US4542114A — Process for the recovery and recycle of effluent …

Claim 1

Independent Claim 321 words

A process wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by combustion in a combustion zone with a mixture of commercially pure oxygen diluted to a concentration of 24-30 mole percent with carbon dioxide is treated to provide a carbon dioxide-rich recycle gas stream, comprising the steps of: (a) introducing the effluent flue gas into a carbon monoxide combustion stage wherein essentially all of the carbon monoxide content of the gas is converted to carbon dioxide by combustion with oxygen gas; (b) reducing the temperature of the resulting combusted effluent gas of step (a) by indirect heat exchange in a waste heat boiler and recovering the waste heat from said gas; (c) direct cooling and quenching the effluent gas by the introduction of a water stream into the gas with the attendant condensation of water of combustion and the entrainment of particulates into the water stream with subsequent removal of the stream from the gas and without significant adsorption of sulfur dioxide from the gas; (d) compressing the effluent gas to approximately the inlet pressure of the combustion zone; (e) separating the effluent gas into a carbon dioxide-rich recycle gas stream which constitutes 61-80 percent of the effluent stream and a remaining net gas stream which comprises the balance of the effluent stream; (f) recycling the carbon dioxide-rich recycle gas stream to the combustion zone as the diluent for oxygen fed to the zone for combustion; (g) compressing the net gas stream to a further elevated pressure; (h) aftercooling the compressed net gas stream with the attendant removal of condensed water; (i) drying the net gas stream to remove essentially any residual moisture, and (j) distilling the net gas stream to recover a gaseous overhead stream of oxygen and carbon dioxide, a liquid carbon dioxide stream formed by the condensed reflux of the distillation and a liquid bottom stream containing oxides of sulfur and nitrogen.

Claim 2

Dependent Claim 321 words

A process wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by combustion in a combustion zone with a mixture of commercially pure oxygen diluted to a concentration of 24-30 mole percent with carbon dioxide is treated to provide a carbon dioxide-rich recycle gas stream, comprising the steps of: (a) introducing the effluent flue gas into a carbon monoxide combustion stage wherein essentially all of the carbon monoxide content of the gas is converted to carbon dioxide by combustion with oxygen gas; (b) reducing the temperature of the resulting combusted effluent gas of step (a) by indirect heat exchange in a waste heat boiler and recovering the waste heat from said gas; (c) direct cooling and quenching the effluent gas by the introduction of a water stream into the gas with the attendant condensation of water of combustion and the entrainment of particulates into the water stream with subsequent removal of the stream from the gas and without significant adsorption of sulfur dioxide from the gas; (d) compressing the effluent gas to approximately the inlet pressure of the combustion zone; (e) separating the effluent gas into a carbon dioxide-rich recycle gas stream which constitutes 61-80 percent of the effluent stream and a remaining net gas stream which comprises the balance of the effluent stream; (f) recycling the carbon dioxide-rich recycle gas stream to the combustion zone as the diluent for oxygen fed to the zone for combustion; (g) compressing the net gas stream to a further elevated pressure; (h) aftercooling the compressed net gas stream with the attendant removal of condensed water; (i) drying the net gas stream to remove essentially any residual moisture, and (j) distilling the net gas stream to recover a gaseous overhead stream of oxygen and carbon dioxide, a liquid carbon dioxide stream formed by the condensed reflux of the distillation and a liquid bottom stream containing oxides of sulfur and nitrogen.

Claim 3

Dependent Claim 30 words

The process of claim 1 wherein a portion of the carbon dioxide recycle stream is removed and introduced into the carbon monoxide combustion stage to moderate the temperature of combustion.

Claim 4

Dependent Claim 39 words

The process of claim 1 further including the step of recycling substantially all of the gaseous overhead stream of oxygen and carbon dioxide in step (j) to the combustion zone to be mixed with oxygen and recycled carbon dioxide.

Claim 5

Dependent Claim 291 words

A process wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by complete combustion in a combustion zone, wherein essentially no residual carbon monoxide exists, with a mixture of oxygen diluted to a concentration of 24-30 mole percent with carbon dioxide is treated to provide a carbon dioxide-rich recycle gas stream comprising the steps of: (a) reducing the temperature of the resulting combusted effluent gas by indirect heat exchange in a waste heat boiler and recovering the waste heat from said gas; (b) direct cooling and quenching the effluent gas by the introduction of a water stream into the gas with the attendant condensation of water of combustion and the entrainment of particulates into the water stream with subsequent removal of the stream from the gas and without significant absorption of sulfur dioxide from the gas; (c) compressing the effluent gas to approximately the inlet pressure of the combustion zone; (d) separating the effluent gas into a carbon dioxide-rich recycle gas stream which constitutes 61-80 percent of the effluent stream and a remaining net gas stream which comprises the balance of the effluent stream; (e) recycling the carbon dioxide-rich recycle gas stream to the combustion zone as the diluent for oxygen fed to the zone for combustion; (f) compressing the net gas stream to a further elevated pressure; (g) aftercooling the compressed net gas stream with the attendant removal of condensed water; (h) drying the net gas stream to remove essentially any residual moisture, and (i) distilling the net gas stream to recover a gaseous overhead stream of oxygen and carbon dioxide, a liquid carbon dioxide stream produced from the condensed reflux of the distillation and a liquid bottom stream containing oxides of sulfur and nitrogen.

