US4532118A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for removal of hydrogen sulfide from gases
Assignee: Kimura Chemical Plants Co Ltd
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Filing: 1984-03-29
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Granted: 1985-07-30
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Expires: 2004-03-29
Abstract
Abstract A process for the removal of hydrogen sulfide from a gas which comprises contacting the gas with a solution comprising ferric ions (Fe 3+ ) and ferrous ions (Fe 2+ ). The solution further comprises ethylenediamine tetraacetic acid (EDTA) or a salt thereof and triethanolamine (TEA) or a salt thereof. The solution has a pH in the range of from 7 to 9 and a mole ratio of ferric ion to total iron ions in the range of from 0.60 to 0.90 as measured just after the hydrogen sulfide contacts the solution. The process is characterized by high removal of hydrogen sulfide, prevention of side reactions, and the inhibition of the formation of intermediate colloidal sulfur.
Inventors
- 👤 Tadaaki Tajiri
- 👤 Hitoshi Nishizawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 23:08
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/52; C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/05
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
89 words
A process for the removal of hydrogen sulfide from a gas comprising contacting said gas with a solution comprising ferric ions and ferrous ions, said solution further comprising ethylenediamine tetraacetic acid or a salt thereof and triethanolamine or a salt thereof, said solution having a pH in the range of from 7 to 9 and a mole ratio of ferric ion to total iron ions in the range of from 0.60 to 0.90, said mole ratio of ferric ion being measured just after said hydrogen sulfide contacts said solution.
Claim 2
Dependent Claim
89 words
A process for the removal of hydrogen sulfide from a gas comprising contacting said gas with a solution comprising ferric ions and ferrous ions, said solution further comprising ethylenediamine tetraacetic acid or a salt thereof and triethanolamine or a salt thereof, said solution having a pH in the range of from 7 to 9 and a mole ratio of ferric ion to total iron ions in the range of from 0.60 to 0.90, said mole ratio of ferric ion being measured just after said hydrogen sulfide contacts said solution.
Claim 3
Dependent Claim
17 words
The process of claim 1 wherein said pH is in the range of from 7.5 to 8.5.
Claim 4
Dependent Claim
27 words
The process of claim 1 wherein said gas is contacted with said solution in a packed tower, a plate tower, a spray tower or a combination thereof.
Claim 5
Dependent Claim
18 words
The process of claim 1 wherein said ferric ions and ferrous ions are initially supplied as ferrous sulfate.
Claim 6
Dependent Claim
16 words
The process of claim 1 wherein ferrous sulfate is added to the solution during said process.
Claim 7
Dependent Claim
23 words
The process of claim 1 wherein said triethanolamine is used in at least a 1.5 molar ratio excess relative to ethylenediamine tetraacetic acid.
Claim 8
Dependent Claim
35 words
The process of claim 1 wherein said ethylenediamine tetraacetic acid is used in an amount sufficient so that said ethylenediamine tetraacetic acid chelates at least 60 mole % of all chelatable iron atoms in solution.
Claim 9
Dependent Claim
22 words
The process of claim 1 wherein two to four moles of ferric ion are used for every one mole of hydrogen sulfide.
Claim 10
Dependent Claim
25 words
The process of claim 1 wherein said mole ratio of ferric ion to total iron ions is in the range of from 0.70 to 0.90.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-07-29 | 1989-01-28 | 1989-07-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-07-29 | 1993-01-28 | 1993-07-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-07-29 | 1997-01-28 | 1997-07-30 | $7700.00 | Window Closed / Lapsed |