US4486519A
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US
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Bisazo compounds and electrophotographic photoconductors comprising the bisazo compounds
Assignee: Ricoh Co Ltd
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Filing: 1983-06-01
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Granted: 1984-12-04
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Expires: 2003-06-01
Abstract
Abstract A novel bisazo compound of the formula ##STR1## where n=2 or 3, and A is ##STR2## when n=2, and when n=3, A is the above (a), (b) or (c), and an electrophotographic photoconductor comprising, on an electroconductive support material, a photoconductive layer containing the above bisazo compound, which electrophotographic photoconductor exhibits relatively high photo-sensitivity and usefulness for electrophotographic copying.
Inventors
- 👤 Masaomi Sasaki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 22:15
CPC Classifications
C; C09; C09B; C09B35/00; C09B35/02; C09B35/039; C09B35/205; C09B35/215
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
188 words
A bisazo compound of the general formula: ##STR285## where n is an integer of 2 or 3, and when n=2, substituent A is selected from the group consisting of ##STR286## and when n=3, A is selected from the group consisting of the above substituents (a), (b) and (c), wherein R 1 is hydrogen, an alkyl group, an unsubstituted or substituted phenyl group; X is an unsubstituted or substituted cyclic hydrocarbon group, or an unsubstituted or substituted heterocyclic group; Y is an unsubstituted or substituted cyclic hydrocarbon group, an unsubstituted or substituted heterocyclic group, or ##STR287## (in which R 4 is an unsubstituted or substituted cyclic hydrocarbon group, an unsubstituted or substituted heterocyclic group, an unsubstituted or substituted styryl group; R 5 is hydrogen, an alkyl group, an unsubstituted or substituted phenyl group; or R 4 and R 5 can form a ring in combination with carbon atoms bonded to R 4 and R 5 ); R 2 is an unsubstituted or substituted hydrocarbon group; R 3 is an alkyl group or a carboxyl group or an ester thereof; and Ar is an unsubstituted or substituted cyclic hydrocarbon group.
Claim 2
Dependent Claim
188 words
A bisazo compound of the general formula: ##STR285## where n is an integer of 2 or 3, and when n=2, substituent A is selected from the group consisting of ##STR286## and when n=3, A is selected from the group consisting of the above substituents (a), (b) and (c), wherein R 1 is hydrogen, an alkyl group, an unsubstituted or substituted phenyl group; X is an unsubstituted or substituted cyclic hydrocarbon group, or an unsubstituted or substituted heterocyclic group; Y is an unsubstituted or substituted cyclic hydrocarbon group, an unsubstituted or substituted heterocyclic group, or ##STR287## (in which R 4 is an unsubstituted or substituted cyclic hydrocarbon group, an unsubstituted or substituted heterocyclic group, an unsubstituted or substituted styryl group; R 5 is hydrogen, an alkyl group, an unsubstituted or substituted phenyl group; or R 4 and R 5 can form a ring in combination with carbon atoms bonded to R 4 and R 5 ); R 2 is an unsubstituted or substituted hydrocarbon group; R 3 is an alkyl group or a carboxyl group or an ester thereof; and Ar is an unsubstituted or substituted cyclic hydrocarbon group.
Claim 3
Dependent Claim
203 words
An electrophotographic photoconductor comprising an electroconductive support material having thereon a photoconductive layer containing a bisazo compound of the general formula: ##STR288## where n is an integer of 2 or 3, and when n=2, substituent A is selected from the group consisting of ##STR289## and when n=3, A is selected from the group consisting of the above substituents (a), (b) and (c), wherein R 1 is hydrogen, an alkyl group, an unsubstituted or substituted phenyl group; X is an unsubstituted or substituted cyclic hydrocarbon group, or an unsubstituted or substituted heterocyclic group; Y is an unsubstituted or substituted cyclic hydrocarbon group, an unsubstituted or substituted heterocyclic group, or ##STR290## (in which R 4 is an unsubstituted or substituted cyclic hydrocarbon group, an unsubstituted or substituted heterocyclic group, an unsubstituted or substituted styryl group; R 5 is hydrogen, an alkyl group, an unsubstituted or substituted phenyl group; or R 4 and R 5 can form a ring in combination with carbon atoms bonded to R 4 and R 5 ); R 2 is an unsubstituted or substituted hydrocarbon group; R 3 is an alkyl group or a carboxyl group or an ester group thereof; and Ar is an unsubstituted or substituted cyclic hydrocarbon group.
