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US4486246A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyoxazolines in aqueous quenchants

Assignee: Houghton Technical Corp
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Filing: 1983-12-16
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Granted: 1984-12-04
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Expires: 2003-12-16
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Abstract

Abstract Metal, such as steel, is quenched in a quenching bath comprising an aqueous solution of a substituted oxazoline polymer, one example of which is polyethyloxazoline having a molecular weight of 50,000 to 500,000. The bath is capable of providing quenching effects similar to those produced by oil quenchants, as well as quenching times between those provided by oil and water.

Inventors

  • 👤 Joseph F. Warchol

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 15:50
CPC Classifications
C; C21; C21D; C21D1/00; C21D1/56; C21D1/60; C21D1/34; C21D1/44; C21D1/48

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 132 words
In the process of quenching which is useful in the heat treatment of metals wherein a metal is heated to an elevated temperature and said heated metal is then quenched in a bath comprising a liquid quenching medium to effect desirable metallurgical changes in the metal, the improvement which comprises using as said quenching medium an aqueous solution containing an effective cooling rate reducing amount of a nonionic, water-soluble or water-dispersible substituted oxazoline polymer having recurring units of the general formula ##STR3## where R is an organic radical which does not significantly alter the nonionic and water-solubility and water-dispersibility characteristics of the polymer when said polymer is present in said concentrations, and n is an integer such as to provide said polymer with a molecular weight of from about 5000 to 1,000,000.
Claim 2
Dependent Claim 132 words
In the process of quenching which is useful in the heat treatment of metals wherein a metal is heated to an elevated temperature and said heated metal is then quenched in a bath comprising a liquid quenching medium to effect desirable metallurgical changes in the metal, the improvement which comprises using as said quenching medium an aqueous solution containing an effective cooling rate reducing amount of a nonionic, water-soluble or water-dispersible substituted oxazoline polymer having recurring units of the general formula ##STR3## where R is an organic radical which does not significantly alter the nonionic and water-solubility and water-dispersibility characteristics of the polymer when said polymer is present in said concentrations, and n is an integer such as to provide said polymer with a molecular weight of from about 5000 to 1,000,000.
Claim 3
Dependent Claim 48 words
A process according to claim 1 in which the concentration of said polymer in said quenching medium is from about 0.5% to 5%, by weight, based on the total weight of the quenching medium, and said polymer has a molecular weight of from about 50,000 to about 500,000.
Claim 4
Dependent Claim 41 words
A process according to claim 2 in which the concentration of said polymer in said quenching medium is from about 1.5% to about 3%, and said polymer has a molecular weight in the range of from about 200,000 to about 500,000.
Claim 5
Dependent Claim 157 words
In the process of quenching which is useful in the heat treatment of metals wherein a metal is heated to an elevated temperature and said heated metal is then quenched in a bath comprising a liquid quenching medium to effect desirable metallurgical changes in the metal, the improvement which comprises using as said quenching medium an aqueous solution containing an effective cooling rate reducing amount of a nonionic, water-soluble or water-dispersible substituted oxazoline polymer having recurring units of the formula ##STR4## where R is a substituent selected from the group consisting of a phenyl group or an alkyl group containing from 1 to 7 carbon atoms which may be halogen substituted, and n is an integer such as to provide said polymer with a molecular weight of from about 5000 to about 1,000,000, the substituent R in at least about 50 percent of said units in said polymer being alkyl containing from 1 to 3 carbon atoms.
Claim 6
Dependent Claim 157 words
In the process of quenching which is useful in the heat treatment of metals wherein a metal is heated to an elevated temperature and said heated metal is then quenched in a bath comprising a liquid quenching medium to effect desirable metallurgical changes in the metal, the improvement which comprises using as said quenching medium an aqueous solution containing an effective cooling rate reducing amount of a nonionic, water-soluble or water-dispersible substituted oxazoline polymer having recurring units of the formula ##STR4## where R is a substituent selected from the group consisting of a phenyl group or an alkyl group containing from 1 to 7 carbon atoms which may be halogen substituted, and n is an integer such as to provide said polymer with a molecular weight of from about 5000 to about 1,000,000, the substituent R in at least about 50 percent of said units in said polymer being alkyl containing from 1 to 3 carbon atoms.
Claim 7
Dependent Claim 49 words
A process according to claim 4 in which the concentration of said polymer in said quenching medium is from about 0.5% to about 5%, by weight, based on the total weight of the quenching medium, and said polymer has a molecular weight of from about 50,000 to about 500,000.
Claim 8
Dependent Claim 36 words
A process according to claim 5 in which the concentration of said polymer in said bath is from about 1.5% to 3% and said polymer has a molecular weight of from about 200,000 to about 500,000.
Claim 9
Dependent Claim 114 words
In a process of quenching which is useful in the heat treatment of metals wherein a metal is heated to an elevated temperature and said heated metal is then quenched in a bath comprising a liquid quenching medium to effect desirable metallurgical changes in the metal, the improvement which comprises using as said quenching medium an aqueous solution containing from about 0.5% to 5%, by weight, based on the total weight of the quenching medium, of a nonionic, water-soluble or water dispersible substituted oxazoline polymer having recurring units of the general formula ##STR5## where n is an integer such as to provide said polymer with a molecular weight of from about 50,000 to 500,000.
Claim 10
Dependent Claim 114 words
In a process of quenching which is useful in the heat treatment of metals wherein a metal is heated to an elevated temperature and said heated metal is then quenched in a bath comprising a liquid quenching medium to effect desirable metallurgical changes in the metal, the improvement which comprises using as said quenching medium an aqueous solution containing from about 0.5% to 5%, by weight, based on the total weight of the quenching medium, of a nonionic, water-soluble or water dispersible substituted oxazoline polymer having recurring units of the general formula ##STR5## where n is an integer such as to provide said polymer with a molecular weight of from about 50,000 to 500,000.
Claim 11
Dependent Claim 37 words
A process according to claim 7 in which the concentration of said polymer in said quenching medium is from about 1.5% to about 3%, and said polymer has a molecular weight of from about 200,000 to 500,000.

References Cited (Backward Citations)

US3220893A Cited
US3483141A Cited
US4087290A Cited
US4404044A Cited
US4381205A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-12-04 1988-06-04 1988-12-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-12-04 1992-06-04 1992-12-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-12-04 1996-06-04 1996-12-04 $7700.00 Window Closed / Lapsed

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