone and the silicate-containing gangue present in particulate limestone ore by the steps of conditioning the particulate limestone ore with at least one surface-active agent selected from the group consisting of aliphatic amines containing from about 8 to about 22 carbon atoms and beta amines containing from about 7 to about 21 carbon atoms, said surface-active agent selectively coating the silicates in the particles to the substantial exclusion of coating the calcium carbonate in the particles, in combination with providing at least one fluorescent dye to said surface-active agent, irradiating the conditioned particulate limestone ore to excite and induce fluorescence of the fluorescent dye and separating the fluorescing coated silicate-containing particles from the substantially nonfluorescing calcium carbonate containing particles, the improvement comprising the step of separating the limestone ore particles into three fractions, each of similar concentration of calcium carbonate by distinguishing among the intensities of fluorescence of the provided fluorescent dye on the particles with a first fraction comprising particles exhibiting a relatively high intensity of fluorescence, a second fraction comprising particles exhibiting a relative intensity of fluorescence lower than particles in the first fraction and a third fraction comprising particles exhibiting a relative intensity of fluorescence lower than particles in the second fraction.

Claim 5

In a process for the separation for higher-grade limestone from lower-grade limestone and the silicate-containing gangue present in particulate limestone ore by the steps of conditioning the particulate limestone ore with at least one surface-active agent selected from the group consisting of aliphatic amines containing from about 8 to about 22 carbon atoms and beta amines containing from about 7 to about 21 carbon atoms, said surface-active agent selectively coating the silicates in the particles to the substantial exclusion of coating the calcium carbonate in the particles, in combination with providing at least one fluorescent dye to said surface-active agent, irradiating the conditioned particulate limestone ore to excite and induce fluorescence of the fluorescent dye and separating the fluorescing coated silicate-containing particles from the substantially nonfluorescing calcium carbonate containing particles, the improvement comprising the step of separating the limestone ore particles into three fractions, each of similar concentration of calcium carbonate by distinguishing among the intensities of fluorescence of the provided fluorescent dye on the particles with a first fraction comprising particles exhibiting a relatively high intensity of fluorescence, a second fraction comprising particles exhibiting a relative intensity of fluorescence lower than particles in the first fraction and a third fraction comprising particles exhibiting a relative intensity of fluorescence lower than particles in the second fraction.

Claim 6

A process as recited in claim 3 wherein the particles are separated into three fractions while in free-fall by deflecting some of the free-falling particles into either of two deflected free-fall paths and by permitting some particles to free-fall in an undeflected path based upon the intensity of fluorescence of the particles.