Claim 6

Dependent Claim 291 words

A process wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by complete combustion in a combustion zone, wherein essentially no residual carbon monoxide exists, with a mixture of oxygen diluted to a concentration of 24-30 mole percent with carbon dioxide is treated to provide a carbon dioxide-rich recycle gas stream comprising the steps of: (a) reducing the temperature of the resulting combusted effluent gas by indirect heat exchange in a waste heat boiler and recovering the waste heat from said gas; (b) direct cooling and quenching the effluent gas by the introduction of a water stream into the gas with the attendant condensation of water of combustion and the entrainment of particulates into the water stream with subsequent removal of the stream from the gas and without significant absorption of sulfur dioxide from the gas; (c) compressing the effluent gas to approximately the inlet pressure of the combustion zone; (d) separating the effluent gas into a carbon dioxide-rich recycle gas stream which constitutes 61-80 percent of the effluent stream and a remaining net gas stream which comprises the balance of the effluent stream; (e) recycling the carbon dioxide-rich recycle gas stream to the combustion zone as the diluent for oxygen fed to the zone for combustion; (f) compressing the net gas stream to a further elevated pressure; (g) aftercooling the compressed net gas stream with the attendant removal of condensed water; (h) drying the net gas stream to remove essentially any residual moisture, and (i) distilling the net gas stream to recover a gaseous overhead stream of oxygen and carbon dioxide, a liquid carbon dioxide stream produced from the condensed reflux of the distillation and a liquid bottom stream containing oxides of sulfur and nitrogen.

Claim 7

Dependent Claim 39 words

The process of claim 4 further including the step of recycling substantially all of the gaseous overhead stream of oxygen and carbon dioxide of step (j) to the combustion zone to be mixed with oxygen and recycled carbon dioxide.

Claim 8

Dependent Claim 312 words

A process wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by combustion in a combustion zone with a mixture of oxygen diluted to a concentration of 24-30 mole percent with carbon dioxide is treated to provide a carbon dioxide-rich recycle gas stream and a carbon-monoxide-rich stream for further processing, comprising the steps of: (a) reducing the temperature of the effluent flue gas from the combustion zone to 150°-425° C. and recovering waste heat; (b) passing the effluent flue gas over a deoxygenation and reducing catalyst to eliminate oxygen and reduce SO X to H 2 S and NO X to N 2 ; (c) further reducing the temperature of the effluent flue gas recovering waste heat; (d) quenching the effluent flue gas by the introduction of a water stream into the gas with the attendant condensation of water of combustion and the entrainment of particulates into the water stream with subsequent removal of the stream from the gas and without significant absorption of sulfur from the gas; (e) compressing the effluent flue gas to a pressure in the range of 10 to 20 atm. and drying the pressurized stream; (f) separating a carbon dioxide-rich recycle stream and a net combustion product gas in a low temperature phase separation of the effluent flue gas; (g) recycling the carbon dioxide-rich recycle stream to the combustion zone as the diluent for oxygen fed to the zone for combustion; (h) compressing the net combustion product gas to an elevated pressure; (i) converting at least a part of the carbon monoxide content of the net combustion product stream by the shift reaction to reduce the carbon monoxide content of the stream and produce hydrogen and additional carbon dioxide, and (j) separating the stream into a carbon dioxide stream, a hydrogen stream and a hydrogen sulfide stream by a solvent sorption system.

Claim 9

Dependent Claim 312 words

A process wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by combustion in a combustion zone with a mixture of oxygen diluted to a concentration of 24-30 mole percent with carbon dioxide is treated to provide a carbon dioxide-rich recycle gas stream and a carbon-monoxide-rich stream for further processing, comprising the steps of: (a) reducing the temperature of the effluent flue gas from the combustion zone to 150°-425° C. and recovering waste heat; (b) passing the effluent flue gas over a deoxygenation and reducing catalyst to eliminate oxygen and reduce SO X to H 2 S and NO X to N 2 ; (c) further reducing the temperature of the effluent flue gas recovering waste heat; (d) quenching the effluent flue gas by the introduction of a water stream into the gas with the attendant condensation of water of combustion and the entrainment of particulates into the water stream with subsequent removal of the stream from the gas and without significant absorption of sulfur from the gas; (e) compressing the effluent flue gas to a pressure in the range of 10 to 20 atm. and drying the pressurized stream; (f) separating a carbon dioxide-rich recycle stream and a net combustion product gas in a low temperature phase separation of the effluent flue gas; (g) recycling the carbon dioxide-rich recycle stream to the combustion zone as the diluent for oxygen fed to the zone for combustion; (h) compressing the net combustion product gas to an elevated pressure; (i) converting at least a part of the carbon monoxide content of the net combustion product stream by the shift reaction to reduce the carbon monoxide content of the stream and produce hydrogen and additional carbon dioxide, and (j) separating the stream into a carbon dioxide stream, a hydrogen stream and a hydrogen sulfide stream by a solvent sorption system.

Claim 10

Dependent Claim 17 words

The process of claim 6 wherein the separation of step (f) is performed predominantly with auto refrigeration.

Claim 11

Dependent Claim 41 words

The process of claim 6 wherein the separation of step (j) is performed by a physical solvent which selectively absorbs H 2 S to a greater extent than CO 2 and does not absorb an appreciable amount of H 2 .

Claim 12

Dependent Claim 35 words

The process of claim 6 wherein the shifting of carbon monoxide of step (i) is only partially complete and the separation of step (j) results in the hydrogen stream having a significant carbon monoxide content.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1988-09-16	1989-03-18	1989-09-17	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1992-09-16	1993-03-18	1993-09-17	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1996-09-16	1997-03-18	1997-09-17	$7700.00	Window Closed / Lapsed

Process for the recovery and recycle of effluent gas from the regeneration of particulate matter with oxygen and carbon dioxide

Abstract

Inventors

Bibliographic Details

Claims Analysis

References Cited (Backward Citations)

USPTO Annuity & Maintenance Windows

Assigned Categories & Tags

Assign Category Tag