US4544784A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Methane conversion
Assignee: Atlantic Richfield Co
•
Filing: 1984-04-16
•
Granted: 1985-10-01
•
Expires: 2004-04-16
Abstract
Abstract A method is disclosed for converting methane to higher hydrocarbon product by contacting methane with a contact solid which comprises a reducible metal oxide which when contacted with methane at a temperature within the range of about 500° to 1000° C. is reduced and produces higher hydrocarbon products and water; and a promoting amount of at least one halogen component.
Inventors
- 👤 John A. Sofranko
- 👤 C. Andrew Jones
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 01:20
CPC Classifications
C; C07; C07C; C07C2/00; C07C2/76; C07C2/82; C07C2/84; C07C2521/00; C07C2521/06; C07C2521/08; C07C2521/10; C07C2523/00; C07C2523/02; C07C2523/08; C07C2523/14; C07C2523/16; C07C2523/18; C07C2523/32; C07C2523/34; Y; Y10; Y10S; Y10S585/00; Y10S585/929; Y10S585/943
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
84 words
In an improved method for converting methane to higher hydrocarbon products wherein a gas comprising methane is contacted at a temperature within the range of about 500° to 1000° C. with a contact solid comprising at least one reducible oxide of at least one metal which oxides when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water, the improvement which comprises conducting the contacting with said contact solid which further comprises at least one halogen or compound thereof.
Claim 2
Dependent Claim
84 words
In an improved method for converting methane to higher hydrocarbon products wherein a gas comprising methane is contacted at a temperature within the range of about 500° to 1000° C. with a contact solid comprising at least one reducible oxide of at least one metal which oxides when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water, the improvement which comprises conducting the contacting with said contact solid which further comprises at least one halogen or compound thereof.
Claim 3
Independent Claim
170 words
A method for converting methane to higher hydrocarbons which comprises: (a) contacting at a temperature selected within the range of about 500° to 1000° C. a gas comprising methane and a contact solid comprising: (1) at least one reducible oxide of at least one metal selected from the group consisting of Mn, Sn, In, Ge, Pb, Sb and Bi and (2) at least one promoter selected from the group consisting of the halogens and compounds thereof, said contacting producing an effluent comprising higher hydrocarbons and water and solids comprising reduced metal oxides; (b) recovering higher hydrocarbons; (c) at least periodically contacting solids comprising reduced metal oxides with an oxygen-containing gas to regenerate solids comprising a reducible metal oxide; (d) at least periodically contacting solids selected from the group consisting of solids comprising reduced metal oxides and said regenerated solids with a halogen source to incorporate additional halogen promoter into said selected solids; and (e) contacting a gas comprising methane with solids produced in step (d) as recited in step (a).
Claim 4
Independent Claim
170 words
A method for converting methane to higher hydrocarbons which comprises: (a) contacting at a temperature selected within the range of about 500° to 1000° C. a gas comprising methane and a contact solid comprising: (1) at least one reducible oxide of at least one metal selected from the group consisting of Mn, Sn, In, Ge, Pb, Sb and Bi and (2) at least one promoter selected from the group consisting of the halogens and compounds thereof, said contacting producing an effluent comprising higher hydrocarbons and water and solids comprising reduced metal oxides; (b) recovering higher hydrocarbons; (c) at least periodically contacting solids comprising reduced metal oxides with an oxygen-containing gas to regenerate solids comprising a reducible metal oxide; (d) at least periodically contacting solids selected from the group consisting of solids comprising reduced metal oxides and said regenerated solids with a halogen source to incorporate additional halogen promoter into said selected solids; and (e) contacting a gas comprising methane with solids produced in step (d) as recited in step (a).
Claim 5
Dependent Claim
22 words
The method of claim 2 hwerein said oxygen-containing gas and said halogen source are simultaneously contacted with solids comprising reduced metal oxides.
Claim 6
Dependent Claim
23 words
The method of claim 2 wherein said gas comprising methane and said halogen source are simultaneously contacted with solids comprising reducible metal oxides.
