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US4468527A Expired / Lapsed US ⏱️ 0.0 years remaining

Fluorinated alcohols

Assignee: 3M Co
•
Filing: 1982-03-15
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Granted: 1984-08-28
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Expires: 2002-03-15
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Abstract

Abstract A fluoroaliphatic radical- and aliphatic chlorine-containing alcohol containing more than 25 weight percent carbon-bonded fluorine in the form of fluoroaliphatic radicals and at least one aliphatic chlorine, an ester of said alcohol and a carboxycylic acid being useful in the treatment of carpet.

Inventors

  • 👤 Kalyanji U. Patel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 13:18
CPC Classifications
D; D06; D06M; D06M13/00; D06M13/10; D06M13/144; C; C07; C07C; C07C311/00; C07C311/01; C07C311/02; C07C311/09; C07C2601/00; C07C2601/12; C07C2601/14

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 226 words
An alcohol having the formula R.sub.f --Q--A--OH where R f is a fluoroaliphatic, saturated, monovalent radical having at least three fully fluorinated carbon atoms and not more than 20 carbon atoms, said alcohol having more than 25 weight % carbon-bonded fluorine in the form of said fluoroaliphatic radical, Q is selected from the group consisting of --CO--, --CONR--, --SO 2 NR--, --SO 2 --, C n H 2n --, --C 6 H 4 --, --C 6 H 3 Cl--, --OC 2 H 4 --, or combinations thereof, where R is H or lower alkyl containing 1 to 6 carbon atoms, and n is 1 to 20, and A is a divalent organic moiety having 2 to 30 carbon atoms, containing at least one aliphatic chlorine atom, and free of hydroxyl-reactive substituents, said alcohol upon reaction with a mono- or polycarboxylic acid forming the corresponding ester which in combination with water-insoluble addition polymer derived from polymerizable ethylenically unsaturated monomer free of nonvinylic fluorine forms a composition suitable for the treatment of carpet to render it durably soil resistant and stain repellant, said ester containing at least 25 percent by weight of carbon-bonded fluorine, in the form of said fluoroaliphatic radical, and having at least one major transition temperature higher than about 25° C., said polymer having at least one major transition temperature higher than about 25° C.
Claim 2
Dependent Claim 226 words
An alcohol having the formula R.sub.f --Q--A--OH where R f is a fluoroaliphatic, saturated, monovalent radical having at least three fully fluorinated carbon atoms and not more than 20 carbon atoms, said alcohol having more than 25 weight % carbon-bonded fluorine in the form of said fluoroaliphatic radical, Q is selected from the group consisting of --CO--, --CONR--, --SO 2 NR--, --SO 2 --, C n H 2n --, --C 6 H 4 --, --C 6 H 3 Cl--, --OC 2 H 4 --, or combinations thereof, where R is H or lower alkyl containing 1 to 6 carbon atoms, and n is 1 to 20, and A is a divalent organic moiety having 2 to 30 carbon atoms, containing at least one aliphatic chlorine atom, and free of hydroxyl-reactive substituents, said alcohol upon reaction with a mono- or polycarboxylic acid forming the corresponding ester which in combination with water-insoluble addition polymer derived from polymerizable ethylenically unsaturated monomer free of nonvinylic fluorine forms a composition suitable for the treatment of carpet to render it durably soil resistant and stain repellant, said ester containing at least 25 percent by weight of carbon-bonded fluorine, in the form of said fluoroaliphatic radical, and having at least one major transition temperature higher than about 25° C., said polymer having at least one major transition temperature higher than about 25° C.
Claim 3
Dependent Claim 107 words
An alcohol having the formula R.sub.f (Q).sub.m CH(OH)CHRCl where R is hydrogen or lower alkyl, R f is a fluoroaliphatic, saturated, monovalent radical having at least three fully fluorinated carbon atoms and not more than 20 carbon atoms, said alcohol having more than 25 weight % carbon-bonded fluorine in the form of said fluoroaliphatic radical, Q is selected from the group consisting of --CO--, --CONR--, --SO 2 NR--, --SO 2 , --C n H 2n --, --C 6 H 4 --, --C 6 H 3 Cl--, OC 2 H 4 --, or combinations thereof, where R is H or lower alkyl containing 1-6 carbons, m is 1.
Claim 4
Dependent Claim 107 words
An alcohol having the formula R.sub.f (Q).sub.m CH(OH)CHRCl where R is hydrogen or lower alkyl, R f is a fluoroaliphatic, saturated, monovalent radical having at least three fully fluorinated carbon atoms and not more than 20 carbon atoms, said alcohol having more than 25 weight % carbon-bonded fluorine in the form of said fluoroaliphatic radical, Q is selected from the group consisting of --CO--, --CONR--, --SO 2 NR--, --SO 2 , --C n H 2n --, --C 6 H 4 --, --C 6 H 3 Cl--, OC 2 H 4 --, or combinations thereof, where R is H or lower alkyl containing 1-6 carbons, m is 1.
Claim 5
Dependent Claim 123 words
An alcohol having the formula ##STR8## where R 1 is hydrogen or lower alkyl, R 2 is hydrogen, lower alkyl, or aryl, R f is a fluoroaliphatic, saturated, monovalent radical having at least three fully fluorinated carbon atoms and not more than 20 carbon atoms, said alcohol having more than 25 weight % carbon-bonded fluorine in the form of said fluoroaliphatic radical, Q is selected from the group consisting of --CO--, --CONR--, --SO 2 NR--, --SO 2 --, --C n H 2n --, --C 6 H 4 --, --C 6 H 3 Cl--, OC 2 H 4 --, or combinations thereof where R is H or lower alkyl containing 1-6 carbons, m is 1, and p is an integer of 1 to 5.
Claim 6
Dependent Claim 123 words
An alcohol having the formula ##STR8## where R 1 is hydrogen or lower alkyl, R 2 is hydrogen, lower alkyl, or aryl, R f is a fluoroaliphatic, saturated, monovalent radical having at least three fully fluorinated carbon atoms and not more than 20 carbon atoms, said alcohol having more than 25 weight % carbon-bonded fluorine in the form of said fluoroaliphatic radical, Q is selected from the group consisting of --CO--, --CONR--, --SO 2 NR--, --SO 2 --, --C n H 2n --, --C 6 H 4 --, --C 6 H 3 Cl--, OC 2 H 4 --, or combinations thereof where R is H or lower alkyl containing 1-6 carbons, m is 1, and p is an integer of 1 to 5.

References Cited (Backward Citations)

GB1172082A Cited
US3663604A Cited
US4289892A Cited
GB1410845A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-28 1988-02-27 1988-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-28 1992-02-27 1992-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-28 1996-02-27 1996-08-28 $7700.00 Window Closed / Lapsed

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