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US4522959A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic compositions in powder form

Assignee: Bayer AG
•
Filing: 1984-03-28
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Granted: 1985-06-11
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Expires: 2004-03-28
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Abstract

Abstract A process for the production of a pulverulent mixture consisting of (A) from 60 to 99 parts by weight of a brittle copolymer consisting of acrylonitrile and styrene, α-methylstyrene, methyl methacrylate or mixtures thereof, and (B) from 1 to 40 parts by weight of a flexible rubber-elastic polymer, by coagulating, in a first stage, a latex of (A) or a mixture of a latex of (A) and a part of a latex of (B), adding, in a second stage, the latex of (B) or the remaining part of the latex of (B), so that the desired quantity ratio of (A) to (B) is attained, and, in a third stage, separating the precipitated mixture of (A) and (B) from the aqueous phase, and drying it.

Inventors

  • 👤 Christian Lindner
  • 👤 Karl-Heinz Ott
  • 👤 Hans-Eberhard Braese

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 23:08
CPC Classifications
C; C08; C08L; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/12; C08J; C08J3/00; C08J3/005; C08L33/00; C08L33/04; C08L33/06; C08L33/10; C08L33/12; C08L21/00

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 244 words
In an improved process for the production of a pulverulent mixture consisting of (A) from 60 to 99 parts, by weight of the pulverulent mixture, of a brittle copolymer consisting of from 35 to 5%, by weight of brittle copolymer, of acrylonitrile and from 95 to 65%, by weight of brittle copolymer, of a monomer of styrene, α-methylstyrene, methyl methacrylate or mixtures thereof; and (B) from 1 to 40 parts, by weight of the pulverulent mixture, of a rubber-elastic polymer of (1) a flexible rubber-elastic polymer having a glass transition temperature less than 20° C., (2) a graft polymer, the rubber basis of which has a glass transition temperature of less than 20° C., or mixtures of (1) and (2), the improvement consisiting of; in a first stage, a latex of (A) or a mixture of a latex of (A) and a part of a latex of (B) are coagulated by the addition of a coagulant at a temperature of from 20° to 100° C., in a second stage, the latex of (B) or the remaining part of the latex of (B) is added and a sufficient amount of additional coagulent, water or mixtures thereof, is added during the second stage or after the second stage, but before a third stage to obtain a solids to water weight ratio of from 1:3 to 1:15, and in a third stage, the precipitated mixture of (A) and (B) is separated from the aqueous phase and dried.
Claim 2
Dependent Claim 244 words
In an improved process for the production of a pulverulent mixture consisting of (A) from 60 to 99 parts, by weight of the pulverulent mixture, of a brittle copolymer consisting of from 35 to 5%, by weight of brittle copolymer, of acrylonitrile and from 95 to 65%, by weight of brittle copolymer, of a monomer of styrene, α-methylstyrene, methyl methacrylate or mixtures thereof; and (B) from 1 to 40 parts, by weight of the pulverulent mixture, of a rubber-elastic polymer of (1) a flexible rubber-elastic polymer having a glass transition temperature less than 20° C., (2) a graft polymer, the rubber basis of which has a glass transition temperature of less than 20° C., or mixtures of (1) and (2), the improvement consisiting of; in a first stage, a latex of (A) or a mixture of a latex of (A) and a part of a latex of (B) are coagulated by the addition of a coagulant at a temperature of from 20° to 100° C., in a second stage, the latex of (B) or the remaining part of the latex of (B) is added and a sufficient amount of additional coagulent, water or mixtures thereof, is added during the second stage or after the second stage, but before a third stage to obtain a solids to water weight ratio of from 1:3 to 1:15, and in a third stage, the precipitated mixture of (A) and (B) is separated from the aqueous phase and dried.
Claim 3
Dependent Claim 57 words
A process according to claim 1, wherein (B) consists of B1: the graft polymer of styrene, acrylonitrile, methyl methacrylate or mixtures thereof on a diene rubber, containing greater than or equal to 30% rubber, and B2: the rubber which is a diene homopolymer or diene copolymer, wherein the latex of B2 is added in the second stage.

References Cited (Backward Citations)

US2755270A Cited
US4302378A Cited
US4376843A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-06-10 1988-12-10 1989-06-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-06-10 1992-12-10 1993-06-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-06-10 1996-12-10 1997-06-11 $7700.00 Window Closed / Lapsed

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