Claim 4
Dependent Claim
203 words
An electrophotographic photoconductor comprising an electroconductive support material having thereon a photoconductive layer containing a bisazo compound of the general formula: ##STR288## where n is an integer of 2 or 3, and when n=2, substituent A is selected from the group consisting of ##STR289## and when n=3, A is selected from the group consisting of the above substituents (a), (b) and (c), wherein R 1 is hydrogen, an alkyl group, an unsubstituted or substituted phenyl group; X is an unsubstituted or substituted cyclic hydrocarbon group, or an unsubstituted or substituted heterocyclic group; Y is an unsubstituted or substituted cyclic hydrocarbon group, an unsubstituted or substituted heterocyclic group, or ##STR290## (in which R 4 is an unsubstituted or substituted cyclic hydrocarbon group, an unsubstituted or substituted heterocyclic group, an unsubstituted or substituted styryl group; R 5 is hydrogen, an alkyl group, an unsubstituted or substituted phenyl group; or R 4 and R 5 can form a ring in combination with carbon atoms bonded to R 4 and R 5 ); R 2 is an unsubstituted or substituted hydrocarbon group; R 3 is an alkyl group or a carboxyl group or an ester group thereof; and Ar is an unsubstituted or substituted cyclic hydrocarbon group.
Claim 5
Dependent Claim
48 words
An electrophotographic photoconductor as claimed in claim 2, wherein said photoconductive layer further comprises a binder agent in which said bisazo compound is dispersed, and the amount of said bisazo compound is in the range of 30 to 70 percent of the total weight of said photoconductive layer.
Claim 6
Dependent Claim
23 words
An electrophotographic photoconductor as claimed in claim 2, wherein said photoconductive layer further comprises a charge transporting medium containing a charge transporting material.
Claim 7
Dependent Claim
47 words
An electrophotographic photoconductor as claimed in claim 2, wherein said photoconductive layer comprises a charge carrier producing layer comprising said bisazo compound and, formed on said electroconductive support material, and a charge transporting layer formed on said charge carrier producing layer and, containing a charge transporting material.
Claim 8
Dependent Claim
29 words
An electrophotographic photoconductor as claimed in claims 3 and 4, wherein the thickness of said photoconductive layer is in the range of about 3 μm to about 50 μm.
Claim 9
Dependent Claim
49 words
An electrophotographic photoconductor as claimed in claim 5, wherein the thickness of said charge carrier producing layer is in the range of about 0.05 μm to about 5 μm, and the thickness of said charge transporting layer is in the range of about 3 μm to about 50 μm.
Claim 10
Dependent Claim
55 words
An electrophotographic photoconductor as claimed in claim 4, wherein the amount of said bisazo compound is in the range of about 1 wt.% to about 50 wt.%, and the amount of said charge transporting material is in the range of about 10 wt.% to about 95 wt.% of the total weight of said photoconductive layer.
Claim 11
Dependent Claim
41 words
An electrophotographic photoconductor as claimed in claim 5, wherein the amount of said charge transporting material in said charge transporting layer is in the range of about 10 wt.% to about 95 wt.% of the total weight of said photoconductive layer.
Claim 12
Dependent Claim
14 words
A bisazo compound as claimed in claim 1 in which A is substituent (a).
Claim 13
Dependent Claim
17 words
A bisazo compound as claimed in claim 1 in which A is substituent (b) or substituent (c).
Claim 14
Dependent Claim
14 words
A bisazo compound as claimed in claim 1 in which A is substituent (d).
Claim 15
Dependent Claim
14 words
An electrophotographic photoconductor as claimed in claim 2 in which A is substituent (a).
Claim 16
Dependent Claim
17 words
An electrophotographic photoconductor as claimed in claim 2 in which A is substituent (b) or substituent (c).
Claim 17
Dependent Claim
14 words
An electrophotographic photoconductor as claimed in claim 2 in which A is substituent (d).
References Cited (Backward Citations)
US4314015A
Cited
US4415641A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-12-04 | 1988-06-04 | 1988-12-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-12-04 | 1992-06-04 | 1992-12-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-12-04 | 1996-06-04 | 1996-12-04 | $7700.00 | Window Closed / Lapsed |