Method for extracting lanthanides and actinides from acid solutions

Claim 2

A process for the recovery of multivalent lanthanide and actinide values from an aqueous acid solution containing these and other values comprising: adjusting the molarity of the acid in the aqueous solution to between 0.1 and 12.0M to form a feed solution; contacting the feed solution with an extraction solution consisting of an organic extractant in an inert water-immiscible organic diluent, the extractant having the formula: ##STR4## where φ is phenyl, R' is a straight or branched alkyl containing from 6 to 12 carbon atoms and R 2 is an alkyl containing from 3 to 6 carbon atoms, whereby the multivalent lanthanide and actinide values are selectively extracted from the feed solution, thereby loading the extraction solution, separating the loaded extraction solution from the feed solution, and stripping the lanthanide and actinide values from the extraction solution, thereby recovering the lanthanide and actinide values.

Claim 3

The process of claim 1 wherein the aqueous acid feed solution is a strong mineral acid selected from the group consisting of nitric, hydrochloric and perchloric acid.

Claim 4

The process of claim 2 wherein the feed solution also contains from 0.05 to 0.2M oxalic acid.

Claim 5

The process of claim 3 wherein the feed solution is from 0.1 to 10M in nitric acid.

Claim 6

The process of claim 4 wherein the feed solution is from 0.5 to 5.0M in nitric acid.

Claim 7

The process of claim 5 wherein the extraction solution is from 0.1 to 0.5M in organic extractant.

Claim 8

The process of claim 6 wherein the lanthanide and actinide values are recovered by contacting the loaded extraction solution with an aqueous solution that is about 0.05 to 0.1M in nitric acid to strip the lanthanide and actinide values from the loaded extraction solution.

Claim 9

The process of claim 7 wherein R' is selected from the group consisting of octyl, 2,4,4-trimethylpentyl, 6-methylheptyl and 2-ethylhexyl, and R 2 is isobutyl.

Claim 10

The process of claim 8 including the additional step of contacting the loaded extraction solution with a 0.1 to 10.0M nitric acid solution to scrub any fission product values from the solution which may be co-extracted with the lanthanide and actinide values.

Claim 11

The process of claim 9 wherein the water-immiscible organic diluent is an aromatic or aliphatic hydrocarbon selected from the group consisting of diethylbenzene, diisopropylbenzene, xylene, decalin, dodecane, and kerosine.

Claim 12

A process for recovering multivalent lanthanide and actinide values from a nitric acid nuclear fuel waste reprocessing solution containing these values together with fission product and other metal values comprising: adjusting the molarity of the acid in the waste solution to between 0.5 and 5.0M and adding from 0.05 to 0.2M oxalic acid to the waste solution to form a feed solution: contacting the feed solution with an extraction solution of 0.1 to 0.5M of an organic extractant having the formula: ##STR5## where φ is phenyl, R' is a straight or branched alkyl containing from 6 to 12 carbon atoms and R 2 is an alkyl containing from 3 to 6 carbon atoms in an inert water-immiscible aromatic or aliphatic hydrocarbon diluent, whereby the multivalent lanthanide and actinide values are selectively extracted from the feed solution thereby loading the extraction solution, separating the loaded extraction solution from the feed solution, and contacting the loaded feed solution with a 0.05 to 0.1M nitric acid solution to strip the lanthanide and actinide values from the extraction solution, thereby recovering the lanthanide and actinide values.

Claim 13

A process for recovering multivalent lanthanide and actinide values from a nitric acid nuclear fuel waste reprocessing solution containing these values together with fission product and other metal values comprising: adjusting the molarity of the acid in the waste solution to between 0.5 and 5.0M and adding from 0.05 to 0.2M oxalic acid to the waste solution to form a feed solution: contacting the feed solution with an extraction solution of 0.1 to 0.5M of an organic extractant having the formula: ##STR5## where φ is phenyl, R' is a straight or branched alkyl containing from 6 to 12 carbon atoms and R 2 is an alkyl containing from 3 to 6 carbon atoms in an inert water-immiscible aromatic or aliphatic hydrocarbon diluent, whereby the multivalent lanthanide and actinide values are selectively extracted from the feed solution thereby loading the extraction solution, separating the loaded extraction solution from the feed solution, and contacting the loaded feed solution with a 0.05 to 0.1M nitric acid solution to strip the lanthanide and actinide values from the extraction solution, thereby recovering the lanthanide and actinide values.

Claim 14

The process of claim 11 including the additional step of contacting the loaded extraction solution with a 0.1 to 10.0M nitric acid solution to scrub any fission product values from the solution which may be co-extracted with the lanthanide and actinide values.

Claim 15

A compound having the structural formula: R1 ? ##STR6## where φ is phenyl, R 1 is a straight or branched alkyl containing from 6 to 12 carbon atoms and R 2 is an alkyl containing from 3 to 6 carbon atoms.

Claim 16

A compound having the structural formula: R1 ? ##STR6## where φ is phenyl, R 1 is a straight or branched alkyl containing from 6 to 12 carbon atoms and R 2 is an alkyl containing from 3 to 6 carbon atoms.

Claim 17

The compound of claim 13 wherein R 1 and R 2 are branched.

Claim 18

The compound of claim 14 wherein R 1 is selected from the group consisting of octyl, 2,4,4-tri-methylpentyl, 6-methylheptyl and 2-ethylhexyl, and R 2 is isobutyl.