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US4524017A Expired / Lapsed US ⏱️ 0.0 years remaining

Derivatives of norbornanes having hydrocarbon side chains and perfume compositions containing the same

Assignee: Eneos Corp
•
Filing: 1982-02-24
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Granted: 1985-06-18
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Expires: 2002-02-24
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Abstract

Abstract Norbornane derivatives having hydrocarbon side chains, the processes for preparing the same and perfume compositions containing the same. The norbornane derivatives are represented by the following general formula (I) <IMAGE> (I) wherein C2 is an ethyl group, an ethylidene group or a vinyl group each connected to 5 or 6 position of the norbornane ring, each of R1 and R2 is a hydrogen atom or a methyl group, and R3 is a formyl group or a group represented by the following general formula (II) <IMAGE> (II) wherein R4 is a methyl group, an ethyl group, a n-propyl group or an isopropyl group, and X is a carbon atom of the norbornane ring. The above norbornane derivatives give a wide variety of woody fragrances and are useful as components for various perfume products.

Inventors

  • 👤 Yoshiharu Inoue
  • 👤 Fumio Tanimoto
  • 👤 Hisao Kitano

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 15:27
CPC Classifications
C; C11; C11B; C11B9/00; C11B9/0042; C11B9/0046; C07; C07C; C07C29/00; C07C29/132; C07C29/136; C07C29/143; C07C29/145; C07C29/17; C07C29/172; C07C29/175; C07C31/00; C07C31/13; C07C31/137; C07C33/00; C07C33/05; C07C33/12; C07C45/00; C07C45/49; C07C45/50; C07C45/56; C07C45/57; C07C45/58; C07C45/61; C07C45/62; C07C47/00; C07C47/28; C07C47/34; C07C47/347; C07C47/38; C07C47/45

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 129 words
A norbornane derivative having a hydrocarbon side chain which is represented by the following general formula (I) ##STR19## wherein C 2 is an ethylidene group or a vinyl group connected to the 5 or 6 position of the norbornane ring, the dashed line connected to C 2 is a single bond when C 2 is a vinyl group and a double bond when C 2 is an ethylidene group, each of R 1 and R 2 is a hydrogen atom or a methyl group, and R 3 is a formyl group or a group represented by the following general formula (II) ##STR20## wherein R 4 is a methyl group, an ethyl group, a n-propyl group or an isopropyl group and X is a carbon atom of the norbornane ring.
Claim 2
Dependent Claim 129 words
A norbornane derivative having a hydrocarbon side chain which is represented by the following general formula (I) ##STR19## wherein C 2 is an ethylidene group or a vinyl group connected to the 5 or 6 position of the norbornane ring, the dashed line connected to C 2 is a single bond when C 2 is a vinyl group and a double bond when C 2 is an ethylidene group, each of R 1 and R 2 is a hydrogen atom or a methyl group, and R 3 is a formyl group or a group represented by the following general formula (II) ##STR20## wherein R 4 is a methyl group, an ethyl group, a n-propyl group or an isopropyl group and X is a carbon atom of the norbornane ring.
Claim 3
Dependent Claim 25 words
A norbornane derivative of claim 1 selected from the group consisting of 4-(5'- or 6'-ethylidene- or 4-(5'- or 6'-vinylnorbornan-2'-yl)-3-methyl-3-buten-2-ol, and their 3'-methyl or 3',3'-dimethyl derivatives.
Claim 4
Dependent Claim 25 words
A norbornane derivative of claim 1 selected from the group consisting of 1-(5'- or 6'-ethylidene- or 1-(5'- or 6'-vinyl-norbornan-2'-yl)-2-methyl-1-penten-3-ol, and their 3'-methyl or 3',3'-dimethyl derivatives.
Claim 5
Dependent Claim 25 words
A norbornane derivative of claim 1 selected from the group consisting of 1-(5'- or 6'-ethylidene- or 1-(5'- or 6'-vinyl-norbornan-2'-yl)-2,4-dimethyl-1-penten-3-ol, and their 3'-methyl or 3',3'-dimethyl derivatives.
Claim 6
Dependent Claim 25 words
A norbornane derivative of claim 1 selected from the group consisting of 1-(5'- or 6'-ethylidene- or 1-(5'- or 6'-vinyl-norbornan-2'-yl)-2-methyl-1-hexen-3-ol, and their 3'-methyl or 3',3'-dimethyl derivatives.
Claim 7
Dependent Claim 125 words
A perfume composition containing a compound represented by the following general formula (I) ##STR21## wherein C 2 is an ethylidene group or a vinyl group connected to the 5 or 6 position of the norbornane ring, the dashed line connected to C 2 is a single bond when C 2 is a vinyl group and a double bond when C 2 is an ethylidene group, each of R 1 and R 2 is a hydrogen atom or a methyl group, and R 3 is a formyl group or a group represented by the following general formula (II) ##STR22## wherein R 4 is a methyl group, an ethyl group, a n-propyl group or an isopropyl group and X is a carbon atom of the norbornane ring.
Claim 8
Dependent Claim 125 words
A perfume composition containing a compound represented by the following general formula (I) ##STR21## wherein C 2 is an ethylidene group or a vinyl group connected to the 5 or 6 position of the norbornane ring, the dashed line connected to C 2 is a single bond when C 2 is a vinyl group and a double bond when C 2 is an ethylidene group, each of R 1 and R 2 is a hydrogen atom or a methyl group, and R 3 is a formyl group or a group represented by the following general formula (II) ##STR22## wherein R 4 is a methyl group, an ethyl group, a n-propyl group or an isopropyl group and X is a carbon atom of the norbornane ring.

References Cited (Backward Citations)

US3860635A Cited
US4128509A Cited
US4229600A Cited
US4223168A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-06-17 1988-12-17 1989-06-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-06-17 1992-12-17 1993-06-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-06-17 1996-12-17 1997-06-18 $7700.00 Window Closed / Lapsed

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