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US4529563A Expired / Lapsed US ⏱️ 0.0 years remaining

Vaporous solvent treatment of thermoplastic substrates

Assignee: FAIS ROBERT G
•
Filing: 1983-11-21
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Granted: 1985-07-16
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Expires: 2003-11-21
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Abstract

Abstract Disclosed is a method for treating a thermoplastic substrate for improving the surface thereof without significant loss of physical properties. Such method comprises: (a) determining the solubility parameter, δ T , of said thermoplastic substrate and the surface energy, γ T , of said thermoplastic substrate; (b) determining a set of destructive solvents which are detrimental to a physical property of said thermoplastic substrate; (c) determining a set of non-destructive solvents which are not detrimental to the physical properties of said thermoplastic substrate; (d) determining the solubility parameters for said set of destructive solvent, δ D , and for said set of non-destructive solvent, δ N ; and the surface tension for said set of destructive solvent, γ D , and for said non-destructive solvent, γ N ; (e) selecting a subset of said destructive solvents which possess solubility parameters, δ D , close to the solubility parameter of said thermoplastic substrate, δ T ; (f) selecting sub-combinations of said subset of destructive solvents (e), and said subset (c) of non-destructive solvents which form azeotropic mixtures, at least one of said solvents possessing a surface tension which is less than the surface energy of said thermoplastic substrate; and (g) treating said surface with at least one of said select subcombinations in the vapor phase.

Inventors

  • 👤 Vincent D. McGinniss

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 12:16
CPC Classifications
B; B29; B29C; B29C71/00; B29C71/0009; C; C08; C08J; C08J7/00; C08J7/02; B29C59/00; B29C73/00; B29C73/02

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 217 words
Method for treating the surface of a thermoplastic substrate for improving said surface without significant loss of physical properties thereof which comprises: (a) determining the solubility parameter, δ T , of said thermoplastic substrate and the surface energy, δ T , of said thermoplastic substrate; (b) determining a set of destructive solvents which are detrimental to a physical property of said thermoplastic substrate; (c) determining a set of non-destructive solvents which are not detrimental to the physical properties of said thermoplastic substrate; (d) determining the solubility parameters for said set of destructive solvent, δ D , and for said set of non-destructive solvent, δ N ; and the surface tension for said set of destructive solvent, δ D , and for said non-destructive solvent, δ N ; (e) selecting a subset of said destructive solvents which possess solubility parameters, δ D , close to the solubility parameter of said thermoplastic substrate, δ T ; (f) selecting sub-combinations of said subset of destructive solvents (e), and said set (c) of non-destructive solvents which form azeotropic mixtures, at least one of said solvents possessing a surface tension which is less than the surface energy of said thermoplastic substrate; and (g) treating said surface with an azeotropic mixture of at least one of said select sub-combinations in the vapor phase.
Claim 2
Dependent Claim 217 words
Method for treating the surface of a thermoplastic substrate for improving said surface without significant loss of physical properties thereof which comprises: (a) determining the solubility parameter, δ T , of said thermoplastic substrate and the surface energy, δ T , of said thermoplastic substrate; (b) determining a set of destructive solvents which are detrimental to a physical property of said thermoplastic substrate; (c) determining a set of non-destructive solvents which are not detrimental to the physical properties of said thermoplastic substrate; (d) determining the solubility parameters for said set of destructive solvent, δ D , and for said set of non-destructive solvent, δ N ; and the surface tension for said set of destructive solvent, δ D , and for said non-destructive solvent, δ N ; (e) selecting a subset of said destructive solvents which possess solubility parameters, δ D , close to the solubility parameter of said thermoplastic substrate, δ T ; (f) selecting sub-combinations of said subset of destructive solvents (e), and said set (c) of non-destructive solvents which form azeotropic mixtures, at least one of said solvents possessing a surface tension which is less than the surface energy of said thermoplastic substrate; and (g) treating said surface with an azeotropic mixture of at least one of said select sub-combinations in the vapor phase.
Claim 3
Dependent Claim 31 words
The method of claim 1 wherein said subset of said destructive solvents (e) possesses a surface tension, γ D , which is less than the surface energy of said thermoplastic substrate.
Claim 4
Dependent Claim 28 words
The method of claim 1 wherein is selected a subset of said non-destructive solvents which possesses a surface tension less than the surface energy of said thermoplastic substrate.
Claim 5
Dependent Claim 34 words
The method of claim 3 wherein said subset of said destructive solvents and said subset of said non-destructive solvents both possess surface tensions which are less than the surface energy of said thermoplastic substrate.
Claim 6
Dependent Claim 24 words
The method of claim 1 wherein said set of non-destructive solvents also possess solubility parameters close to the solubility parameter of said thermoplastic substrate.
Claim 7
Dependent Claim 27 words
The method of claim 1 wherein said sub-combinations of step (g) are selected so that the volume of said destructive solvent in said azeotropic mixtures is minimized.
Claim 8
Dependent Claim 26 words
The method of claim 1 wherein said sub-combination selected in step (g) are azeotropic mixtures in which the molecular volume of said destructive solvents are maximized.
Claim 9
Dependent Claim 27 words
The method of claim 1 wherein said treating of step (g) is done at a temperature of less than the glass transition temperature of said thermoplastic substrate.

References Cited (Backward Citations)

US2126714A Cited
US2294479A Cited
US3020661A Cited
US3524795A Cited
US3473960A Cited
US3546331A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-07-15 1989-01-14 1989-07-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-07-15 1993-01-14 1993-07-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-07-15 1997-01-14 1997-07-16 $7700.00 Window Closed / Lapsed

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