Claim 7
Dependent Claim
102 words
In an improved process for converting methane to higher hydrocarbon products comprising contacting a gas comprising methane at a temperature selected within the range of about 500° to 1000° C. with a solid comprising: (a) at least one reducible oxide of at least one metal which oxide(s) when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water and (b) at least one member of the group consisting of alkali metals, alkaline earth metals and compounds thereof; the improvement which comprises conducting the contacting with said solid which further comprises at least one halogen or compound thereof.
Claim 8
Dependent Claim
102 words
In an improved process for converting methane to higher hydrocarbon products comprising contacting a gas comprising methane at a temperature selected within the range of about 500° to 1000° C. with a solid comprising: (a) at least one reducible oxide of at least one metal which oxide(s) when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water and (b) at least one member of the group consisting of alkali metals, alkaline earth metals and compounds thereof; the improvement which comprises conducting the contacting with said solid which further comprises at least one halogen or compound thereof.
Claim 9
Dependent Claim
23 words
The method of claim 5 wherein component (b) of the solid is selected from the group consisting of alkali metals and compounds thereof.
Claim 10
Dependent Claim
22 words
The method of claim 5 wherein component (b) of the solid is selected from the group consisting of sodium and compounds thereof.
Claim 11
Dependent Claim
22 words
The method of claim 5 wherein component (b) of the solid is selected from the group consisting of lithium and compounds thereof.
Claim 12
Dependent Claim
22 words
The method of claim 5 wherein component (b) of the solid is selected from the group consisting of potassium and compounds thereof.
Claim 13
Dependent Claim
133 words
In an improved method for converting methane to higher hydrocarbon products which method comprises: (a) contacting a gas comprising methane at a temperature within the range of about 500° to 1000° C. with at least one reducible oxide of at least one metal which oxide(s) when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water, (b) recovering higher hydrocarbons, (c) at least periodically contacting solids comprising reduced metal oxides with an oxygen-containing gas to regenerate solids comprising a reducible metal oxide, and (d) contacting a gas comprising methane with solids produced in (d) as recited in (a); the improvement which comprises at least periodically contacting a member of the group consisting of said reducible metal oxides, said reduced metal oxides, and mixtures thereof, with a halogen source.
Claim 14
Dependent Claim
133 words
In an improved method for converting methane to higher hydrocarbon products which method comprises: (a) contacting a gas comprising methane at a temperature within the range of about 500° to 1000° C. with at least one reducible oxide of at least one metal which oxide(s) when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water, (b) recovering higher hydrocarbons, (c) at least periodically contacting solids comprising reduced metal oxides with an oxygen-containing gas to regenerate solids comprising a reducible metal oxide, and (d) contacting a gas comprising methane with solids produced in (d) as recited in (a); the improvement which comprises at least periodically contacting a member of the group consisting of said reducible metal oxides, said reduced metal oxides, and mixtures thereof, with a halogen source.
Claim 15
Dependent Claim
84 words
In an improved method for converting methane to higher hydrocarbon products wherein a gas comprising methane is contacted at a temperature within the range of about 500° to 1000° C. with at least one reducible oxide of at least one metal which oxide(s) when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water, the improvement which comprises conducting the contacting in the presence of at least one promoter selected from the group consisting of halogens and compounds thereof.
Claim 16
Dependent Claim
84 words
In an improved method for converting methane to higher hydrocarbon products wherein a gas comprising methane is contacted at a temperature within the range of about 500° to 1000° C. with at least one reducible oxide of at least one metal which oxide(s) when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water, the improvement which comprises conducting the contacting in the presence of at least one promoter selected from the group consisting of halogens and compounds thereof.
References Cited (Backward Citations)
US4205194A
Cited
US4199533A
Cited
US4239508A
Cited
US4443648A
Cited
US4443645A
Cited
US4444984A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-09-30 | 1989-04-01 | 1989-10-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-09-30 | 1993-04-01 | 1993-10-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-09-30 | 1997-04-01 | 1997-10-01 | $7700.00 | Window Closed / Lapsed |