Sulfated addition products of selected unsaturated dicarboxylic acids and poly(oxyalkylated) alcohols as anionic surfactants

Claim 2

A surfactant composition made by the process comprising: a. forming a carboxylic acid group-containing addition product by reacting, in the presence of a peroxy-type free-radical initiator, an ethylenically unsaturated dicarboxylic acid selected from the group consisting of maleic acid and fumaric acid and mixtures thereof, with at least one poly(oxyalkylated) alcohol having the formula: ##STR3## wherein R is a hydrocarbon-containing radical having an average of from about 6 to about 18 carbon atoms; R 1 , R 2 , and R 3 are individually selected from hydrogen and methyl with the proviso that R 2 is different than R 1 and R 3 ; x is an integer having a value from 1 to about 25; y is an integer having a value from about 1 to about 25; and z is an integer from about 0 to about 25; in the said weight ratio of said poly(oxyalkylated) from about 95:5 to about 40:60; and b. sulfating said addition product with a sufficient amount of a sulfating agent to convert at least a major portion of said terminal hydroxyl groups to sulfonate groups.

Claim 3

The surfactant composition of claim 1 wherein R is a linear, aliphatic hydrocarbon radical having an average of from about 8 to about 14 carbon atoms.

Claim 4

The surfactant composition of claim 1 wherein x is an integer having a value from about 2 to about 12.

Claim 5

The surfactant composition of claim 1 wherein y is an integer having a value from about 2 to about 15.

Claim 6

The surfactant composition of claim 1 wherein z is an integer having a value from about 5 to : about 20.

Claim 7

The surfactant composition of claim 1 wherein the weight ratio of said poly(oxyalkylated) alcohol to said dicarboxylic acid is from about 90:10 to about 60:40.

Claim 8

The surfactant composition of claim 1 wherein said addition product is sulfated with a sufficient amount of a sulfating agent to convert at least substantially all of said terminal hydroxyl sulfonate groups.

Claim 9

The surfactant composition of claim 1 wherein said sulfating agent is sulfamic acid.

Claim 10

The surfactant composition of claim 1 wherein said addition product is neutralized prior to sulfating step (b).

Claim 11

A surfactant composition made by the process comprising: a. forming a carboxylic acid group-containing addition product by reacting, in the presence of a peroxy-type free-radical initiator, an ethylenically unsaturated dicarboxylic acid selected from the group consisting of maleic acid and fumaric acid and mixtures thereof, with at least one poly(oxyalkylated) alcohol having the formula: ##STR4## wherein R is a hydrocarbon-containing radical having an average of from about 6 to about 18 carbon atoms; R 1 , R 2 , and R 3 are individually selected from hydrogen and methyl with the proviso that R 2 is different than R 1 and R 3 ; x is an integer having a value from 1 to about 25; y is an integer having a value from about 1 to about 25; and z is an integer weight ratio of said poly(oxyalkylated) alcohol to said dicarboxylic acid being from about 95:5 to about 40:60; b. sulfating said addition product with a sufficient amount of a sulfating agent to convert at least a major portion of terminal hydroxyl groups to sulfate groups; and c. neutralizing said sulfated addition product with a sufficient amount of a neutralizing agent to convert at least a major portion of the total of said carboxylic acid groups and said sulfate groups to salt groups.

Claim 12

A surfactant composition made by the process comprising: a. forming a carboxylic acid group-containing addition product by reacting, in the presence of a peroxy-type free-radical initiator, an ethylenically unsaturated dicarboxylic acid selected from the group consisting of maleic acid and fumaric acid and mixtures thereof, with at least one poly(oxyalkylated) alcohol having the formula: ##STR4## wherein R is a hydrocarbon-containing radical having an average of from about 6 to about 18 carbon atoms; R 1 , R 2 , and R 3 are individually selected from hydrogen and methyl with the proviso that R 2 is different than R 1 and R 3 ; x is an integer having a value from 1 to about 25; y is an integer having a value from about 1 to about 25; and z is an integer weight ratio of said poly(oxyalkylated) alcohol to said dicarboxylic acid being from about 95:5 to about 40:60; b. sulfating said addition product with a sufficient amount of a sulfating agent to convert at least a major portion of terminal hydroxyl groups to sulfate groups; and c. neutralizing said sulfated addition product with a sufficient amount of a neutralizing agent to convert at least a major portion of the total of said carboxylic acid groups and said sulfate groups to salt groups.

Claim 13

The surfactant composition of claim 10 wherein R is a linear, aliphatic hydrocarbon radical having an average of from about 8 to about 14 carbon atoms.

Claim 14

The surfactant composition of claim 10 wherein x is an integer having a value from about 2 to about 12.

Claim 15

The surfactant composition of claim 10 wherein y is an integer having a value from about 2 to about 15.

Claim 16

The surfactant composition of claim 10 wherein z is an integer having a value from about 5 to about 20.

Claim 17

The surfactant composition of claim 10 wherein the weight ratio of said poly(oxyalkylated) alcohol to said dicarboxylic acid is from about 90:10 to about 60:40.

Claim 18

The surfactant composition of claim 10 wherein said addition product is neutralized with a sufficient amount of a neutralization agent to convert substantially all of the total of said carboxylic acid groups and said sulfate groups to salt groups.

Claim 19

An aqueous solution comprising water and at least about 10% by weight of an alkali metal hyroxide and an effective surface active amount of the surfactant of claim 1.

Claim 20

An aqueous solution comprising water and at least about 10% by weight of an alkali metal hydroxide and an effective surface active amount of the surfactant of claim 10.