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US4508598A Expired / Lapsed US ⏱️ 0.0 years remaining

Gas sensor and method of using same

Assignee: Giner Electrochemical Systems LLC
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Filing: 1982-09-30
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Granted: 1985-04-02
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Expires: 2002-09-30
📄 Original PDF 🌐 Google Patents

Abstract

Abstract An electrochemical sensor capable of determining the partial pressure of various gases (e.g., CO, CO 2 , H 2 S, alcohol vapors, hydrocarbons, NO x , etc.) and, optionally, substantially concurrently, but independently, oxygen content in gases and liquids. The sensor measures the amount of chemisorbent species formed either electrochemically by partial reduction (such as "Reduced-CO 2 " in the case of CO 2 ) or partial oxidation (in the case of alcohol) or non-electrochemically via specific adsorption (in the case of CO and hydrocarbons) on platinum or other metals. The charge required to oxidize this chemisorbed species is proportional to the amount of adsorbate on the electrode surface which is made a reproducible and reliable function of the partial pressure of the gas to be measured. By the proper selection of the sensor construction and electrical parameters, high sensitivity, fast response time, and high selectivity can be obtained.

Inventors

  • 👤 Jose D. Giner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 03:44
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/416; G01N27/49

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 39 words
Method of quantitatively determining gas concentration in a fluid by (A) transforming gas from the fluid onto an electrode surface in contact with electrolyte as an adsorbed species; and (B) electrochemically determining quantitatively the amount of said adsorbed species.
Claim 2
Dependent Claim 39 words
Method of quantitatively determining gas concentration in a fluid by (A) transforming gas from the fluid onto an electrode surface in contact with electrolyte as an adsorbed species; and (B) electrochemically determining quantitatively the amount of said adsorbed species.
Claim 3
Dependent Claim 15 words
The method of claim 1 wherein the electrode includes a platinum group metal or gold.
Claim 4
Dependent Claim 10 words
The method of claim 2 including an electrode cleaning step.
Claim 5
Dependent Claim 22 words
The method of claim 2 wherein steps (A) and (B) are potentiostatically controlled and the current flowing during step (B) is integrated.
Claim 6
Dependent Claim 20 words
The method of claim 4 including step (C) for substantially concurrently and independently measuring the oxygen content of the fluid.
Claim 7
Dependent Claim 24 words
The method of claim 1 wherein steps (A) and (B) are potentiostatically and galvanostatically controlled, respectively, and the current of step (B) is integrated.
Claim 8
Dependent Claim 21 words
The method of claim 6 including a step (C) for substantially concurrently and independently measuring the oxygen content of the fluid.
Claim 9
Dependent Claim 13 words
The method of claim 2 wherein steps (A) and (B) are galvanostatically controlled.
Claim 10
Dependent Claim 18 words
The method of claim 8 including a step (C) for substantially concurrently and independently measuring the oxygen content.
Claim 11
Dependent Claim 36 words
The method of claim 2 wherein step (A) occurs at controlled potential and step (B) occurs at open circuit potential, and the open circuit potential is measured and related to amount of the adsorbed species formed.
Claim 12
Dependent Claim 35 words
The method of claim 2 wherein step (A) occurs at constant current and step (B) occurs at open circuit potential, and the open circuit potential is measured and related to amount of adsorbed species formed.
Claim 13
Dependent Claim 29 words
Method of claim 1 wherein the amount of gas transformed into the adsorbed species is determined by the diffusion of gas from the fluid bulk to the electrode surface.
Claim 14
Dependent Claim 18 words
The method of claim 12 wherein the diffusion is controlled by using an adsorption step of predetermined duration.
Claim 15
Dependent Claim 11 words
The method of claim 1 wherein said gas is carbon dioxide.
Claim 16
Dependent Claim 11 words
The method of claim 1 wherein said gas is carbon monoxide.
Claim 17
Dependent Claim 11 words
The method of claim 1 wherein said gas is hydrogen sulfide.
Claim 18
Dependent Claim 23 words
The method of claim 12 wherein said diffusion of gas from the fluid bulk to the electrode surface is through a hydrophobic membrane.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-04-01 1988-10-01 1989-04-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-04-01 1992-10-01 1993-04-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-04-01 1996-10-01 1997-04-02 $7700.00 Window Closed / Lapsed

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